Substances and articles not accepted for carriage

Explosive substances which are unduly sensitive according to the criteria of the Manual of Tests and Criteria, Part I, or are liable to spontaneous reaction, as well as explosive substances and articles  which cannot be assigned to a name or n.o.s. entry listed in Table A of Chapter 3.2, shall not be accepted for carriage.

Articles of compatibility group K shall not be accepted for carriage (1.2K, UN No. 0020 and 1.3K,  UN No. 0021).

List of collective entries

Classification code (see 2.2.1.1.4)

UN

No.

Name of the substance or article

1.1A

0473

SUBSTANCES, EXPLOSIVE, N.O.S.

1.1B

0461

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.

1.1C

0474

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0497

PROPELLANT, LIQUID

 

0498

PROPELLANT, SOLID

 

0462

ARTICLES, EXPLOSIVE, N.O.S.

1.1D

0475

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0463

ARTICLES, EXPLOSIVE, N.O.S.

1.1E

0464

ARTICLES, EXPLOSIVE, N.O.S.

1.1F

0465

ARTICLES, EXPLOSIVE, N.O.S.

1.1G

0476

SUBSTANCES, EXPLOSIVE, N.O.S.

1.1L

0357

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0354

ARTICLES, EXPLOSIVE, N.O.S.

1.2B

0382

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.

1.2C

0466

ARTICLES, EXPLOSIVE, N.O.S.

1.2D

0467

ARTICLES, EXPLOSIVE, N.O.S.

1.2E

0468

ARTICLES, EXPLOSIVE, N.O.S.

1.2F

0469

ARTICLES, EXPLOSIVE, N.O.S.

1.2L

0358

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0248

CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or

 

 

propelling charge

 

0355

ARTICLES, EXPLOSIVE, N.O.S.

1.3C

0132

DEFLAGRATING METAL SALTS OF AROMATIC NITRO-DERIVATIVES, N.O.S.

 

0477

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0495

PROPELLANT, LIQUID

 

0499

PROPELLANT, SOLID

 

0470

ARTICLES, EXPLOSIVE, N.O.S.

1.3G

0478

SUBSTANCES, EXPLOSIVE, N.O.S.

1.3L

0359

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0249

CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or

 

 

propelling charge

 

0356

ARTICLES, EXPLOSIVE, N.O.S.

1.4B

0350

ARTICLES, EXPLOSIVE, N.O.S.

 

0383

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.

1.4C

0479

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0501

PROPELLANT, SOLID

 

0351

ARTICLES, EXPLOSIVE, N.O.S.

1.4D

0480

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0352

ARTICLES, EXPLOSIVE, N.O.S.

1.4E

0471

ARTICLES, EXPLOSIVE, N.O.S.

1.4F

0472

ARTICLES, EXPLOSIVE, N.O.S.

 

 

Classification code (see 2.2.1.1.4)

UN

No.

Name of the substance or article

1.4G

0485

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0353

ARTICLES, EXPLOSIVE, N.O.S.

1.4S

0481

SUBSTANCES, EXPLOSIVE, N.O.S.

 

0349

ARTICLES, EXPLOSIVE, N.O.S.

 

0384

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.

1.5D

0482

SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI) N.O.S.

1.6N

0486

ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI)

 

0190

SAMPLES, EXPLOSIVE other than initiating explosive

NOTE: Division and Compatibility Group shall be defined as directed by the competent authority and according to the principles in 2.2.1.1.4.

Glossary of names

NOTE 1: The descriptions in the glossary are not intended to replace the test procedures, nor to determine the hazard classification of a substance or article of Class 1. Assignment to the correct division and a decision on whether Compatibility Group S is appropriate shall be based on testing of the product in accordance with the Manual of Tests and Criteria, Part I or by analogy with similar products which have already been tested and assigned in accordance with the procedures of the Manual of Tests and Criteria.

NOTE 2: The figures given after the names refer to the relevant UN numbers (Column 1 of Table A of Chapter 3.2). For the classification code, see 2.2.1.1.4.

AMMUNITION, ILLUMINATING, with or without burster, expelling charge or propelling charge: UN Nos. 0171, 0254, 0297

Ammunition designed to produce a single source of intense light for lighting up an area. The term includes illuminating cartridges, grenades and projectiles; and illuminating and target identification bombs.

NOTE:  The  following  articles:  CARTRIDGES,  SIGNAL;  SIGNAL  DEVICES  HAND;  SIGNALS,
DISTRESS; FLARES, AERIAL; FLARES, SURFACE are not included in this definition. They are  listed separately.

AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge: UN No. 0247

Ammunition containing liquid or gelatinous incendiary substance. Except when the incendiary substance is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge.

AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge: UN Nos. 0243, 0244

Ammunition containing white phosphorus as incendiary substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge.

AMMUNITION, INCENDIARY with or  without  burster,  expelling charge  or propelling charge:  UN Nos. 0009, 0010, 0300

Ammunition containing incendiary composition. Except when the composition is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge.

AMMUNITION, PRACTICE: UN Nos. 0362, 0488

Ammunition without a main bursting charge, containing a burster or expelling charge. Normally it also contains a fuze and a propelling charge.

NOTE: GRENADES, PRACTICE are not included in this definition. They are listed separately.

