4.1.1.20.4

The proper shipping name, the UN number preceded by the letters "UN" and label(s) as required for

packages in Chapter 5.2 applicable to the dangerous goods inside the contained pressure receptacle(s)

shall be applied to the salvage pressure receptacle for carriage.

4.1.1.20.5

Salvage pressure receptacles shall be cleaned, purged and visually inspected internally and externally

after each use. They shall be periodically inspected and tested in accordance with 6.2.3.5 at least once

every five years.

4.1.1.21

Verification of the chemical compatibility of plastics packagings, including IBCs, by assimilation of filling substances to standard liquids

4.1.1.21.1

Scope

For polyethylene packagings as specified in 6.1.5.2.6, and for polyethylene IBCs as specified in

6.5.6.3.5, the chemical compatibility with filling substances may be verified by assimilation to

standard liquids following the procedures, as set out in 4.1.1.21.3 to 4.1.1.21.5 and using the list in

table 4.1.1.21.6, provided that the particular design types have been tested with these standard liquids

in accordance with 6.1.5 or 6.5.6, taking into account 6.1.6 and that the conditions in 4.1.1.21.2 are

met. When assimilation in accordance with this sub-section is not possible, the chemical compatibility

needs to be verified by design type testing in accordance with 6.1.5.2.5 or by laboratory tests in

accordance with 6.1.5.2.7 for packagings, and in accordance with 6.5.6.3.3 or 6.5.6.3.6 for IBCs,

respectively.

NOTE: Irrespective of the provisions of this sub-section, the use of packagings, including IBCs,

for a specific filling substance is subject to the limitations of Table A of Chapter 3.2, and the packing

instructions in Chapter 4.1.

4.1.1.21.2

Conditions

The relative densities of the filling substances shall not exceed that used to determine the height for

the drop test performed successfully according to 6.1.5.3.5 or 6.5.6.9.4 and the mass for the stacking

test performed successfully according to 6.1.5.6 or where necessary according to 6.5.6.6 with the

assimilated standard liquid(s). The vapour pressures of the filling substances at 50 °C or 55 °C shall

not exceed that used to determine the pressure for the internal pressure (hydraulic) test performed

successfully according to 6.1.5.5.4 or 6.5.6.8.4.2 with the assimilated standard liquid(s). In case that

filling substances are assimilated to a combination of standard liquids, the corresponding values of the

filling substances shall not exceed the minimum values derived from the applied drop heights,

stacking masses and internal test pressures.

Example: UN 1736 Benzoyl chloride is assimilated to the combination of standard liquids "Mixture of

hydrocarbons and wetting solution". It has a vapour pressure of 0.34 kPa at 50 °C and a relative

density of approximately 1.2. Design type tests for plastics drums and jerricans were frequently

performed at minimum required test levels. In practice this means that the stacking test is commonly

performed with stacking loads considering only a relative density of 1.0 for the "Mixture of

hydrocarbons" and a relative density of 1.2 for the "Wetting solution" (see definition of standard

liquids in 6.1.6). As a consequence chemical compatibility of such tested design types would not be

verified for benzoyl chloride by reason of the inadequate test level of the design type with the standard

liquid "mixture of hydrocarbons". (Due to the fact that in the majority of cases the applied internal

hydraulic test pressure is not less than 100 kPa, the vapour pressure of benzoyl chloride would be

covered by such test level according to 4.1.1.10).

All components of a filling substance, which may be a solution, mixture or preparation, such as

wetting agents in detergents and disinfectants, irrespective whether dangerous or non-dangerous, shall

be included in the assimilation procedure.

4.1.1.21.3

Assimilation procedure

The following steps shall be taken to assign filling substances to listed substances or groups of

substances in table 4.1.1.21.6 (see also scheme in Figure 4.1.1.21.1):

(a) Classify the filling substance in accordance with the procedures and criteria of Part 2

(determination of the UN number and packing group);

(b) If it is included there, go to the UN number in column (1) of table 4.1.1.21.6;

presence of non-dangerous components etc. by means of the information given in columns

(2a), (2b) and (4), if there is more than one entry for this UN number.

If this is not possible, the chemical compatibility shall be verified in accordance with 6.1.5.2.5

or 6.1.5.2.7 for packagings, and in accordance with 6.5.6.3.3 or 6.5.6.3.6 for IBCs (however, in

the case of aqueous solutions, see 4.1.1.21.4);

(d) If the UN number and packing group of the filling substance determined in accordance with (a)

is not included in the assimilation list, the chemical compatibility shall be proved in

accordance with 6.1.5.2.5 or 6.1.5.2.7 for packagings, and in accordance with 6.5.6.3.3 or

6.5.6.3.6 for IBCs;

(e) Apply the "Rule for collective entries", as described in 4.1.1.21.5, if this is indicated in column

(5) of the selected line;

(f) The chemical compatibility of the filling substance may be regarded as verified taking into

account 4.1.1.21.1 and 4.1.1.21.2, if a standard liquid or a combination of standard liquids is

assimilated in column (5) and the design type is approved for that/those standard liquid(s).

Figure 4.1.1.21.1: Scheme for the assimilation of filling substances to standard liquids

4.1.1.21.4

Aqueous solutions

Aqueous solutions of substances and groups of substances assimilated to specific standard liquid(s) in

accordance with 4.1.1.21.3 may also be assimilated to that (those) standard liquid(s) provided the

following conditions are met:

(a) the aqueous solution can be assigned to the same UN number as the listed substance in

accordance with the criteria of 2.1.3.3, and

(b) the aqueous solution is not specifically mentioned by name otherwise in the assimilation list in

4.1.1.21.6, and

Example: Aqueous solutions of UN 1120 tert-Butanol:

- Pure tert-Butanol itself is assigned to the standard liquid "acetic acid" in the assimilation list.

- Aqueous solutions of tert-Butanol can be classified under the entry UN 1120 BUTANOLS in

accordance with 2.1.3.3, because the aqueous solution of tert-Butanol does not differ from the

entries of the pure substances relating to the class, the packing group(s) and the physical state.

Furthermore, the entry "1120 BUTANOLS" is not explicitly limited to the pure substances, and

aqueous solutions of these substances are not specifically mentioned by name otherwise in

Table A of chapter 3.2 as well as in the assimilation list.

- UN 1120 BUTANOLS do not react with water under normal conditions of carriage.

As a consequence, aqueous solutions of UN 1120 tert-Butanol may be assigned to the standard liquid

"acetic acid".

