Principles of classification
The dangerous goods covered by the heading of a class are defined on the basis of their properties
according to sub-section 2.2.x.1 of the relevant class. Assignment of dangerous goods to a class and a
packing group is made according to the criteria mentioned in the same sub-section 2.2.x.1.
Assignment of one or several subsidiary risk(s) to a dangerous substance or article is made according
to the criteria of the class or classes corresponding to those risks, as mentioned in the appropriate subsection(
All dangerous goods entries are listed in Table A of Chapter 3.2 in the numerical order of their UN
Number. This table contains relevant information on the goods listed, such as name, class, packing
group(s), label(s) to be affixed, packing and carriage provisions1. The substances listed by name in
column (2) of Table A of Chapter 3.2 shall be carried according to their classification in Table A or
under the conditions specified in 22.214.171.124.
A substance may contain technical impurities (for example those deriving from the production
process) or additives for stability or other purposes that do not affect their classification. However, a
substance mentioned by name, i.e. listed as a single entry in Table A of Chapter 3.2, containing
technical impurities or additives for stability or other purposes affecting its classification shall be
considered a solution or mixture (see 126.96.36.199).
Dangerous goods which are listed or defined in sub-section 2.2.x.2 of each class are not to be accepted
Goods not mentioned by name, i.e. goods not listed as single entries in Table A of Chapter 3.2 and not
listed or defined in one of the above-mentioned sub-sections 2.2.x.2 shall be assigned to the relevant
class in accordance with the procedure of section 2.1.3. In addition, the subsidiary risk (if any) and the
packing group (if any) shall be determined. Once the class, subsidiary risk (if any) and packing group
(if any) have been established the relevant UN number shall be determined. The decision trees in subsections
2.2.x.3 (list of collective entries) at the end of each class indicate the relevant parameters for
selecting the relevant collective entry (UN number). In all cases the most specific collective entry
covering the properties of the substance or article shall be selected, according to the hierarchy
indicated in 188.8.131.52 by the letters B, C and D respectively. If the substance or article cannot be
classified under entries of type B or C according to 184.108.40.206, then, and only then shall it be classified
under an entry of type D.
On the basis of the test procedures of Chapter 2.3 and the criteria set out in sub-sections 2.2.x.1 of
classes when it is so specified, it may be determined that a substance, solution or mixture of a certain
class, mentioned by name in Table A of Chapter 3.2, does not meet the criteria of that class. In such a
case, the substance, solution or mixture is deemed not to belong to that class.
For the purposes of classification, substances with a melting point or initial melting point of 20 °C or
lower at a pressure of 101.3 kPa shall be considered to be liquids. A viscous substance for which a
specific melting point cannot be determined shall be subjected to the ASTM D 4359-90 test or to the
test for determining fluidity (penetrometer test) prescribed in 2.3.4.
A consignor who has identified, on the basis of test data, that a substance listed by name in column 2
of Table A of Chapter 3.2 meets classification criteria for a class that is not identified in column 3a or
5 of Table A of Chapter 3.2, may, with the approval of the competent authority, consign the
– Under the most appropriate collective entry listed in sub-sections 2.2.x.3 reflecting all hazards;
– Under the same UN number and name but with additional hazard communication information
as appropriate to reflect the additional subsidiary risk(s) (documentation, label, placard)
provided that the class remains unchanged and that any other carriage conditions (e.g. limited
quantity, packaging and tank provisions) that would normally apply to substances possessing
such a combination of hazards are the same as those applicable to the substance listed.
NOTE 1: The competent authority granting the approval may be the competent authority of any
ADR Contracting Party who may also recognize an approval granted by the competent authority of a
country which is not an ADR Contracting Party provided that this approval has been granted in
accordance with the procedures applicable according to RID, ADR, ADN, the IMDG Code or the
ICAO Technical Instructions.
NOTE 2: When a competent authority grants such approvals, it should inform the United Nations
Sub-Committee of Experts on the Transport of Dangerous Goods accordingly and submit a relevant
proposal of amendment to the Dangerous Goods List of the UN Model Regulations. Should the
proposed amendment be rejected, the competent authority should withdraw its approval.
NOTE 3: For carriage in accordance with 220.127.116.11, see also 18.104.22.168.20.
Classification of substances, including solutions and mixtures (such as preparations and wastes), not mentioned by name
Substances including solutions and mixtures not mentioned by name shall be classified according to
their degree of danger on the basis of the criteria mentioned in sub-section 2.2.x.1 of the various
classes. The danger(s) presented by a substance shall be determined on the basis of its physical and
chemical characteristics and physiological properties. Such characteristics and properties shall also be
taken into account when such experience leads to a more stringent assignment.
A substance not mentioned by name in Table A of Chapter 3.2 presenting a single hazard shall be
classified in the relevant class under a collective entry listed in sub-section 2.2.x.3 of that class.
A solution or mixture meeting the classification criteria of ADR composed of a single predominant
substance mentioned by name in Table A of Chapter 3.2 and one or more substances not subject to
ADR or traces of one or more substances mentioned by name in Table A of Chapter 3.2, shall be
assigned the UN number and proper shipping name of the predominant substance mentioned by name
in Table A of Chapter 3.2 unless:
(a) The solution or mixture is mentioned by name in Table A of Chapter 3.2;
(b) The name and description of the substance mentioned by name in Table A of Chapter 3.2
specifically indicate that they apply only to the pure substance;
(c) The class, classification code, packing group, or physical state of the solution or mixture is
different from that of the substance mentioned by name in Table A of Chapter 3.2; or
(d) The hazard characteristics and properties of the solution or mixture necessitate emergency
response measures that are different from those required for the substance mentioned by name
in Table A of Chapter 3.2.
In those other cases, except the one described in (a), the solution or mixture shall be classified as a
substance not mentioned by name in the relevant class under a collective entry listed in
sub-section 2.2.x.3 of that class taking account of the subsidiary risks presented by that solution or
mixture, if any, unless the solution or mixture does not meet the criteria of any class, in which case it
is not subject to ADR.
Solutions and mixtures containing substances belonging to one of the entries mentioned in 22.214.171.124.1 or
126.96.36.199.2 shall be classified in accordance with the provisions of these paragraphs.
Solutions and mixtures containing one of the following substances mentioned by name shall always
be classified under the same entry as the substance they contain, provided they do not have the hazard
characteristics as indicated in 188.8.131.52.3:
- Class 3
UN No. 1921 PROPYLENEIMINE, STABILIZED; UN No. 3064 NITROGLYCERIN
SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin;
- Class 6.1
UN No. 1051 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water; UN
No. 1185 ETHYLENEIMINE, STABILIZED; UN No. 1259 NICKEL CARBONYL; UN No.
1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE,
AQUEOUS SOLUTION), with not more than 20% hydrogen cyanide; UN No. 1614
HYDROGEN CYANIDE, STABILIZED, containing not more than 3% water and absorbed in
a porous inert material; UN No. 1994 IRON PENTACARBONYL; UN No. 2480 METHYL
ISOCYANATE; UN No. 2481 ETHYL ISOCYANATE; UN No. 3294 HYDROGEN
CYANIDE, SOLUTION IN ALCOHOL, with not more than 45% hydrogen cyanide;
- Class 8
UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS; UN No. 1744 BROMINE or UN
No. 1744 BROMINE SOLUTION; UN No. 1790 HYDROFLUORIC ACID with more than
85% hydrogen fluoride; UN No. 2576 PHOSPHORUS OXYBROMIDE, MOLTEN;