AMMUNITION, PROOF: UN No. 0363

Ammunition containing pyrotechnic substances, used to test the performance or strength of new ammunition, weapon components or assemblies.

AMMUNITION, SMOKE, WHITE PHOSPHORUS, with burster, expelling charge or propelling charge: UN Nos. 0245, 0246

Ammunition containing white phosphorus as a smoke-producing substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke.
 

AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge: UN Nos. 0015, 0016, 0303

Ammunition containing a smoke-producing substance such as chlorosulphonic acid mixture or titanium tetrachloride; or a smoke-producing pyrotechnic composition based on hexachloroethane or red phosphorus. Except when the substance is an explosive per se, the ammunition also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke.

NOTE: SIGNALS, SMOKE are not included in this definition. They are listed separately.

AMMUNITION, TEAR-PRODUCING, with burster, expelling charge or  propelling  charge:  UN Nos. 0018, 0019, 0301

Ammunition containing a tear-producing substance. It also contains one or more of the following: a pyrotechnic substance; a propelling charge with primer and igniter charge; a fuze with burster or expelling charge.

ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES EEI): UN No. 0486

Articles containing only extremely insensitive substances which demonstrate a negligible probability of accidental initiation or propagation under normal conditions of transport, and which have passed Test Series 7.

ARTICLES, PYROPHORIC: UN No. 0380

Articles which contain a pyrophoric substance (capable of spontaneous ignition when exposed to air) and an explosive substance or component. The term excludes articles containing white phosphorus.

ARTICLES, PYROTECHNIC, for technical purposes: UN Nos. 0428, 0429, 0430, 0431, 0432
Articles which contain pyrotechnic substances and are used for technical purposes such as heat generation, gas generation, theatrical effects, etc.

NOTE: The following articles: all ammunition; CARTRIDGES, SIGNAL; CUTTERS, CABLE, EXPLOSIVE; FIREWORKS; FLARES, AERIAL; FLARES, SURFACE; RELEASE DEVICES, EXPLOSIVE; RIVETS, EXPLOSIVE; SIGNAL DEVICES, HAND; SIGNALS, DISTRESS;   SIGNALS,
RAILWAY TRACK, EXPLOSIVES; SIGNALS, SMOKE are not included in this definition. They are listed separately.

BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS: UN No. 0028

Substance consisting of a pelletized form of black powder.

BLACK POWDER (GUNPOWDER), granular or as meal: UN No. 0027

Substance consisting of an intimate mixture of charcoal or other carbon and either potassium nitrate or sodium nitrate, with or without sulphur.

BOMBS, WITH FLAMMABLE LIQUID, with bursting charge: UN Nos. 0399, 0400

Articles which are dropped from aircraft, consisting of a tank filled with inflammable liquid and bursting charge.

BOMBS, PHOTO-FLASH: UN No. 0038

Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive without means of initiation or with means of initiation containing two or more effective protective features.

BOMBS, PHOTO-FLASH: UN No. 0037

Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive with means of initiation not containing two or more effective protective features.
 

BOMBS, PHOTO-FLASH: UN Nos. 0039, 0299

Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a photo-flash composition.

BOMBS with bursting charge: UN Nos. 0034; 0035

Explosive articles which are dropped from aircraft, without means of initiation or with means of initiation containing two or more effective protective features.

BOMBS with bursting charge: UN Nos. 0033, 0291

Explosive articles which are dropped from aircraft, with means of initiation not containing two or more effective protective features.

BOOSTERS WITH DETONATOR: UN Nos. 0225, 0268

Articles consisting of a charge of detonating explosive with means of initiation. They are used to increase the initiating power of detonators or detonating cord.

BOOSTERS without detonator: UN Nos. 0042, 0283

Articles consisting of a charge of detonating explosive without means of initiation. They are used to increase the initiating power of detonators or detonating cord.

BURSTERS, explosive: UN No. 0043

Articles consisting of a small charge of explosive used to open projectiles or other ammunition in order to disperse their contents.

CARTRIDGES, FLASH: UN Nos. 0049, 0050

Articles consisting of a casing, a primer and flash powder, all assembled in one piece ready for firing. CARTRIDGES FOR TOOLS, BLANK: UN No. 0014
Article, used in tools, consisting of a closed cartridge case with a centre or rim fire primer with or without a charge of smokeless or black powder but with no projectile.

CARTRIDGES FOR WEAPONS, BLANK: UN Nos. 0326, 0413, 0327, 0338, 0014

Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder but no projectile. It produces a loud noise and is used for training,  saluting, propelling charge, starter pistols, etc. The term includes ammunition, blank.

CARTRIDGES FOR WEAPONS, INERT PROJECTILE: UN Nos. 0328, 0417, 0339, 0012

Ammunition consisting of a projectile without bursting charge but with a propelling charge with or without a primer. The articles may include a tracer, provided that the predominant hazard is that of the propelling charge.

CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0006, 0321, 0412

Ammunition consisting of a projectile with a bursting charge without means of initiation or with means of initiation containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together.

CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0005, 0007, 0348

Ammunition consisting of a projectile with a bursting charge with means of initiation not containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together.
 

CARTRIDGES, OIL WELL: UN Nos. 0277, 0278

Articles consisting of a thin casing of fibreboard, metal or other material containing only propellant powder which projects a hardened projectile to perforate an oil well casing.

NOTE: CHARGES, SHAPED are not included in this definition. They are listed separately.