4.1.1.21.5

Rule for collective entries

For the assimilation of filling substances for which "Rule for collective entries" is indicated in column

(5), the following steps shall be taken and conditions be met (see also scheme in Figure 4.1.1.21.2):

(a) Perform the assimilation procedure for each dangerous component of the solution, mixture or

preparation in accordance with 4.1.1.21.3 taking into account the conditions in 4.1.1.21.2. In

the case of generic entries, components may be neglected, that are known to have no

damaging effect on high density polyethylene (e.g. solid pigments in UN 1263 PAINT or

PAINT RELATED MATERIAL);

(b) A solution, mixture or preparation cannot be assimilated to a standard liquid, if:

(i) the UN number and packing group of one or more of the dangerous components does

not appear in the assimilation list; or

(ii) "Rule for collective entries" is indicated in column (5) of the assimilation list for one

or more of the components; or

(iii) (with the exception of UN 2059 NITROCELLULOSE SOLUTION, FLAMMABLE)

the classification code of one or more of its dangerous components differs from that

of the solution, mixture or preparation.

in accordance with the classification code of the solution, mixture or preparation itself, and

all dangerous components are assimilated to the same standard liquid or combination of

standard liquids in column (5), the chemical compatibility of the solution, mixture or

preparation may be regarded as verified taking into account 4.1.1.21.1 and 4.1.1.21.2;

(d) If all dangerous components are listed in the assimilation list and its classification codes are

in accordance with the classification code of the solution, mixture or preparation itself, but

different standard liquids are indicated in column (5), the chemical compatibility may only

be regarded as verified for the following combinations of standard liquids taking into

account 4.1.1.21.1 and 4.1.1.21.2:

(i) water/nitric acid 55%; with the exception of inorganic acids with the classification

code C1, which are assigned to standard liquid "water";

(ii) water/wetting solution;

(iii) water/acetic acid;

(iv) water/mixture of hydrocarbons;

(v) water/n-butyl acetate – n-butyl acetate-saturated wetting solution;

(e) In the scope of this rule, chemical compatibility is not regarded as verified for other

combinations of standard liquids than those specified in (d) and for all cases specified in (b).

In such cases the chemical compatibility shall be verified by other means (see 4.1.1.21.3 (d)).

Example 1: Mixture of UN 1940 THIOGLYCOLIC ACID (50%) and UN 2531 METHACRYLIC

ACID, STABILIZED (50%); classification of the mixture: UN 3265 CORROSIVE LIQUID, ACIDIC,

ORGANIC, N.O.S.

- Both the UN numbers of the components and the UN number of the mixture are included in the

assimilation list;

- Both the components and the mixture have the same classification code: C3;

- UN 1940 THIOGLYCOLIC ACID is assimilated to standard liquid "acetic acid", and UN 2531

METHACRYLIC ACID, STABILIZED is assimilated to standard liquid "n-butyl acetate/n-butyl

acetate-saturated wetting solution". According to paragraph (d) this is not an acceptable

combination of standard liquids. The chemical compatibility of the mixture has to be verified

by other means.

Example 2: Mixture of UN 1793 ISOPROPYL ACID PHOSPHATE (50%) and UN 1803

PHENOLSULPHONIC ACID, LIQUID (50%); classification of the mixture: UN 3265 CORROSIVE

LIQUID, ACIDIC, ORGANIC, N.O.S.

- Both the UN numbers of the components and the UN number of the mixture are included in the

assimilation list;

- Both the components and the mixture have the same classification code: C3;

- UN 1793 ISOPROPYL ACID PHOSPHATE is assimilated to standard liquid "wetting

solution", and UN 1803 PHENOLSULPHONIC ACID, LIQUID is assimilated to standard

liquid "water". According to paragraph (d) this is one of the acceptable combinations of

standard liquids. As a consequence the chemical compatibility may be regarded as verified for

this mixture, provided the packaging design type is approved for the standard liquids "wetting

solution" and "water".

Acceptable combinations of standard liquids:

- water/nitric acid (55%), with the exception of inorganic acids of classification code C1 which are assigned to

standard liquid "water";

- water/wetting solution;

- water/acetic acid;

- water/mixture of hydrocarbons;

- water/n-butyl acetate – n-butyl acetate saturated wetting solution

4.1.1.21.6

Assimilation list

In the following table (assimilation list) dangerous substances are listed in the numerical order of their

UN numbers. As a rule, each line deals with a dangerous substance, single entry or collective entry

covered by a specific UN number. However, several consecutive lines may be used for the same UN

number, if substances belonging to the same UN number have different names (e.g. individual

isomers of a group of substances), different chemical properties, different physical properties and/or

different transport conditions. In such cases the single entry or collective entry within the particular

packing group is the last one of such consecutive lines.

Columns (1) to (4) of table 4.1.1.21.6, following a structure similar to that of Table A of Chapter 3.2,

are used to identify the substance for the purpose of this sub-section. The last column indicates the

standard liquid(s) to which the substance can be assimilated.

Explanatory notes for each column:

Column (1) UN No.

Contains the UN number:

- of the dangerous substance, if the substance has been assigned its own specific UN number, or

- of the collective entry to which dangerous substances not listed by name have been assigned in

accordance with the criteria ("decision trees") of Part 2.

Column (2a) Proper shipping name or technical name

Contains the name of the substance, the name of the single entry, which may cover various isomers,

or the name of the collective entry itself.

The indicated name can deviate from the applicable proper shipping name.

Column (2b) Description

Contains a descriptive text to clarify the scope of the entry in those cases when the classification, the

transport conditions and/or the chemical compatibility of the substance may be variable.

Column (3a) Class

Contains the number of the class, whose heading covers the dangerous substance. This class number

is assigned in accordance with the procedures and criteria of Part 2.

Column (3b) Classification code

Contains the classification code of the dangerous substance in accordance with the procedures and

criteria of Part 2.

Column (4) Packing group

Contains the packing group number(s) (I, II or III) assigned to the dangerous substance in accordance

with the procedures and criteria of Part 2. Certain substances are not assigned to packing groups.

Column (5) Standard liquid

This column indicates, as definite information, either a standard liquid or a combination of standard

liquids to which the substance can be assimilated, or a reference to the rule for collective entries in

4.1.1.21.5.

