Solutions and mixtures containing substances belonging to one of the entries mentioned in 2.1.3.4.1 or
2.1.3.4.2 shall be classified in accordance with the provisions of these paragraphs.

Solutions and mixtures containing one of the following substances mentioned by name shall always
be classified under the same entry as the substance they contain, provided they do not have the hazard
characteristics as indicated in 2.1.3.5.3:
- Class 3
UN No. 1921 PROPYLENEIMINE, STABILIZED; UN No. 3064 NITROGLYCERIN
SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin;
- Class 6.1
UN No. 1051 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water; UN
No. 1185 ETHYLENEIMINE, STABILIZED; UN No. 1259 NICKEL CARBONYL; UN No.
1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE,
AQUEOUS SOLUTION), with not more than 20% hydrogen cyanide; UN No. 1614
HYDROGEN CYANIDE, STABILIZED, containing not more than 3% water and absorbed in
a porous inert material; UN No. 1994 IRON PENTACARBONYL; UN No. 2480 METHYL
ISOCYANATE; UN No. 2481 ETHYL ISOCYANATE; UN No. 3294 HYDROGEN
CYANIDE, SOLUTION IN ALCOHOL, with not more than 45% hydrogen cyanide;
- Class 8
UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS; UN No. 1744 BROMINE or UN
No. 1744 BROMINE SOLUTION; UN No. 1790 HYDROFLUORIC ACID with more than
85% hydrogen fluoride; UN No. 2576 PHOSPHORUS OXYBROMIDE, MOLTEN;

 

Solutions and mixtures containing a substance belonging to one of the following entries of Class 9:
UN No. 2315 POLYCHLORINATED BIPHENYLS, LIQUID;
UN No. 3151 POLYHALOGENATED BIPHENYLS, LIQUID;
UN No. 3151 HALOGENATED MONOMETHYLDIPHENYLMETHANES, LIQUID;
UN No. 3151 POLYHALOGENATED TERPHENYLS, LIQUID;
UN No. 3152 POLYHALOGENATED BIPHENYLS, SOLID;
UN No. 3152 HALOGENATED MONOMETHYLDIPHENYLMETHANES, SOLID;
UN No. 3152 POLYHALOGENATED TERPHENYLS, SOLID; or
UN No. 3432 POLYCHLORINATED BIPHENYLS, SOLID
shall always be classified under the same entry of Class 9 provided that:
- they do not contain any additional dangerous component other than components of packing
group III of classes 3, 4.1, 4.2, 4.3, 5.1, 6.1 or 8; and
- they do not have the hazard characteristics as indicated in 2.1.3.5.3.

Substances not mentioned by name in Table A of Chapter 3.2, having more than one hazard
characteristic and solutions or mixtures meeting the classification criteria of ADR containing several
dangerous substances shall be classified under a collective entry (see 2.1.2.5) and packing group of
the appropriate class in accordance with their hazard characteristics. Such classification according to
the hazard characteristics shall be carried out as follows:

The physical and chemical characteristics and physiological properties shall be determined by
measurement or calculation and the substance, solution or mixture shall be classified according to the
criteria mentioned in sub-section 2.2.x.1 of the various classes.

If this determination is not possible without disproportionate cost or effort (as for some kinds of
wastes), the substance, solution or mixture shall be classified in the class of the component presenting
the major hazard.

If the hazard characteristics of the substance, solution or mixture fall within more than one class or
group of substances listed below then the substance, solution or mixture shall be classified in the class
or group of substances corresponding to the major hazard on the basis of the following order of
precedence:
(a) Material of Class 7 (apart from radioactive material in excepted packages for which, except for
UN 3507 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED
PACKAGE, special provision 290 of Chapter 3.3 applies , where the other hazardous
properties take precedence);
(b) Substances of Class 1;
(c) Substances of Class 2;
(d) Liquid desensitized explosives of Class 3;
(e) Self-reactive substances and solid desensitized explosives of Class 4.1;
(f) Pyrophoric substances of Class 4.2;
(g) Substances of Class 5.2;
(h) Substances of Class 6.1 meeting the inhalation toxicity criteria of packing group I (Substances
meeting the classification criteria of Class 8 and having an inhalation toxicity of dust and mist
(LC50) in the range of Packing group I and a toxicity through oral ingestion or dermal contact
only in the range of Packing group III or less, shall be allocated to Class 8);
(i) Infectious substances of Class 6.2.

 

If the hazard characteristics of the substance fall within more than one class or group of substances
not listed in 2.1.3.5.3 above, the substance shall be classified in accordance with the same procedure
but the relevant class shall be selected according to the precedence of hazards table in 2.1.3.10.