CARTRIDGES, POWER DEVICE: UN Nos. 0275, 0276, 0323, 0381

Articles designed to accomplish mechanical actions. They consist of a casing with a charge of deflagrating explosive and a means of ignition. The gaseous products of the deflagration produce inflation, linear or rotary motion or activate diaphragms, valves or switches or project fastening devices or extinguishing agents.

CARTRIDGES, SIGNAL: UN Nos. 0054, 0312, 0405

Articles designed to fire coloured flares or other signals from signal pistols, etc. CARTRIDGES, SMALL ARMS: UN Nos. 0417, 0339, 0012
Ammunition consisting of a cartridge case fitted with a centre or rim fire primer and containing both a propelling charge and solid projectile. They are designed to be fired in weapons of calibre not larger than 19.1 mm. Shot-gun cartridges of any calibre are included in this description.

NOTE: CARTRIDGES, SMALL ARMS, BLANK, are not included in this definition. They are listed separately. Some military small arms cartridges are not included in this definition. They are listed under CARTRIDGES FOR WEAPONS, INERT PROJECTILE.

CARTRIDGES, SMALL ARMS, BLANK: UN Nos. 0014, 0327, 0338

Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder. The cartridge cases contain no projectiles. The cartridges are designed to be fired from weapons with a calibre of at most 19.1 mm and serve to produce a loud noise and are used for training, saluting, propelling charge, starter pistols, etc.

CASES, CARTRIDGE, EMPTY, WITH PRIMER: UN Nos. 0379; 0055

Articles consisting of a cartridge case made from metal, plastics or other non-inflammable material, in which the only explosive component is the primer.

CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER: UN Nos. 0447, 0446

Articles consisting of a cartridge case made partly or entirely from nitrocellulose. CHARGES, BURSTING, PLASTICS BONDED: UN Nos. 0457, 0458, 0459, 0460
Articles consisting of a charge of detonating explosive, plastics bonded, manufactured in a specific form without a casing and without means of initiation. They are designed as components of ammunition such as warheads.

CHARGES, DEMOLITION: UN No. 0048

Articles containing a charge of a detonating explosive in a casing of fibreboard, plastics, metal or other material. The articles are without means of initiation or with means of initiation containing two or more effective protective features.

NOTE: The following articles: BOMBS; MINES; PROJECTILES are not included in this definition. They are listed separately.

CHARGES, DEPTH: UN No. 0056

Articles consisting of a charge of detonating explosive contained in a drum or projectile without means of initiation or with means of initiation containing two or more effective protective features. They are designed to detonate under water.
 

CHARGES, EXPLOSIVE, COMMERCIAL without detonator: UN Nos. 0442, 0443, 0444, 0445

Articles consisting of a charge of detonating explosive without means of initiation, used for explosive welding, jointing, forming and other metallurgical processes.

CHARGES, PROPELLING, FOR CANNON: UN Nos. 0242, 0279, 0414

Charges of propellant in any physical form for separate-loading ammunition for cannon. CHARGES, PROPELLING: UN Nos. 0271, 0272, 0415, 0491
Articles consisting of a charge of a propellant charge in any physical form, with or without a casing,  as a component of rocket motors or for reducing the drag of projectiles.

CHARGES, SHAPED, without detonator: UN Nos. 0059, 0439, 0440, 0441

Articles consisting of a casing containing a charge of detonating explosive with a cavity lined with rigid material, without means of initiation. They are designed to produce a powerful, penetrating jet effect.

CHARGES, SHAPED, FLEXIBLE, LINEAR: UN Nos. 0237, 0288

Articles consisting of a V-shaped core of a detonating explosive clad by a flexible sheath. CHARGES, SUPPLEMENTARY, EXPLOSIVE: UN No. 0060
Articles consisting of a small removable booster placed in the cavity of a projectile between the fuze and the bursting charge.

COMPONENTS, EXPLOSIVE TRAIN, N.O.S.: UN Nos. 0382, 0383, 0384, 0461

Articles containing an explosive designed to transmit detonation or deflagration within an explosive train.

CONTRIVANCES, WATER-ACTIVATED with burster, expelling  charge  or  propelling  charge: UN Nos.  0248, 0249

Articles whose functioning depends upon physico-chemical reaction of their contents with water. CORD, DETONATING, flexible: UN Nos. 0065, 0289
Article consisting of a core of detonating explosive enclosed in spun fabric and a plastics or other covering. The covering is not necessary if the spun fabric is sift-proof.

CORD (FUSE) DETONATING, metal clad: UN Nos. 0102, 0290

Article consisting of a core of detonating explosive clad by a soft metal tube with or  without protective covering.

CORD (FUSE) DETONATING, MILD EFFECT, metal clad: UN No. 0104

Article consisting of a core of detonating explosive clad by a soft metal tube with or without a protective covering. The quantity of explosive substance is so small that only a mild effect is manifested outside the cord.

CORD, IGNITER: UN No. 0066

Article consisting of textile yarns covered with black powder or another fast burning pyrotechnic composition and of a flexible protective covering; or it consists of a core of black powder surrounded by a flexible woven fabric. It burns progressively along its length with an external flame and is used  to transmit ignition from a device to a charge or primer.
 

CUTTERS, CABLE, EXPLOSIVE: UN No. 0070

Articles consisting of a knife-edged device which is driven by a small charge of deflagrating  explosive into an anvil.

DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting: UN Nos. 0360, 0361, 0500

Non-electric detonators assembled with and activated by such means as safety fuse, shock tube, flash tube or detonating cord. They may be of instantaneous design or incorporate delay elements. Detonating relays incorporating detonating cord are included.

DETONATORS, ELECTRIC for blasting: UN Nos. 0030, 0255, 0456

Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Electric detonators are activated by an electric current.

DETONATORS FOR AMMUNITION: UN Nos. 0073, 0364, 0365, 0366

Articles consisting of a small metal or plastics tube containing explosives such as lead azide, PETN or combinations of explosives. They are designed to start a detonation train.

DETONATORS, NON-ELECTRIC for blasting: UN Nos. 0029, 0267, 0455

Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Non-electric detonators are activated by such means as shock tube, flash tube, safety fuse, other igniferous device or flexible detonating cord. Detonating relays without detonating cord are included.

EXPLOSIVE, BLASTING, TYPE A: UN No. 0081

Substances consisting of liquid organic nitrates such as nitroglycerine or a mixture of such ingredients with one or more of the following: nitrocellulose; ammonium nitrate or other inorganic nitrates; aromatic nitro-derivatives, or combustible materials, such as wood-meal and aluminium powder. They may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives shall be in powdery, gelatinous or elastic form. The term includes dynamite; gelatine, blasting and gelatine dynamites.

EXPLOSIVE, BLASTING, TYPE B: UN Nos. 0082, 0331

Substances consisting of

(a)    a mixture of ammonium nitrate or other inorganic nitrates with an explosive such as trinitrotoluene, with or without other substances such as wood-meal and aluminium powder; or

(b)    a mixture of ammonium nitrate or other inorganic nitrates with other combustible substances which are not explosive ingredients. In both cases they may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates or chlorates.

EXPLOSIVE, BLASTING, TYPE C: UN No. 0083

Substances consisting of a mixture of either potassium or sodium chlorate or potassium, sodium or ammonium perchlorate with organic nitro-derivatives or combustible materials such as wood-meal or aluminium powder or a hydrocarbon. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine or similar liquid organic nitrates.

EXPLOSIVE, BLASTING, TYPE D: UN No. 0084

Substances consisting of a mixture of organic nitrated compounds and combustible materials such as hydrocarbons and aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates, chlorates and ammonium nitrate. The term generally includes plastic explosives.
 

EXPLOSIVES, BLASTING, TYPE E: UN Nos. 0241, 0332

Substances consisting of water as an essential ingredient and high proportions of ammonium nitrate or other oxidizers, some or all of which are in solution. The other constituents may include nitro-derivatives such as trinitrotoluene, hydrocarbons or aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. The term includes explosives, emulsion, explosives, slurry and explosives, watergel.

FIREWORKS: UN Nos. 0333, 0334, 0335, 0336, 0337

Pyrotechnic articles designed for entertainment.

FLARES, AERIAL: UN Nos. 0093, 0403, 0404, 0420, 0421

Articles containing pyrotechnic substances which are designed to be dropped from an aircraft to illuminate, identify, signal or warn.

FLARES, SURFACE: UN Nos. 0092, 0418, 0419

Articles containing pyrotechnic substances which are designed for use on the surface to illuminate, identify, signal or warn.

FLASH POWDER: UN Nos. 0094, 0305

Pyrotechnic substance which, when ignited, produces an intense light.

FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells: UN No. 0099

Articles consisting of a charge of detonating explosive contained in a casing without means of initiation. They are used to fracture the rock around a drill shaft to assist the flow of crude oil from the rock.

FUSE, IGNITER, tubular, metal clad: UN No. 0103

Article consisting of a metal tube with a core of deflagrating explosive. FUSE, NON-DETONATING: UN No. 0101
Article consisting of cotton yarns impregnated with fine black powder (quickmatch). It burns with an external flame and is used in ignition trains for fireworks, etc.

FUSE, SAFETY: UN No. 0105

Article consisting of a core of fine grained black powder surrounded by a flexible woven fabric with one or more protective outer coverings. When ignited, it burns at a predetermined rate without any external explosive effect.

FUZES, DETONATING: UN Nos. 0106, 0107, 0257, 0367

Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. They generally incorporate protective features.

FUZES, DETONATING with protective features: UN Nos. 0408, 0409, 0410

Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. The detonating fuze must incorporate two or more effective protective features.

FUZES, IGNITING: UN Nos. 0316, 0317, 0368

Articles with primary explosive components designed to produce a deflagration in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to start the deflagration. They generally incorporate protective features.
 

GRENADES, hand or rifle, with bursting charge: UN Nos. 0284, 0285

Articles which are designed to be thrown by hand or to be projected by a rifle. They are without means of initiation or with means of initiation containing two or more effective protective features.

GRENADES, hand or rifle, with bursting charge: UN Nos. 0292, 0293

Articles which are designed to be thrown by hand or to be projected by a rifle. They are with means of initiation not containing two or more effective protective features.

GRENADES, PRACTICE, hand or rifle: UN Nos. 0110, 0372, 0318, 0452

Articles without a main bursting charge which are designed to be thrown by hand or to be projected  by a rifle. They contain the priming device and may contain a spotting charge.