Table 4.1.1.21.6: Assimilation list

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
1090	Acetone		3	F1	II	Mixture of hydrocarbons Remark: applicable only, if it is proved that the permeability of the substance out of the package intended for carriage has an acceptable level
1093	Acrylonitrile, stabilized		3	FT1	I	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1104	Amyl acetates	pure isomers and isomeric mixture	3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1105	Pentanols	pure isomers and isomeric mixture	3	F1	II/III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1106	Amylamines	pure isomers and isomeric mixture	3	FC	II/III	Mixture of hydrocarbons and wetting solution
1109	Amyl formates	pure isomers and isomeric mixture	3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1120	Butanols	pure isomers and isomeric mixture	3	F1	II/III	Acetic acid
1123	Butyl acetates	pure isomers and isomeric mixture	3	F1	II/III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1125	n-Butylamine		3	FC	II	Mixture of hydrocarbons and wetting solution
1128	n-Butyl formate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1129	Butyraldehyde		3	F1	II	Mixture of hydrocarbons
1133	Adhesives	containing flammable liquid	3	F1	I/II/III	Rule for collective entries
1139	Coating solution	includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining	3	F1	I/II/III	Rule for collective entries
1145	Cyclohexane		3	F1	II	Mixture of hydrocarbons
1146	Cyclopentane		3	F1	II	Mixture of hydrocarbons
1153	Ethylene glycol diethyl ether		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
1154	Diethylamine		3	FC	II	Mixture of hydrocarbons and wetting solution
1158	Diisopropylamine		3	FC	II	Mixture of hydrocarbons and wetting solution

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
1160	Dimethylamine aqueous solution		3	FC	II	Mixture of hydrocarbons and wetting solution
1165	Dioxane		3	F1	II	Mixture of hydrocarbons
1169	Extracts, aromatic, liquid		3	F1	II/III	Rule for collective entries
1170	Ethanol or Ethanol solution	aqueous solution	3	F1	II/III	Acetic acid
1171	Ethylene glycol monoethyl ether		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
1172	Ethylene glycol monoethyl ether acetate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
1173	Ethyl acetate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1177	2-Ethylbutyl acetate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1178	2-Ethylbutyraldehyde		3	F1	II	Mixture of hydrocarbons
1180	Ethyl butyrate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1188	Ethylene glycol monomethyl ether		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
1189	Ethylene glycol monomethyl ether acetate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
1190	Ethyl formate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1191	Octyl aldehydes	pure isomers and isomeric mixture	3	F1	III	Mixture of hydrocarbons
1192	Ethyl lactate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1195	Ethyl propionate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1197	Extracts, flavouring, liquid		3	F1	II/III	Rule for collective entries
1198	Formaldehyde solution, flammable	aqueous solution, flashpoint between 23 °C and 60 °C	3	FC	III	Acetic acid
1202	Diesel fuel	complying with EN 590:2013 + AC:2014 or with a flashpoint not more than 100 °C	3	F1	III	Mixture of hydrocarbons

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
1202	Gas oil	flashpoint not more than 100 °C	3	F1	III	Mixture of hydrocarbons
1202	Heating oil, light	extra light	3	F1	III	Mixture of hydrocarbons
1202	Heating oil, light	complying with EN 590:2013 + AC:2014 or with a flashpoint not more than 100 °C	3	F1	III	Mixture of hydrocarbons
1203	Motor spirit, or gasoline, or petrol		3	F1	II	Mixture of hydrocarbons
1206	Heptanes	pure isomers and isomeric mixture	3	F1	II	Mixture of hydrocarbons
1207	Hexaldehyde	n-Hexaldehyde	3	F1	III	Mixture of hydrocarbons
1208	Hexanes	pure isomers and isomeric mixture	3	F1	II	Mixture of hydrocarbons
1210	Printing ink or Printing ink related material	flammable, including printing ink thinning or reducing compound	3	F1	I/II/III	Rule for collective entries
1212	Isobutanol		3	F1	III	Acetic acid
1213	Isobutyl acetate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1214	Isobutylamine		3	FC	II	Mixture of hydrocarbons and wetting solution
1216	Isooctenes	pure isomers and isomeric mixture	3	F1	II	Mixture of hydrocarbons
1219	Isopropanol		3	F1	II	Acetic acid
1220	Isopropyl acetate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1221	Isopropylamine		3	FC	I	Mixture of hydrocarbons and wetting solution
1223	Kerosene		3	F1	III	Mixture of hydrocarbons
1224	3,3-Dimethyl-2-butanone		3	F1	II	Mixture of hydrocarbons
1224	Ketones, liquid, n.o.s.		3	F1	II/III	Rule for collective entries
1230	Methanol		3	FT1	II	Acetic acid
1231	Methyl acetate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1233	Methylamyl acetate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1235	Methylamine, aqueous solution		3	FC	II	Mixture of hydrocarbons and wetting solution
1237	Methyl butyrate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1247	Methyl methacrylate monomer, stabilized		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1248	Methyl propionate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
1262	Octanes	pure isomers and isomeric mixture	3	F1	II	Mixture of hydrocarbons
1263	Paint or Paint related material	including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base or including paint thinning and reducing compound	3	F1	I/II/III	Rule for collective entries
1265	Pentanes	n-Pentane	3	F1	II	Mixture of hydrocarbons
1266	Perfumery products	with flammable solvents	3	F1	II/III	Rule for collective entries
1268	Coal tar naphtha	vapour pressure at 50 °C not more than 110 kPa	3	F1	II	Mixture of hydrocarbons
1268	Petroleum distillates, n.o.s. or Petroleum products, n.o.s.		3	F1	I/II/III	Rule for collective entries
1274	n-Propanol		3	F1	II/III	Acetic acid
1275	Propionaldehyde		3	F1	II	Mixture of hydrocarbons
1276	n-Propyl acetate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1277	Propylamine	n-Propylamine	3	FC	II	Mixture of hydrocarbons and wetting solution
1281	Propyl formates	pure isomers and isomeric mixture	3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1282	Pyridine		3	F1	II	Mixture of hydrocarbons
1286	Rosin oil		3	F1	II/III	Rule for collective entries
1287	Rubber solution		3	F1	II/III	Rule for collective entries
1296	Triethylamine		3	FC	II	Mixture of hydrocarbons and wetting solution
1297	Trimethylamine, aqueous solution	not more than 50% trimethylamine, by mass	3	FC	I/II/III	Mixture of hydrocarbons and wetting solution
1301	Vinyl acetate, stabilized		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1306	Wood preservatives, liquid		3	F1	II/III	Rule for collective entries
1547	Aniline		6.1	T1	II	Acetic acid
1590	Dichloroanilines, liquid	pure isomers and isomeric mixture	6.1	T1	II	Acetic acid
1602	Dye, liquid, toxic, n.o.s. or Dye intermediate, liquid, toxic, n.o.s.		6.1	T1	I/II/III	Rule for collective entries
1604	Ethylenediamine		8	CF1	II	Mixture of hydrocarbons and wetting solution
1715	Acetic anhydride		8	CF1	II	Acetic acid