If the substance to be carried is a waste, with a composition that is not precisely known, its assignment
to a UN number and packing group in accordance with 2.1.3.5.2 may be based on the consignor’s
knowledge of the waste, including all available technical and safety data as requested by safety and
environmental legislation in force2.
In case of doubt, the highest danger level shall be taken.
If however, on the basis of the knowledge of the composition of the waste and the physical and
chemical properties of the identified components, it is possible to demonstrate that the properties of
the waste do not correspond to the properties of the packing group I level, the waste may be classified
by default in the most appropriate n.o.s. entry of packing group II. However, if it is known that the
waste possesses only environmentally hazardous properties, it may be assigned to packing group III
under UN Nos. 3077 or 3082.
This procedure may not be used for wastes containing substances mentioned in 2.1.3.5.3, substances
of Class 4.3, substances of the case mentioned in 2.1.3.7 or substances which are not accepted for
carriage in accordance with 2.2.x.2.

The most specific applicable collective entry (see 2.1.2.5) shall always be used, i.e. a general n.o.s.
entry shall only be used if a generic entry or a specific n.o.s. entry cannot be used.

Solutions and mixtures of oxidizing substances or substances with an oxidizing subsidiary risk may
have explosive properties. In such a case they are not to be accepted for carriage unless they meet the
requirements for Class 1.

Substances of classes 1 to 6.2, 8 and 9, other than those assigned to UN Nos. 3077 and 3082, meeting
the criteria of 2.2.9.1.10 are additionally to their hazards of classes 1 to 6.2, 8 and 9 considered to be
environmentally hazardous substances. Other substances meeting the criteria of no other class, but
those of 2.2.9.1.10 are to be assigned to UN Nos. 3077 and 3082 as appropriate.

Wastes that do not meet the criteria for classification in classes 1 to 9 but are covered by the Basel
Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal
may be carried under UN Nos. 3077 or 3082.

2.1.3.10 Table of precedence of hazards

Table of precedence of hazards
Class
and
packing
group

 

4.1, II

 

4,1, III

 

4.2, II

 

4.2, III

 

4.3, I

 

4.3, II

 

4.3, III

 

5.1, I

 

5.1, II

 

5,1, III

 

6.1, I DERMAL

 

6.1, I ORAL

 

6.1, II

 

6.1, III

 

8, I

 

8, II

 

8, III

 

9

 

3, I

SOL LIQ

4.1 3, I

SOL LIQ

4.1 3, I

SOL LIQ

4.2 3, I

SOL LIQ

4.2 3, I

4.3, I

4.3, I

4.3, I

SOL LIQ 5.1, I 3, I

SOL LIQ 5.1, I 3, I

SOL LIQ 5.1, I 3, I

3, I

3, I

3, I

3, I

3, I

3, I

3, I

3, I

3, II

SOL LIQ

4.1 3, II

SOL LIQ

4.1 3, II

SOL LIQ

4.2 3, II

SOL LIQ

4.2 3, II

4.3, I

4.3, II

4.3, II

SOL LIQ 5.1, I 3, I

SOL LIQ 5.1, II 3, II

SOL LIQ 5.1, II 3, II

3, I

3, I

3, II

3, II

8, I

3, II

3, II

3, II

3, III

SOL LIQ

4.1 3, II

SOL LIQ

4.1 3, III

SOL LIQ

4.2 3, II

SOL LIQ

4.2 3, III

4,3, I

4.3, II

4.3, III

SOL LIQ 5.1, I 3, I

SOL LIQ 5.1, II 3, II

SOL LIQ 5.1, III 3, III

6.1, I

6.1, I

6.1, II

3, III a

8, I

8, II

3, III

3, III

4.1, II

   

4.2, II

4.2, II

4.3, I

4.3, II

4.3, II

5.1, I

4.1, II

4.1, II

6.1, I

6.1, I

SOL LIQ 4.1, II 6.1, II

SOL LIQ 4.1, II 6.1, II

8, I

SOL LIQ 4.1, II 8, II

SOL LIQ 4.1, II 8, II

4.1, II

4.1, III

   

4.2, II

4.2, III

4.3, I

4.3, II

4.3, III

5.1, I

4,1, II

4.1, III

6.1, I

6.1, I

6.1, II

SOL LIQ 4.1, III 6.1, III

8, I

8, II

SOL LIQ 4.1, III 8, III

4.1, III

4.2, II

       