HEXOTONAL: UN No. 0393

Substance    consisting    of    an    intimate    mixture    of    cyclotrimethylene-trinitramine    (RDX), trinitrotoluene (TNT) and aluminium.

HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass: UN No. 0118

Substance consisting of an intimate mixture of cyclotrimethylene-trinitramine (RDX) and trinitrotoluene (TNT). The term includes "Composition B".

IGNITERS: UN Nos. 0121, 0314, 0315, 0325, 0454

Articles containing one or more explosive substances designed to produce a deflagration in an explosive train. They may be actuated chemically, electrically or mechanically.

NOTE: The following articles: CORD, IGNITER; FUSE, IGNITER; FUSE, NON-DETONATING; FUZES,  IGNITING;  LIGHTERS,  FUSE;  PRIMERS,  CAP  TYPE;  PRIMERS,  TUBULAR  are  not
included in this definition. They are listed separately.

JET PERFORATING GUNS, CHARGED, oil well, without detonator: UN Nos. 0124, 0494

Articles consisting of a steel tube or metallic strip, into which are inserted shaped charges connected by detonating cord, without means of initiation.

LIGHTERS, FUSE: UN No. 0131

Articles of various design actuated by friction, percussion or electricity and used to ignite a safety  fuse.

MINES with bursting charge: UN Nos. 0137, 0138

Articles consisting normally of metal or composition receptacles filled with a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes".

MINES with bursting charge: UN Nos. 0136, 0294

Articles consisting normally of metal or composition receptacles filled with a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes".

OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass: UN No. 0266

Substance consisting of an intimate mixture of cyclotetramethylene-tetranitramine (HMX) and trinitrotoluene (TNT).

OCTONAL: UN No. 0496

Substance consisting of an intimate mixture of cyclotetramethylenetetranitramine (HMX), trinitrotoluene (TNT) and aluminium.
 

PENTOLITE, dry or wetted with less than 15% water, by mass: UN No. 0151

Substance consisting of an intimate mixture  of  pentaerythrite  tetranitrate  (PETN)  and  trinitrotoluene (TNT).

POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass; POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass: UN Nos. 0433, 0159

Substance consisting of nitrocellulose impregnated with not more than 60% of nitroglycerine or other liquid organic nitrates or a mixture of these.

POWDER, SMOKELESS: UN Nos. 0160, 0161, 0509

Substance based on nitrocellulose used as propellant. The term includes propellants with a single base (nitrocellulose (NC) alone), those with a double base (such as NC and nitroglycerine/(NG)) and those with a triple base (such as NC/NG/nitroguanidine).

NOTE: Cast, pressed or bag-charges of smokeless powder are listed under CHARGES, PROPELLING or CHARGES, PROPELLING, FOR CANON.

PRIMERS, CAP TYPE: UN Nos. 0044, 0377, 0378

Articles consisting of a metal or plastics cap containing a small amount of primary explosive mixture that is readily ignited by impact. They serve as igniting elements in small arms cartridges and in percussion primers for propelling charges.

PRIMERS, TUBULAR: UN Nos. 0319, 0320, 0376

Articles consisting of a primer for ignition and an auxiliary charge of deflagrating explosive such as black powder used to ignite the propelling charge in a cartridge case for cannon, etc.

PROJECTILES, inert with tracer: UN Nos. 0345, 0424, 0425

Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm.

PROJECTILES with burster or expelling charge: UN Nos. 0346, 0347

Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials.

PROJECTILES with burster or expelling charge: UN Nos. 0426, 0427

Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials.

PROJECTILES with burster or expelling charge: UN Nos. 0434, 0435

Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm. They are used to scatter dyes for spotting or other inert materials.

PROJECTILES with bursting charge: UN Nos. 0168, 0169, 0344

Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features.

PROJECTILES with bursting charge: UN Nos. 0167, 0324

Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features.
 

PROPELLANT, LIQUID: UN Nos. 0495, 0497

Substance consisting of a deflagrating liquid explosive, used for propulsion. PROPELLANT, SOLID: UN Nos. 0498, 0499, 0501
Substance consisting of a deflagrating solid explosive, used for propulsion. RELEASE DEVICES, EXPLOSIVE: UN No. 0173
Articles consisting of a small charge of explosive with means of initiation and rods or links. They sever the rods or links to release equipment quickly.

RIVETS, EXPLOSIVE: UN No. 0174

Articles consisting of a small charge of explosive inside a metallic rivet. ROCKET MOTORS: UN Nos. 0186, 0280, 0281, 0510
Articles consisting of a charge of explosive, generally a solid propellant, contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile.

ROCKET MOTORS, LIQUID FUELLED: UN Nos. 0395, 0396

Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile.

ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge: UN Nos. 0322, 0250

Articles consisting of a hypergolic fuel contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile.

ROCKETS, LINE THROWING: UN Nos. 0238, 0240, 0453

Articles consisting of a rocket motor which is designed to extend a line. ROCKETS, LIQUID FUELLED with bursting charge: UN Nos. 0397, 0398
Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles and fitted with a warhead. The term includes guided missiles.

ROCKETS with bursting charge: UN Nos. 0181, 0182

Articles consisting of a rocket motor and a warhead without means of initiation or with means of initiation containing two or more effective protective features. The term includes guided missiles.