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
1717	Acetyl chloride		3	FC	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1718	Butyl acid phosphate		8	C3	III	Wetting solution
1719	Hydrogen sulphide	aqueous solution	8	C5	III	Acetic acid
1719	Caustic alkali liquid, n.o.s.	inorganic	8	C5	II/III	Rule for collective entries
1730	Antimony pentachloride, liquid	pure	8	C1	II	Water
1736	Benzoyl chloride		8	C3	II	Mixture of hydrocarbons and wetting solution
1750	Chloroacetic acid solution	aqueous solution	6.1	TC1	II	Acetic acid
1750	Chloroacetic acid solution	mixtures of mono- and dichloroacetic acid	6.1	TC1	II	Acetic acid
1752	Chloroacetyl chloride		6.1	TC1	I	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1755	Chromic acid solution	aqueous solution with not more than 30% chromic acid	8	C1	II/III	Nitric acid
1760	Cyanamide	aqueous solution with not more than 50% cyanamide	8	C9	II	Water
1760	O,O-Diethyl- dithiophosphoric acid		8	C9	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1760	O,O-Diisopropyl- dithiophosphoric acid		8	C9	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1760	O,O-Di-n-propyl- dithiophosphoric acid		8	C9	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1760	Corrosive liquid, n.o.s.	flashpoint more than 60 °C	8	C9	I/II/III	Rule for collective entries
1761	Cupriethylenediamine solution	aqueous solution	8	CT1	II/III	Mixture of hydrocarbons and wetting solution
1764	Dichloroacetic acid		8	C3	II	Acetic acid
1775	Fluoroboric acid	aqueous solution with not more than 50% fluoroboric acid	8	C1	II	Water
1778	Fluorosilicic acid		8	C1	II	Water
1779	Formic acid	with more than 85% acid by mass	8	C3	II	Acetic acid
1783	Hexamethylenediamine solution	aqueous solution	8	C7	II/III	Mixture of hydrocarbons and wetting solution
1787	Hydriodic acid	aqueous solution	8	C1	II/III	Water
1788	Hydrobromic acid	aqueous solution	8	C1	II/III	Water
1789	Hydrochloric acid	not more than 38% aqueous solution	8	C1	II/III	Water
1790	Hydrofluoric acid	with not more than 60% hydrofluoric acid	8	CT1	II	Water the permissible period of use: not more than 2 years
1791	Hypochlorite solution	aqueous solution, containing wetting agents as customary in trade	8	C9	II/III	Nitric acid and wetting solution *

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
1791	Hypochlorite solution	aqueous solution	8	C9	II/III	Nitric acid *
* For UN 1791: Test to be carried out only with vent. If the test is carried out with nitric acid as the standard liquid, an acid-resistant vent and gasket shall be used. If the test is carried out with hypochlorite solutions themselves, vents and gaskets of the same design type, resistant to hypochlorite (e.g. of silicone rubber) but not resistant to nitric acid, are also permitted.
1793	Isopropyl acid phosphate		8	C3	III	Wetting solution
1802	Perchloric acid	aqueous solution with not more than 50% acid, by mass	8	CO1	II	Water
1803	Phenolsulphonic acid, liquid	isomeric mixture	8	C3	II	Water
1805	Phosphoric acid, solution		8	C1	III	Water
1814	Potassium hydroxide solution	aqueous solution	8	C5	II/III	Water
1824	Sodium hydroxide solution	aqueous solution	8	C5	II/III	Water
1830	Sulphuric acid	with more than 51% pure acid	8	C1	II	Water
1832	Sulphuric acid, spent	chemical stable	8	C1	II	Water
1833	Sulphurous acid		8	C1	II	Water
1835	Tetramethylammonium hydroxide, solution	aqueous solution, flashpoint more than 60 °C	8	C7	II	Water
1840	Zinc chloride solution	aqueous solution	8	C1	III	Water
1848	Propionic acid	with not less than 10% and less than 90% acid by mass	8	C3	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1862	Ethyl crotonate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1863	Fuel, aviation, turbine engine		3	F1	I/II/III	Mixture of hydrocarbons
1866	Resin solution	flammable	3	F1	I/II/III	Rule for collective entries
1902	Diisooctyl acid phosphate		8	C3	III	Wetting solution
1906	Sludge acid		8	C1	II	Nitric acid
1908	Chlorite solution	aqueous solution	8	C9	II/III	Acetic acid
1914	Butyl propionates		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1915	Cyclohexanone		3	F1	III	Mixture of hydrocarbons
1917	Ethyl acrylate, stabilized		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1919	Methyl acrylate, stabilized		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1920	Nonanes	pure isomers and isomeric mixture, flashpoint between 23 °C and 60 °C	3	F1	III	Mixture of hydrocarbons
1935	Cyanide solution, n.o.s.	inorganic	6.1	T4	I/II/III	Water
1940	Thioglycolic acid		8	C3	II	Acetic acid
1986	Alcohols, flammable, toxic, n.o.s.		3	FT1	I/II/III	Rule for collective entries
1987	Cyclohexanol	technical pure	3	F1	III	Acetic acid
1987	Alcohols, n.o.s.		3	F1	II/III	Rule for collective entries
1988	Aldehydes, flammable, toxic, n.o.s.		3	FT1	I/II/III	Rule for collective entries