4.3, I

4.3, II

4.3, II

5.1, I

4.2, II

4.2, II

6.1, I

6.1, I

4.2, II

4.2, II

8, I

4.2, II

4.2, II

4.2, II

4.2, III

       

4.3, I

4.3, II

4.3, III

5.1, I

5.1, II

4.2, III

6.1, I

6.1, I

6.1, II

4.2, III

8, I

8, II

4,2, III

4.2, III

4.3, I

             

5.1, I

4.3, I

4.3, I

6.1, I

4.3, I

4.3, I

4.3, I

4,3, I

4.3, I

4.3, I

4.3, I

4.3, II

             

5.1, I

4.3, II

4.3, II

6.1, I

4.3, I

4.3, II

4.3, II

8, I

4.3, II

4.3, II

4.3, II

4.3, III

             

5.1, I

5.1, II

4.3, III

6.1, I

6.1, I

6.1, II

4.3, III

8, I

8, II

4.3, III

4.3, III

5.1, I

                   

5.1, I

5.1, I

5,1, I

5.1, I

5,1, I

5,1, I

5.1, I

5,1, I

5.1, II

                   

6.1, I

5.1, I

5.1, II

5.1, II

8, I

5.1, II

5.1, II

5.1, II

5.1, III

                   

6.1, I

6.1, I

6.1, II

5.1, III

8, I

8, II

5.1, III

5.1, III

6.1, I DERMAL

                           

SOL LIQ 6.1, I 8, I

6.1, I

6.1, I

6.1, I

6.1, I ORAL

                           

SOL LIQ 6.1, I 8, I

6.1, I

6.1, I

6.1, I

6.1, II SOLUMA

                           

SOL LIQ 6.1, I 8, I

6.1, II

6.1, II

6.1, II

6.1, II DERMAL

                           

SOL LIQ 6.1, I 8, I

SOL LIQ 6.1, II 8, II

6.1, II

6.1, II

6.1, II ORAL

   

 

SOL = Solid substances and mixtures
LIQ = Liquid substances, mixtures and solutions
DERMAL = Dermal toxicity
ORAL = Oral toxicity
INHAL = Inhalation toxicity
a Class 6.1 for pesticides

8.1

SOL LIQ 6.1, II 8, II

6.1, II

6.1, II

6.1, III

   

8, I

8, II

8, III

6.1, III

8, I

         

8, I

8, II

         

8, II

8, III

         

8, III

 
 
NOTE 1: Examples to explain the use of the table
Classification of a single substance
Description of the substance to be classified:
An amine not mentioned by name meeting the criteria for Class 3, packing group II as well as those
for Class 8, packing group I.
Procedure:
The intersection of line 3 II with column 8 I gives 8 I.
This amine has therefore to be classified in Class 8 under:
UN No. 2734 AMINES LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or UN No. 2734
POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.
packing group I
Classification of a mixture
Description of the mixture to be classified:
Mixture consisting of a flammable liquid classified in Class 3, packing group III, a toxic substance in
Class 6.1, packing group II and a corrosive substance in Class 8, packing group I.
Procedure:
The intersection of line 3 III with column 6.1 II gives 6.1 II.
The intersection of line 6.1 II with column 8 I gives 8 I LIQ.
This mixture not further defined has therefore to be classified in Class 8 under:
UN No. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. packing group I.
NOTE 2: Examples for the classification of mixtures and solutions under a class and a packing
group:
A phenol solution of Class 6.1, (II), in benzene of Class 3, (II) is to be classified in Class 3, (II); this
solution is to be classified under UN No. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S., Class 3, (II),
by virtue of the toxicity of the phenol.
A solid mixture of sodium arsenate of Class 6.1, (II) and sodium hydroxide of Class 8, (II) is to be
classified under UN No. 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S., in Class 6.1 (II).
A solution of crude or refined naphthalene of Class 4.1, (III) in petrol of Class 3, (II), is to be
classified under UN No. 3295 HYDROCARBONS, LIQUID, N.O.S. in Class 3, (II).
A mixture of hydrocarbons of Class 3, (III), and of polychlorinated biphenyls (PCB) of Class 9, (II), is
to be classified under UN No. 2315 POLYCHLORINATED BIPHENYLS LIQUID or UN No. 3432
POLYCHLORINATED BIPHENYLS SOLID in Class 9, (II).
A mixture of propyleneimine of Class 3, and polychlorinated biphenyls (PCB) of Class 9, (II), is to be
classified under UN No. 1921 PROPYLENEIMINE, INHIBITED in Class 3.

Classification of samples

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