ROCKETS with bursting charge: UN Nos. 0180, 0295

Articles consisting of a rocket motor and a warhead with means of initiation not containing two or more effective protective features. The term includes guided missiles.

ROCKETS with expelling charge: UN Nos. 0436, 0437, 0438

Articles consisting of a rocket motor and a charge to expel the payload from a rocket head. The term includes guided missiles.

ROCKETS with inert head: UN Nos. 0183, 0502

Articles consisting of a rocket motor and an inert head. The term includes guided missiles. SAFETY DEVICES, PYROTECHNIC: UN No. 0503
Articles which contain pyrotechnic substances or dangerous goods of other classes and are used in vehicles, vessels or aircraft to enhance safety to persons. Examples are: air bag inflators, air bag
 

modules, seat-belt pretensioners and pyromechanical devices. These pyromechanical devices are assembled components for tasks such as but not limited to separation, locking, or occupant restraint.

SAMPLES, EXPLOSIVE, other than initiating explosive UN No. 0190

New or existing explosive substances or articles, not yet assigned to a name in Table A of Chapter 3.2 and carried in conformity with the instructions of the competent authority and generally in small quantities, inter alia, for the purposes of testing, classification, research and development, or quality control, or as commercial samples.

NOTE: Explosive substances or articles already assigned to another name in Table A of Chapter 3.2 are not included in this definition.

SIGNAL DEVICES, HAND: UN Nos. 0191, 0373

Portable articles containing pyrotechnic substances which produce visual signals or warnings. The term includes small surface flares such as highway or railway flares and small distress flares.

SIGNALS, DISTRESS, ship: UN Nos. 0194, 0195, 0505, 0506

Articles containing pyrotechnic substances designed to produce signals by means of sound, flame or smoke or any combination thereof.

SIGNALS, RAILWAY TRACK, EXPLOSIVE: UN Nos. 0192, 0193, 0492, 0493

Articles containing a pyrotechnic substance which explodes with a loud report when the article is crushed. They are designed to be placed on a rail.

SIGNALS, SMOKE: UN Nos. 0196, 0197, 0313, 0487, 0507

Articles containing pyrotechnic substances which emit smoke. In addition they may contain devices for emitting audible signals.

SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0374, 0375

Articles consisting of a charge of detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed.

SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0204, 0296

Articles consisting of a charge of detonating explosive with means of initiation not containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed.

SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (Substances, EVI), N.O.S.: UN No. 0482

Substances presenting a mass explosion hazard but which are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of transport, and which have passed Test Series 5.

TORPEDOES, LIQUID FUELLED with inert head: UN No. 0450

Articles consisting of a liquid explosive system to propel the torpedo through the water, with an inert head.

TORPEDOES, LIQUID FUELLED with or without bursting charge: UN No. 0449

Articles consisting of either a liquid explosive system to propel the torpedo through the water, with or without a warhead; or a liquid non-explosive system to propel the torpedo through the water, with a warhead.
 

TORPEDOES with bursting charge: UN No. 0451

Articles consisting of a non-explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features.

TORPEDOES with bursting charge: UN No. 0329

Articles consisting of an explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features.

TORPEDOES with bursting charge: UN No. 0330

Articles consisting of an explosive or non-explosive system to propel the torpedo through the water, and a warhead with means of initiation not containing two or more effective protective features.

TRACERS FOR AMMUNITION: UN Nos. 0212, 0306

Sealed articles containing pyrotechnic substances, designed to reveal the trajectory of a projectile. TRITONAL: UN No. 0390
Substance consisting of trinitrotoluene (TNT) mixed with aluminium. WARHEADS, ROCKET with burster or expelling charge: UN No. 0370
Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles.

WARHEADS, ROCKET with burster or expelling charge: UN No. 0371
Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive,  with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles.

WARHEADS, ROCKET with bursting charge: UN Nos. 0286, 0287

Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads for guided missiles.

WARHEADS, ROCKET with bursting charge: UN No. 0369

Articles consisting of a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads  for guided missiles.

WARHEADS, TORPEDO with bursting charge: UN No. 0221

Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a torpedo.
 

Class 2 Gases

Criteria

The heading of Class 2 covers pure gases, mixtures of gases, mixtures of one or more gases with one or more other substances and articles containing such substances.

A gas is a substance which:

(a)    at 50 °C has a vapour pressure greater than 300 kPa (3 bar); or

(b)    is completely gaseous at 20 °C at the standard pressure of 101.3 kPa.

NOTE 1: UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS  is  nevertheless  classified  in  Class 8.

NOTE 2: A pure gas may contain other components deriving from its production process or added to preserve the stability of the product, provided that the level of these components does not change its classification or its conditions of carriage, such as filling ratio, filling pressure, test pressure.

NOTE 3:  N.O.S. entries in 2.2.2.3 may cover pure gases as well as mixtures.
 