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
1989	Aldehydes, n.o.s.		3	F1	I/II/III	Rule for collective entries
1992	2,6-cis-Dimethyl- morpholine		3	FT1	III	Mixture of hydrocarbons
1992	Flammable liquid, toxic, n.o.s.		3	FT1	I/II/III	Rule for collective entries
1993	Propionic acid vinyl ester		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1993	(1-Methoxy-2-propyl) acetate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
1993	Flammable liquid, n.o.s.		3	F1	I/II/III	Rule for collective entries
2014	Hydrogen peroxide, aqueous solution	with not less than 20% but not more than 60% hydrogen peroxide, stabilized as necessary	5.1	OC1	II	Nitric acid
2022	Cresylic acid	liquid mixture containing cresols, xylenols and methyl phenols	6.1	TC1	II	Acetic acid
2030	Hydrazine aqueous solution	with not less than 37% but not more than 64% hydrazine, by mass	8	CT1	II	Water
2030	Hydrazine hydrate	aqueous solution with 64% hydrazine	8	CT1	II	Water
2031	Nitric acid	other than red fuming, with not more than 55% pure acid	8	CO1	II	Nitric acid
2045	Isobutyraldehyde		3	F1	II	Mixture of hydrocarbons
2050	Diisobutylene isomeric compounds		3	F1	II	Mixture of hydrocarbons
2053	Methyl isobutyl carbinol		3	F1	III	Acetic acid
2054	Morpholine		8	CF1	I	Mixture of hydrocarbons
2057	Tripropylene		3	F1	II/III	Mixture of hydrocarbons
2058	Valeraldehyde	pure isomers and isomeric mixture	3	F1	II	Mixture of hydrocarbons
2059	Nitrocellulose solution, flammable		3	D	I/II/III	Rule for collective entries: Deviating from the general procedure this rule may be applied to solvents of classification code F1
2075	Chloral, anhydrous, stabilized		6.1	T1	II	Wetting solution
2076	Cresols, liquid	pure isomers and isomeric mixture	6.1	TC1	II	Acetic acid
2078	Toluene diisocyanate	liquid	6.1	T1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2079	Diethylenetriamine		8	C7	II	Mixture of hydrocarbons
2209	Formaldehyde solution	aqueous solution with 37% Form-aldehyde, methanol content: 8-10%	8	C9	III	Acetic acid
2209	Formaldehyde solution	aqueous solution, with not less than 25% formaldehyde	8	C9	III	Water
2218	Acrylic acid, stabilized		8	CF1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
2227	n-Butyl methacrylate, stabilized		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2235	Chlorobenzyl chlorides, liquid	para-Chlorobenzyl chloride	6.1	T2	III	Mixture of hydrocarbons
2241	Cycloheptane		3	F1	II	Mixture of hydrocarbons
2242	Cycloheptene		3	F1	II	Mixture of hydrocarbons
2243	Cyclohexyl acetate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2244	Cyclopentanol		3	F1	III	Acetic acid
2245	Cyclopentanone		3	F1	III	Mixture of hydrocarbons
2247	n-Decane		3	F1	III	Mixture of hydrocarbons
2248	Di-n-butylamine		8	CF1	II	Mixture of hydrocarbons
2258	1,2-Propylenediamine		8	CF1	II	Mixture of hydrocarbons and wetting solution
2259	Triethylenetetramine		8	C7	II	Water
2260	Tripropylamine		3	FC	III	Mixture of hydrocarbons and wetting solution
2263	Dimethylcyclohexanes	pure isomers and isomeric mixture	3	F1	II	Mixture of hydrocarbons
2264	N,N-Dimethyl- cyclohexylamine		8	CF1	II	Mixture of hydrocarbons and wetting solution
2265	N,N-Dimethyl-formamide		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2266	Dimethyl-N-propylamine		3	FC	II	Mixture of hydrocarbons and wetting solution
2269	3,3'-Imino-dipropylamine		8	C7	III	Mixture of hydrocarbons and wetting solution
2270	Ethylamine, aqueous solution	with not less than 50% but not more than 70% ethylamine, flashpoint below 23 °C, corrosive or slightly corrosive	3	FC	II	Mixture of hydrocarbons and wetting solution
2275	2-Ethylbutanol		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2276	2-Ethylhexylamine		3	FC	III	Mixture of hydrocarbons and wetting solution
2277	Ethyl methacrylate, stabilized		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2278	n-Heptene		3	F1	II	Mixture of hydrocarbons
2282	Hexanols	pure isomers and isomeric mixture	3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2283	Isobutyl methacrylate, stabilized		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
2286	Pentamethylheptane		3	F1	III	Mixture of hydrocarbons
2287	Isoheptenes		3	F1	II	Mixture of hydrocarbons
2288	Isohexenes		3	F1	II	Mixture of hydrocarbons
2289	Isophoronediamine		8	C7	III	Mixture of hydrocarbons and wetting solution
2293	4-Methoxy-4-methyl- pentan-2-one		3	F1	III	Mixture of hydrocarbons
2296	Methylcyclohexane		3	F1	II	Mixture of hydrocarbons
2297	Methylcyclohexanone	pure isomers and isomeric mixture	3	F1	III	Mixture of hydrocarbons
2298	Methylcyclopentane		3	F1	II	Mixture of hydrocarbons
2302	5-Methylhexan-2-one		3	F1	III	Mixture of hydrocarbons
2308	Nitrosylsulphuric acid, liquid		8	C1	II	Water
2309	Octadienes		3	F1	II	Mixture of hydrocarbons
2313	Picolines	pure isomers and isomeric mixture	3	F1	III	Mixture of hydrocarbons
2317	Sodium cuprocyanide solution	aqueous solution	6.1	T4	I	Water
2320	Tetraethylenepentamine		8	C7	III	Mixture of hydrocarbons and wetting solution
2324	Triisobutylene	mixture of C12-mono- olefines, flashpoint between 23 °C and 60 °C	3	F1	III	Mixture of hydrocarbons
2326	Trimethyl- cyclohexylamine		8	C7	III	Mixture of hydrocarbons and wetting solution
2327	Trimethylhexamethylene- diamines	pure isomers and isomeric mixture	8	C7	III	Mixture of hydrocarbons and wetting solution
2330	Undecane		3	F1	III	Mixture of hydrocarbons
2336	Allyl formate		3	FT1	I	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2348	Butyl acrylates, stabilized	pure isomers and isomeric mixture	3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2357	Cyclohexylamine	flashpoint between 23 °C and 60 °C	8	CF1	II	Mixture of hydrocarbons and wetting solution
2361	Diisobutylamine		3	FC	III	Mixture of hydrocarbons and wetting solution
2366	Diethyl carbonate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2367	alpha-Methyl- valeraldehyde		3	F1	II	Mixture of hydrocarbons
2370	1-Hexene		3	F1	II	Mixture of hydrocarbons
2372	1,2-Di-(dimethylamino)- ethane		3	F1	II	Mixture of hydrocarbons and wetting solution

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
2379	1,3-Dimethylbutylamine		3	FC	II	Mixture of hydrocarbons and wetting solution
2383	Dipropylamine		3	FC	II	Mixture of hydrocarbons and wetting solution
2385	Ethyl isobutyrate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2393	Isobutyl formate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2394	Isobutyl propionate	flashpoint between 23 °C and 60 °C	3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2396	Methacrylaldehyde, stabilized		3	FT1	II	Mixture of hydrocarbons
2400	Methyl isovalerate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2401	Piperidine		8	CF1	I	Mixture of hydrocarbons and wetting solution
2403	Isopropenyl acetate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2405	Isopropyl butyrate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2406	Isopropyl isobutyrate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2409	Isopropyl propionate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2410	1,2,3,6-Tetrahydro- pyridine		3	F1	II	Mixture of hydrocarbons
2427	Potassium chlorate, aqueous solution		5.1	O1	II/III	Water
2428	Sodium chlorate, aqueous solution		5.1	O1	II/III	Water
2429	Calcium chlorate, aqueous solution		5.1	O1	II/III	Water
2436	Thioacetic acid		3	F1	II	Acetic acid
2457	2,3-Dimethylbutane		3	F1	II	Mixture of hydrocarbons
2491	Ethanolamine		8	C7	III	Wetting solution
2491	Ethanolamine solution	aqueous solution	8	C7	III	Wetting solution
2496	Propionic anhydride		8	C3	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2524	Ethyl orthoformate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2526	Furfurylamine		3	FC	III	Mixture of hydrocarbons and wetting solution

