Substances not accepted for carriage

Substances of Class 3 which are liable to form peroxides easily (as happens with ethers or with certain heterocyclic oxygenated substances) shall not be accepted for carriage if their peroxide content, calculated as hydrogen peroxide (H2O2), exceeds 0.3%. The peroxide content shall be determined as indicated in 2.3.3.3.

Chemically unstable substances of Class 3 shall not be accepted for carriage unless the necessary precautions have been taken to prevent the possibility of a dangerous decomposition  or polymerization under normal conditions of carriage. For the precautions necessary to prevent polymerization, see special provision 386 of Chapter 3.3. To this end particular care shall be taken to ensure that receptacles and tanks do not contain any substances liable to promote these reactions.

Liquid desensitized explosives other than those listed in Table A of Chapter 3.2 shall not be accepted for carriage as substances of Class 3.

List of collective entries

List of collective entries

Class 7 Radioactive material

Definitions

Radioactive material means any material containing radionuclides where both the activity concentration and the total activity in the consignment exceed the values specified in 2.2.7.2.2.1 to 2.2.7.2.2.6.

Contamination

Contamination means the presence of a radioactive substance on a surface in quantities in excess of 0.4 Bq/cm2for beta and gamma emitters and low toxicity alpha emitters, or 0.04 Bq/cm2for all other alpha emitters.Non-fixed contamination means contamination that can be removed from a surface during routine conditions of carriage.Fixed contamination means contamination other than non-fixed contamination.

Definitions of specific terms

A1 and A2

A1 means the activity value of special form radioactive material which is listed in the Table in 2.2.7.2.2.1 or derived in 2.2.7.2.2.2 and is used to determine the activity limits for the requirements of ADR.

A2 means the activity value of radioactive material, other than special form radioactive material, which is listed in the Table in 2.2.7.2.2.1 or derived in 2.2.7.2.2.2 and is used to determine the activity limits for the requirements of ADR.

Fissile nuclidesmeans uranium-233, uranium-235, plutonium-239 and plutonium-241. Fissile materialmeans a material containing any of the fissile nuclides. Excluded from the definition of fissile material are the following:

(a)Natural uranium or depleted uranium which is unirradiated;

(b)Natural uranium or depleted uranium which has been irradiated in thermal reactors only;

(c)Material with fissile nuclides less than a total of0.25g;

(d)Any combination of (a), (b) and/or (c).

These exclusions are only valid if there is no other material with fissile nuclides in the package or in the consignment if shipped unpackaged.

Low dispersible radioactive materialmeans either a solid radioactive material or a solid radioactive material in a sealed capsule, that has limited dispersibility and is not in powder form.

Low specific activity (LSA) materialmeans radioactive material which by its nature has a limited specific activity, or radioactive material for which limits of estimated average specific activity apply. External shielding materials surrounding the LSA material shall not be considered in determining the estimated average specific activity.

Low toxicity alpha emittersare: natural uranium; depleted uranium; natural thorium; uranium-235 or uranium-238; thorium-232; thorium-228 and thorium-230 when contained in ores or physical andchemical concentrates; or alpha emitters with a half-life of less than 10 days.

Special form radioactive materialmeans either:

(a)An indispersible solid radioactive material; or

(b)A sealed capsule containing radioactive material.

Specific activity of a radionuclidemeans the activity per unit mass of that nuclide. The specific activity of a material shall mean the activity per unit mass of the material in which the radionuclides are essentially uniformly distributed.

Surface contaminated object (SCO) means a solid object which is not itself radioactive but which has radioactive material distributed on its surface.Unirradiated thoriummeans thorium containing not more than 10-7g of uranium-233 per gram of thorium-232.

Unirradiated uraniummeans uraniumcontaining not more than 2 ×103Bq of plutonium per gram of uranium-235, not more than 9×106Bq of fission products per gram of uranium-235 and not more than 5 ×10-3g of uranium-236 per gram of uranium-235.

Uranium - natural, depleted, enrichedmeansthe following:

Natural uraniummeans uranium (which may be chemically separated) containing the naturally occurring distribution of uranium isotopes (approximately 99.28% uranium-238, and 0.72% uranium-235 by mass).

Depleted uraniummeans uranium containing a lesser mass percentage of uranium-235 than in natural uranium.

Enriched uraniummeans uranium containing a greater mass percentage of uranium-235than0.72%.

In all cases, a very small mass percentage of uranium-234 is present.

Classification

General provisions

 Radioactive material shall be assigned to one of the UN numbers specified in Table 2.2.7.2.1.1, in accordance with 2.2.7.2.4 and 2.2.7.2.5, taking into account the material characteristics determined in 2.2.7.2.3.

 

Table 2.2.7.2.1.1 Assignment of UN numbers

UN No

Proper shipping name and description a

Excepted packages  (1.7.1.5)

UN 2908

RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING

UN 2909

RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM

UN 2910

RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL

UN 2911

RADYOAKTİF MALZEME, ADİ PAKET - ALETLER veya NESNELER

UN 3507

RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - INSTRUMENTS or ARTICLES UN 3507 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE less than 0.1 kg per package, non-fissile or fissile-excepted b, c

Low specific activity radioactive material (2.2.7.2.3.1)

UN 2912

RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I), non fissile or fissile-excepted b

UN 3321

RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), non fissile or fissile-excepted b

UN 3322

RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-excepted b

UN 3324

RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), FISSILE 

UN 3325

RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSA-III), FISSILE

Surface contaminated objects (2.2.7.2.3.2)

UN 2913

RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), non fissile or fissile-excepted b

UN 3326

RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE

Type A packages (2.2.7.2.4.4)

UN 2915

RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile- excepted b

UN 3327

RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form

UN 3332

RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissile excepted b

UN 3333

RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE

Type B(U) packages (2.2.7.2.4.6)

UN 2916

 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-excepted b

UN 3328

RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE

Type B(M) packages (2.2.7.2.4.6)

UN 2917

RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non fissile or fissile-excepted b

UN 3329

RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE

Type C packages (2.2.7.2.4.6)

UN 3323

RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissile-excepted b

UN 3330

RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE

Special arrangement (2.2.7.2.5)

UN 2919

RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted b

UN 3331

RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE

Uranium hexafluoride (2.2.7.2.4.5)

UN 2977

RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE

UN 2978

RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissile-excepted b

UN 3507

URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE less than 0.1 kg per package, non-fissile or fissile-excepted b, c

_____________________

a The proper shipping name is found in the column “proper shipping name and description” and is restricted to that part shown in capital letters. In the cases of UN Nos. 2909, 2911, 2913 and 3326, where alternative proper shipping names are separated by the word “or” only the relevant proper shipping name shall be used.

b  The term "fissile-excepted" refers only to material excepted under 2.2.7.2.3.5.

c For UN No. 3507, see also special provision 369 in Chapter 3.3.

Determination of basic radionuclide values

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