The substances and articles of Class 2 are subdivided as follows:

1.    Compressed gas: a gas which when packaged under pressure for carriage is entirely gaseous at
-50 °C; this category includes all gases with a critical temperature less than or equal to -50 °C;

2.    Liquefied gas: a gas which when packaged under pressure for carriage is partially liquid at temperatures above -50 °C. A distinction is made between:

High pressure liquefied gas: a gas with a critical temperature above -50 °C and equal to or below +65 °C; and

Low pressure liquefied gas: a gas with a critical temperature above +65 °C;

3.    Refrigerated liquefied gas: a gas which when packaged for carriage is made partially liquid because of its low temperature;

4.    Dissolved gas: a gas which when packaged under pressure for carriage is dissolved in a liquid phase solvent;

5.    Aerosol dispensers and receptacles, small, containing gas (gas cartridges);

6.    Other articles containing gas under pressure;

7.    Non-pressurized gases subject to special requirements (gas samples);

8.    Chemicals under pressure: liquids, pastes or powders, pressurized with a propellant that meets the definition of a compressed or liquefied gas and mixtures thereof.

9.    Adsorbed gas: a gas which when packaged for carriage is adsorbed onto a solid porous  material resulting in an internal receptacle pressure of less than 101.3 kPa at 20 C and less  than 300 kPa at 50 C.
 

Substances and articles (except aerosols and chemicals under pressure) of Class 2 are assigned to one of the following groups according to their hazardous properties, as follows:

A    asphyxiant;

O    oxidizing;

F    flammable;

T    toxic;

TF    toxic, flammable;

TC    toxic, corrosive;

TO    toxic, oxidizing;

TFC toxic, flammable, corrosive;

TOC   toxic, oxidizing, corrosive.

For gases and gas mixtures presenting hazardous properties associated with more than one group according to the criteria, the groups designated by letter T take precedence over all other groups. The groups designated by letter F take precedence over the groups designated by letters A or O.

NOTE 1: In the UN Model Regulations, the IMDG Code and the ICAO Technical Instructions, gases are assigned to one of the following three divisions, based on the primary hazard:

Division 2.1:    flammable gases (corresponding to the groups designated by the capital letter F);

Division 2.2:    non-flammable,  non-toxic  gases  (corresponding  to  the  groups  designated   by  the capital letters A or O);

Division 2.3:    toxic gases (corresponding to the groups designated by the capital letter T i.e.  T, TF, TC, TO, TFC and TOC).

NOTE 2: Receptacles, small containing gas (UN No. 2037) shall be assigned to the groups A to TOC according to the hazard of the contents. For aerosols (UN No. 1950), see 2.2.2.1.6. For chemicals under pressure (UN Nos. 3500 to 3505), see 2.2.2.1.7.

NOTE 3: Corrosive gases are considered to be toxic, and are therefore assigned to the group TC, TFC or TOC.
 

If a mixture of Class 2 mentioned by name in Table A of Chapter 3.2 meets different criteria as mentioned in 2.2.2.1.2 and 2.2.2.1.5, this mixture shall be classified according to the criteria and assigned to an appropriate N.O.S. entry.

Substances and articles (except aerosols and chemicals under pressure) of Class 2 which are not mentioned  by name in Table A of Chapter 3.2  shall be classified  under a collective    entry listed  in
2.2.2.3 in accordance with 2.2.2.1.2 and 2.2.2.1.3. The following criteria shall apply:

Asphyxiant gases

Gases which are non-oxidizing, non-flammable and non-toxic and which dilute or replace oxygen normally in the atmosphere.

Flammable gases

Gases which at 20 °C and a standard pressure of 101.3 kPa:

(a)    are ignitable when in a mixture of 13% or less by volume with air; or

(b)    have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit.

Flammability shall be determined by tests or by calculation, in accordance with methods adopted by ISO (see ISO 10156:2010).

Where insufficient data are available to use these methods, tests by a comparable method recognized by the competent authority of the country of origin may be used.

If the country of origin is not a Contracting Party to ADR these methods shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment.
 

Oxidizing gases

Gases, which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does. These are pure gases or gas mixtures with an oxidizing power greater  than 23.5% as determined by a method specified in ISO 10156:2010.

Toxic gases

NOTE: Gases meeting the criteria for toxicity in part or completely owing to their corrosivity are to be classified as toxic. See also the criteria under the heading "Corrosive gases" for a possible subsidiary corrosivity hazard.

Gases which:

(a)    are known to be so toxic or corrosive to humans as to pose a hazard to health; or

(b)    are presumed to be toxic or corrosive to humans because they have a LC50 value for acute toxicity equal to or less than 5 000 ml/m³ (ppm) when tested in accordance with 2.2.61.1.

In the case of gas mixtures (including vapours of substances from other classes) the following formula may be used:

LC    Toxic (mixture) =   
 
 
 

where    fi    =    mole fraction of the ith component substance of the mixture; Ti    =    toxicity index of the ith component substance of the mixture.
The Ti equals the LC50 value as found in packing instruction P200 of 4.1.4.1.

When no LC50 value is listed in packing instruction P200 of 4.1.4.1, a LC50 value available in scientific literature shall be used.
When the LC50 value is unknown, the toxicity index is determined by using the lowest LC50 value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility.

Corrosive gases

Gases or gas mixtures meeting the criteria for toxicity completely owing to their corrosivity are to be classified as toxic with a subsidiary corrosivity hazard.

A gas mixture that is considered to be toxic due to the combined effects of corrosivity and toxicity has a subsidiary hazard of corrosivity when the mixture is known by human experience to be destructive to the skin, eyes or mucous membranes or when the LC50 value of the corrosive components of the mixture is equal to or less than 5 000 ml/m3 (ppm) when the LC50 is calculated by the formula:

 
LC50  Corrosive (mixture) =

where    fci    =    mole fraction of the ith corrosive component substance of the mixture; Tci    =    toxicity index of the ith corrosive component substance of the mixture.
The Tci equals the LC50 value as found in packing instruction P200 of 4.1.4.1.