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
2527	Isobutyl acrylate, stabilized		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2528	Isobutyl isobutyrate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2529	Isobutyric acid		3	FC	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2531	Methacrylic acid, stabilized		8	C3	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2542	Tributylamine		6.1	T1	II	Mixture of hydrocarbons
2560	2-Methylpentan-2-ol		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2564	Trichloroacetic acid solution	aqueous solution	8	C3	II/III	Acetic acid
2565	Dicyclohexylamine		8	C7	III	Mixture of hydrocarbons and wetting solution
2571	Ethylsulphuric acid		8	C3	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2571	Alkylsulphuric acids		8	C3	II	Rule for collective entries
2580	Aluminium bromide solution	aqueous solution	8	C1	III	Water
2581	Aluminium chloride solution	aqueous solution	8	C1	III	Water
2582	Ferric chloride solution	aqueous solution	8	C1	III	Water
2584	Methane sulphonic acid	with more than 5% free sulphuric acid	8	C1	II	Water
2584	Alkylsulphonic acids, liquid	with more than 5% free sulphuric acid	8	C1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2584	Benzene sulphonic acid	with more than 5% free sulphuric acid	8	C1	II	Water
2584	Toluene sulphonic acids	with more than 5% free sulphuric acid	8	C1	II	Water
2584	Arylsulphonic acids, liquid	with more than 5% free sulphuric acid	8	C1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2586	Methane sulfonic acid	with not more than 5% free sulphuric acid	8	C1	III	Water
2586	Alkylsulphonic acids, liquid	with not more than 5% free sulphuric acid	8	C1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2586	Benzene sulphonic acid	with not more than 5% free sulphuric acid	8	C1	III	Water
2586	Toluene sulphonic acids	with not more than 5% free sulphuric acid	8	C1	III	Water
2586	Arylsulphonic acids, liquid	with not more than 5% free sulphuric acid	8	C1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2610	Triallylamine		3	FC	III	Mixture of hydrocarbons and wetting solution

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
2614	Methallyl alcohol		3	F1	III	Acetic acid
2617	Methylcyclohexanols	pure isomers and isomeric mixture, flashpoint between 23 °C and 60 °C	3	F1	III	Acetic acid
2619	Benzyldimethylamine		8	CF1	II	Mixture of hydrocarbons and wetting solution
2620	Amyl butyrates	pure isomers and isomeric mixture, flashpoint between 23 °C and 60 °C	3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2622	Glycidaldehyde	flashpoint below 23 °C	3	FT1	II	Mixture of hydrocarbons
2626	Chloric acid, aqueous solution	with not more than 10% chloric acid	5.1	O1	II	Nitric acid
2656	Quinoline	flashpoint more than 60 °C	6.1	T1	III	Water
2672	Ammonia solution	relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia	8	C5	III	Water
2683	Ammonium sulphide solution	aqueous solution, flashpoint between 23 °C and 60 °C	8	CFT	II	Acetic acid
2684	3-Diethylamino- propylamine		3	FC	III	Mixture of hydrocarbons and wetting solution
2685	N,N-Diethylethylene- diamine		8	CF1	II	Mixture of hydrocarbons and wetting solution
2693	Bisulphites, aqueous solution, n.o.s.	inorganic	8	C1	III	Water
2707	Dimethyldioxanes	pure isomers and isomeric mixture	3	F1	II/III	Mixture of hydrocarbons
2733	Amines, flammable, corrosive , n.o.s. or Polyamines, flammable, corrosive, n.o.s.		3	FC	I/II/III	Mixture of hydrocarbons and wetting solution
2734	Di-sec-butylamine		8	CF1	II	Mixture of hydrocarbons
2734	Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s.		8	CF1	I/II	Mixture of hydrocarbons and wetting solution
2735	Amines, liquid, corrosive, n.o.s. or Polyamines, liquid, corrosive, n.o.s.		8	C7	I/II/III	Mixture of hydrocarbons and wetting solution
2739	Butyric anhydride		8	C3	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2789	Acetic acid, glacial or Acetic acid solution	aqueous solution, more than 80% acid, by mass	8	CF1	II	Acetic acid
2790	Acetic acid solution	aqueous solution, more than 10% but not more than 80% acid, by mass	8	C3	II/III	Acetic acid

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
2796	Sulphuric acid	with not more than 51% pure acid	8	C1	II	Water
2797	Battery fluid, alkali	Potassium/Sodium hydroxide, aqueous solution	8	C5	II	Water
2810	2-Chloro-6-fluorobenzyl chloride	stabilized	6.1	T1	III	Mixture of hydrocarbons
2810	2-Phenylethanol		6.1	T1	III	Acetic acid
2810	Ethylene glycol monohexyl ether		6.1	T1	III	Acetic acid
2810	Toxic liquid, organic, n.o.s.		6.1	T1	I/II/III	Rule for collective entries
2815	N-Aminoethylpiperazine		8	CT1	III	Mixture of hydrocarbons and wetting solution
2818	Ammonium polysulphide solution	aqueous solution	8	CT1	II/III	Acetic acid
2819	Amyl acid phosphate		8	C3	III	Wetting solution
2820	Butyric acid	n-Butyric acid	8	C3	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2821	Phenol solution	aqueous solution, toxic, non- alkaline	6.1	T1	II/III	Acetic acid
2829	Caproic acid	n-Caproic acid	8	C3	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2837	Bisulphates, aqueous solution		8	C1	II/III	Water
2838	Vinyl butyrate, stabilized		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2841	Di-n-amylamine		3	FT1	III	Mixture of hydrocarbons and wetting solution
2850	Propylene tetramer	mixture of C12- monoolefines, flashpoint between 23 °C and 60 °C	3	F1	III	Mixture of hydrocarbons
2873	Dibutylaminoethanol	N,N-Di-n- butylaminoethanol	6.1	T1	III	Acetic acid
2874	Furfuryl alcohol		6.1	T1	III	Acetic acid
2920	O,O-Diethyl- dithiophosphoric acid	flashpoint between 23 °C and 60 °C	8	CF1	II	n-Butylacetate/ n-Butylacetate-saturated wetting solution
2920	O,O-Dimethyl- dithiophosphoric acid	flashpoint between 23 °C and 60 °C	8	CF1	II	Wetting solution
2920	Hydrogen bromide	33% solution in glacial acetic acid	8	CF1	II	Wetting solution
2920	Tetramethylammonium hydroxide	aqueous solution, flashpoint between 23 °C and 60 °C	8	CF1	II	Water
2920	Corrosive liquid, flammable, n.o.s.		8	CF1	I/II	Rule for collective entries
2922	Ammonium sulphide	aqueous solution, flashpoint more than 60 °C	8	CT1	II	Water
2922	Cresols	aqueous alkaline solution, mixture of sodium and potassium cresolate,	8	CT1	II	Acetic acid

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
2922	Phenol	aqueous alkaline solution, mixture of sodium and potassium phenolate	8	CT1	II	Acetic acid
2922	Sodium hydrogen difluoride	aqueous solution	8	CT1	III	Water
2922	Corrosive liquid, toxic, n.o.s.		8	CT1	I/II/III	Rule for collective entries
2924	Flammable liquid, corrosive, n.o.s.	slightly corrosive	3	FC	I/II/III	Rule for collective entries
2927	Toxic liquid, corrosive, organic, n.o.s.		6.1	TC1	I/II	Rule for collective entries
2933	Methyl 2-chloro- propionate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2934	Isopropyl 2-chloro- propionate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2935	Ethyl 2-chloropropionate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2936	Thiolactic acid		6.1	T1	II	Acetic acid
2941	Fluoroanilines	pure isomers and isomeric mixture	6.1	T1	III	Acetic acid
2943	Tetrahydrofurfurylamine		3	F1	III	Mixture of hydrocarbons
2945	N-Methylbutylamine		3	FC	II	Mixture of hydrocarbons and wetting solution
2946	2-Amino-5-diethyl- aminopentane		6.1	T1	III	Mixture of hydrocarbons and wetting solution
2947	Isopropyl chloroacetate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
2984	Hydrogen peroxide, aqueous solution	with not less than 8% but less than 20% hydrogen peroxide, stabilized as necessary	5.1	O1	III	Nitric acid
3056	n-Heptaldehyde		3	F1	III	Mixture of hydrocarbons
3065	Alcoholic beverages	with more than 24% alcohol by volume	3	F1	II/III	Acetic acid
3066	Paint or Paint related material	including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base or including paint thinning and reducing compound	8	C9	II/III	Rule for collective entries
3079	Methacrylonitrile, stabilized		6.1	TF1	I	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3082	sec-Alcohol C6-C17 poly (3-6) ethoxylate		9	M6	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
3082	Alcohol C12-C15 poly (1-3) ethoxylate		9	M6	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
3082	Alcohol C13-C15 poly (1-6) ethoxylate		9	M6	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
3082	Aviation turbine fuel JP-5	flashpoint more than 60 °C	9	M6	III	Mixture of hydrocarbons
3082	Aviation turbine fuel JP-7	flashpoint more than 60 °C	9	M6	III	Mixture of hydrocarbons
3082	Coal tar	flashpoint more than 60 °C	9	M6	III	Mixture of hydrocarbons
3082	Coal tar naphtha	flashpoint more than 60 °C	9	M6	III	Mixture of hydrocarbons
3082	Creosote produced of coal tar	flashpoint more than 60 °C	9	M6	III	Mixture of hydrocarbons
3082	Creosote produced of wood tar	flashpoint more than 60 °C	9	M6	III	Mixture of hydrocarbons
3082	Cresyl diphenyl phosphate		9	M6	III	Wetting solution
3082	Decyl acrylate		9	M6	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
3082	Diisobutyl phthalate		9	M6	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
3082	Di-n-butyl phthalate		9	M6	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons
3082	Hydrocarbons	liquid, flashpoint more than 60 °C, environmentally hazardous	9	M6	III	Rule for collective entries
3082	Isodecyl diphenyl phosphate		9	M6	III	Wetting solution
3082	Methylnaphthalenes	isomeric mixture, liquid	9	M6	III	Mixture of hydrocarbons
3082	Triaryl phosphates	n.o.s.	9	M6	III	Wetting solution
3082	Tricresyl phosphate	with not more than 3% ortho-isomer	9	M6	III	Wetting solution
3082	Trixylenyl phosphate		9	M6	III	Wetting solution
3082	Zinc alkyl dithiophosphate	C3-C14	9	M6	III	Wetting solution
3082	Zinc aryl dithiophosphate	C7-C16	9	M6	III	Wetting solution
3082	Environmentally hazardous substance, liquid, n.o.s.		9	M6	III	Rule for collective entries
3099	Oxidizing liquid, toxic, n.o.s.		5.1	OT1	I/II/III	Rule for collective entries