When no LC50 value is listed in packing instruction P200 of 4.1.4.1, a LC50 value available in scientific literature shall be used.
When the LC50 value is unknown the toxicity index is determined by  using the lowest LC50 value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility.
 

Aerosols

Aerosols (UN No. 1950) are assigned to one of the following groups according to their hazardous properties, as follows:

A    asphyxiant;

O    oxidizing;

F    flammable;

T    toxic;

C    corrosive;

CO    corrosive, oxidizing;

FC    flammable, corrosive;

TF    toxic, flammable;

TC    toxic, corrosive;

TO    toxic, oxidizing;

TFC    toxic, flammable, corrosive; TOC    toxic, oxidizing, corrosive.
The classification depends on the nature of the contents of the aerosol dispenser.

NOTE: Gases, which meet the definition of toxic gases according to 2.2.2.1.5 and gases identified as "Considered as pyrophoric" by table note c of Table 2 of packing instruction P200 in 4.1.4.1, shall  not be used as a propellant in an aerosol dispenser. Aerosols with contents meeting the criteria for packing group I for toxicity or corrosivity shall not be accepted for carriage (see also 2.2.2.2.2).

The following criteria shall apply:

(a)    Assignment to group A shall apply when the contents do not meet the criteria for any other group according to sub-paragraphs (b) to (f) below;

(b)    Assignment to group O shall apply when the aerosol contains an oxidizing gas according to 2.2.2.1.5;

(c)    Assignment to group F shall apply if the contents include 85% by mass or more flammable components and the chemical heat of combustion is 30 kJ/g or more.

It shall not apply if the contents contain 1% by mass or less flammable components and the heat of combustion is less than 20 kJ/g.

Otherwise the aerosol shall be tested for flammability in accordance with the tests described in the Manual of Tests and Criteria, Part III, section 31. Extremely flammable and flammable aerosols shall be assigned to group F;

NOTE: Flammable components are flammable  liquids,  flammable  solids  or  flammable gases and gas mixtures as defined in Notes 1 to 3 of sub-section 31.1.3 of Part III of the Manual of Tests and Criteria. This designation does not cover pyrophoric, self-heating or water-reactive substances. The chemical heat of combustion shall be determined by one of the following methods ASTM D 240, ISO/FDIS 13943:1999 (E/F) 86.1 to 86.3 or NFPA 30B.

(d)    Assignment to group T shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, are classified as Class 6.1, packing groups II or III;

(e)    Assignment to group C shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, meet the criteria for Class 8, packing groups II or III;

(f)    When the criteria for more than one group amongst groups O, F, T, and C are met, assignment to groups CO, FC, TF, TC TO, TFC or TOC shall apply, as relevant.
 

Chemicals under pressure

Chemicals under pressure (UN Nos. 3500 to 3505) are assigned to one of the following groups according to their hazardous properties, as follows:

A    asphyxiant;

F    flammable;

T    toxic;

C    corrosive;

FC    flammable, corrosive; TF    toxic, flammable.
The classification depends on the hazard characteristics of the components in the different states:

The propellant; The liquid; or The solid.
NOTE 1: Gases, which meet the definition of toxic gases or of oxidizing gases according to 2.2.2.1.5 or gases identified as "Considered as pyrophoric" by table note c of Table 2 of packing instruction P200 in 4.1.4.1, shall not be used as a propellant in chemicals under pressure.

NOTE 2: Chemicals under pressure with contents meeting the criteria for packing group I for toxicity or corrosivity or with contents meeting both the criteria for packing group II or III for toxicity and for packing group II or III for corrosivity shall not be accepted for carriage under these UN numbers.

NOTE 3: Chemicals under pressure with components meeting the properties of Class 1; liquid desensitized explosives of Class 3; self-reactive substances and solid desensitized explosives of Class 4.1; Class 4.2; Class 4.3; Class 5.1; Class 5.2; Class 6.2; or Class 7, shall not be used for carriage under these UN numbers.

NOTE 4: A chemical under pressure in an aerosol dispenser shall be carried under UN No. 1950.

The following criteria shall apply:

(a)    Assignment to group A shall apply when the contents do not meet the criteria for any other group according to sub-paragraphs (b) to (e) below;

(b)    Assignment to group F shall apply if one of the components, which can be a pure substance or  a mixture, needs to be classified as flammable. Flammable components are flammable liquids and liquid mixtures, flammable solids and solid mixtures or flammable gases and gas mixtures meeting the following criteria:

(i)    A flammable liquid is a liquid having a flashpoint of not more than 93 °C;

(ii)    A flammable solid is a solid which meets the criteria in 2.2.41.1;

(iii)    A flammable gas is a gas which meets the criteria in 2.2.2.1.5;

(c)    Assignment to group T shall apply when the contents, other than the propellant, are classified as dangerous goods of Class 6.1, packing groups II or III;

(d)    Assignment to group C shall apply when the contents, other than the propellant, are classified as dangerous goods of Class 8, packing groups II or III;

(e)    When the criteria for two groups amongst groups F, T, and C are met, assignment to groups FC or TF shall apply, as relevant.
 

Gases not accepted for carriage

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