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
3101 3103 3105 3107 3109 3111 3113 3115 3117 3119	Organic Peroxide, Type B, C, D, E or F, liquid or Organic Peroxide, Type B, C, D, E or F, liquid, temperature controlled		5.2	P1		n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons and nitric acid**
** For UN Nos. 3101, 3103, 3105, 3107, 3109, 3111, 3113, 3115, 3117, 3119 (tert-butyl hydroperoxide with more than 40% peroxide content and peroxyacetic acids are excluded): All organic peroxides in a technically pure form or in solution in solvents which, as far as their compatibility is concerned, are covered by the standard liquid "mixture of hydrocarbons" in this list. Compatibility of vents and gaskets with organic peroxides may be verified, also independently of the design type test, by laboratory tests with nitric acid.
3145	Butylphenols	liquid, n.o.s.	8	C3	I/II/III	Acetic acid
3145	Alkylphenols, liquid, n.o.s.	including C2 to C12 homologues	8	C3	I/II/III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3149	Hydrogen peroxide and peroxyacetic acid mixture, stabilized	with UN 2790 acetic acid, UN 2796 sulphuric acid and/or UN 1805 phosphoric acid, water and not more than 5% peroxyacetic acid	5.1	OC1	II	Wetting solution and nitric acid
3210	Chlorates, inorganic, aqueous solution, n.o.s.		5.1	O1	II/III	Water
3211	Perchlorates, inorganic, aqueous solution, n.o.s.		5.1	O1	II/III	Water
3213	Bromates, inorganic, aqueous solution, n.o.s.		5.1	O1	II/III	Water
3214	Permanganates, inorganic, aqueous solution, n.o.s.		5.1	O1	II	Water
3216	Persulphates, inorganic, aqueous solution, n.o.s.		5.1	O1	III	Wetting solution
3218	Nitrates, inorganic, aqueous solution, n.o.s.		5.1	O1	II/III	Water
3219	Nitrites, inorganic, aqueous solution, n.o.s.		5.1	O1	II/III	Water
3264	Cupric chloride	aqueous solution, slightly corrosive	8	C1	III	Water
3264	Hydroxylamine sulphate	25% aqueous solution	8	C1	III	Water
3264	Phosphorous acid	aqueous solution	8	C1	III	Water
3264	Corrosive liquid, acidic, inorganic, n.o.s.	flashpoint more than 60 °C	8	C1	I/II/III	Rule for collective entries; not applicable to mixtures having components of UN Nos.: 1830, 1832, 1906 and 2308
3265	Methoxyacetic acid		8	C3	I	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265	Allyl succinic acid anhydride		8	C3	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265	Dithioglycolic acid		8	C3	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
3265	Butyl phosphate	mixture of mono- and di- butyl phosphate	8	C3	III	Wetting solution
3265	Caprylic acid		8	C3	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265	Isovaleric acid		8	C3	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265	Pelargonic acid		8	C3	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265	Pyruvic acid		8	C3	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265	Valeric acid		8	C3	III	Acetic acid
3265	Corrosive liquid, acidic, organic, n.o.s.	flashpoint more than 60 °C	8	C3	I/II/III	Rule for collective entries
3266	Sodium hydrosulphide	aqueous solution	8	C5	II	Acetic acid
3266	Sodium sulphide	aqueous solution, slightly corrosive	8	C5	III	Acetic acid
3266	Corrosive liquid, basic, inorganic, n.o.s.	flashpoint more than 60 °C	8	C5	I/II/III	Rule for collective entries
3267	2,2'-(Butylimino)- bisethanol		8	C7	II	Mixture of hydrocarbons and wetting solution
3267	Corrosive liquid, basic, organic, n.o.s.	flashpoint more than 60 °C	8	C7	I/II/III	Rule for collective entries
3271	Ethylene glycol monobutyl ether	flashpoint 60 °C	3	F1	III	Acetic acid
3271	Ether, n.o.s.		3	F1	II/III	Rule for collective entries
3272	Acrylic acid tert-butyl ester		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3272	Isobutyl propionate	flashpoint below 23 °C	3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3272	Methyl valerate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3272	Trimethyl ortho-formate		3	F1	II	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3272	Ethyl valerate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3272	Isobutyl isovalerate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3272	n-Amyl propionate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3272	n-Butylbutyrate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3272	Methyl lactate		3	F1	III	n-Butyl acetate/ n-butyl acetate-saturated wetting solution
3272	Ester, n.o.s.		3	F1	II/III	Rule for collective entries

UN No.	Proper shipping name or technical name	Description	Class	Classifi- cation Code	Packing group	Standard liquid
UN No.	3.1.2	3.1.2	2.2	2.2	2.1.1.3	Standard liquid
(1)	(2a)	(2b)	(3a)	(3b)	(4)	(5)
3287	Sodium nitrite	40% aqueous solution	6.1	T4	III	Water
3287	Toxic liquid, inorganic, n.o.s.		6.1	T4	I/II/III	Rule for collective entries
3291	Clinical waste, unspecified, n.o.s.	liquid	6.2	I3	II	Water
3293	Hydrazine, aqueous solution	with not more than 37% hydrazine, by mass	6.1	T4	III	Water
3295	Heptenes	n.o.s	3	F1	II	Mixture of hydrocarbons
3295	Nonanes	flashpoint below 23 °C	3	F1	II	Mixture of hydrocarbons
3295	Decanes	n.o.s	3	F1	III	Mixture of hydrocarbons
3295	1,2,3-Trimethylbenzene		3	F1	III	Mixture of hydrocarbons
3295	Hydrocarbons, liquid, n.o.s.		3	F1	I/II/III	Rule for collective entries
3405	Barium chlorate, solution	aqueous solution	5.1	OT1	II/III	Water
3406	Barium perchlorate, solution	aqueous solution	5.1	OT1	II/III	Water
3408	Lead perchlorate, solution	aqueous solution	5.1	OT1	II/III	Water
3413	Potassium cyanide, solution	aqueous solution	6.1	T4	I/II/III	Water
3414	Sodium cyanide, solution	aqueous solution	6.1	T4	I/II/III	Water
3415	Sodium fluoride, solution	aqueous solution	6.1	T4	III	Water
3422	Potassium fluoride, solution	aqueous solution	6.1	T4	III	Water

4.1.2

Additional general provisions for the use of IBCs

4.1.2.1

When IBCs are used for the carriage of liquids with a flash-point of 60 °C (closed cup) or lower, or of

powders liable to dust explosion, measures shall be taken to prevent a dangerous electrostatic

discharge.

4.1.2.2

Every metal, rigid plastics and composite IBC, shall be inspected and tested, as relevant, in

accordance with 6.5.4.4 or 6.5.4.5:

- before it is put into service;

- thereafter at intervals not exceeding two and a half and five years, as appropriate;

- after the repair or remanufacture, before it is re-used for carriage.

An IBC shall not be filled and offered for carriage after the date of expiry of the last periodic test or

inspection. However, an IBC filled prior to the date of expiry of the last periodic test or inspection

may be carried for a period not to exceed three months beyond the date of expiry of the last periodic

test or inspection. In addition, an IBC may be carried after the date of expiry of the last periodic test

or inspection:

(a) after emptying but before cleaning, for purposes of performing the required test or inspection

prior to refilling; and

(b) unless otherwise approved by the competent authority, for a period not to exceed six months

beyond the date of expiry of the last periodic test or inspection in order to allow the return of

dangerous goods or residues for proper disposal or recycling.

NOTE: For the particulars in the transport document, see 5.4.1.1.11.

4.1.2.3

IBCs of type 31HZ2 shall be filled to at least 80% of the volume of the outer casing.

4.1.2.4

Except for routine maintenance of metal, rigid plastics, composite and flexible IBCs performed by the

owner of the IBC, whose State and name or authorized symbol is durably marked on the IBC, the

party performing routine maintenance shall durably mark the IBC near the manufacturer's UN design

type mark to show:

(a) The State in which the routine maintenance was carried out; and

(b) The name or authorized symbol of the party performing the routine maintenance.

4.1.3

General provisions concerning packing instructions

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