In the following table (assimilation list) dangerous substances are listed in the numerical order of their UN numbers. As a rule, each line deals with a dangerous substance, single entry or collective entry covered by a specific UN number. However, several consecutive lines may be used for the same UN number, if substances belonging to the same UN number have different names (e.g. individual isomers of a group of substances), different chemical properties, different physical properties and/or different transport conditions. In such cases the single entry or collective entry within the particular packing group is the last one of such consecutive lines.
Columns (1) to (4) of table 4.1.1.21.6, following a structure similar to that of Table A of Chapter 3.2, are used to identify the substance for the purpose of this sub-section. The last column indicates the standard liquid(s) to which the substance can be assimilated.
Explanatory notes for each column:
Column (1) UN No.
Contains the UN number:
of the dangerous substance, if the substance has been assigned its own specific UN number, or
of the collective entry to which dangerous substances not listed by name have been assigned in accordance with the criteria ("decision trees") of Part 2.
Column (2a) Proper shipping name or technical name
Contains the name of the substance, the name of the single entry, which may cover various isomers, or the name of the collective entry itself.
The indicated name can deviate from the applicable proper shipping name.
Column (2b) Description
Contains a descriptive text to clarify the scope of the entry in those cases when the classification, the transport conditions and/or the chemical compatibility of the substance may be variable.
Column (3a) Class
Contains the number of the class, whose heading covers the dangerous substance. This class number is assigned in accordance with the procedures and criteria of Part 2.
Column (3b) Classification code
Contains the classification code of the dangerous substance in accordance with the procedures and criteria of Part 2.
Column (4) Packing group
Contains the packing group number(s) (I, II or III) assigned to the dangerous substance in accordance with the procedures and criteria of Part 2. Certain substances are not assigned to packing groups.
Column (5) Standard liquid
This column indicates, as definite information, either a standard liquid or a combination of standard liquids to which the substance can be assimilated, or a reference to the rule for collective entries in 4.1.1.21.5.
Table 4.1.1.21.6: Assimilation list
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
1090 |
Acetone |
3 |
F1 |
II |
Mixture of hydrocarbons Remark: applicable only, if it is proved that the permeability of the substance out of the package intended for carriage has an acceptable level |
|
1093 |
Acrylonitrile, stabilized |
3 |
FT1 |
I |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1104 |
Amyl acetates |
pure isomers and isomeric mixture |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
1105 |
Pentanols |
pure isomers and isomeric mixture |
3 |
F1 |
II/III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
1106 |
Amylamines |
pure isomers and isomeric mixture |
3 |
FC |
II/III |
Mixture of hydrocarbons and wetting solution |
1109 |
Amyl formates |
pure isomers and isomeric mixture |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
1120 |
Butanols |
pure isomers and isomeric mixture |
3 |
F1 |
II/III |
Acetic acid |
1123 |
Butyl acetates |
pure isomers and isomeric mixture |
3 |
F1 |
II/III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
1125 |
n-Butylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
1128 |
n-Butyl formate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1129 |
Butyraldehyde |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
1133 |
Adhesives |
containing flammable liquid |
3 |
F1 |
I/II/III |
Rule for collective entries |
1139 |
Coating solution |
includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining |
3 |
F1 |
I/II/III |
Rule for collective entries |
1145 |
Cyclohexane |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
1146 |
Cyclopentane |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
1153 |
Ethylene glycol diethyl ether |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
1154 |
Diethylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
1158 |
Diisopropylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
1160 |
Dimethylamine aqueous solution |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
1165 |
Dioxane |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
1169 |
Extracts, aromatic, liquid |
3 |
F1 |
II/III |
Rule for collective entries |
|
1170 |
Ethanol or Ethanol solution |
aqueous solution |
3 |
F1 |
II/III |
Acetic acid |
1171 |
Ethylene glycol monoethyl ether |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
1172 |
Ethylene glycol monoethyl ether acetate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
1173 |
Ethyl acetate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1177 |
2-Ethylbutyl acetate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1178 |
2-Ethylbutyraldehyde |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
1180 |
Ethyl butyrate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1188 |
Ethylene glycol monomethyl ether |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
1189 |
Ethylene glycol monomethyl ether acetate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
1190 |
Ethyl formate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1191 |
Octyl aldehydes |
pure isomers and isomeric mixture |
3 |
F1 |
III |
Mixture of hydrocarbons |
1192 |
Ethyl lactate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1195 |
Ethyl propionate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1197 |
Extracts, flavouring, liquid |
3 |
F1 |
II/III |
Rule for collective entries |
|
1198 |
Formaldehyde solution, flammable |
aqueous solution, flashpoint between 23 °C and 60 °C |
3 |
FC |
III |
Acetic acid |
1202 |
Diesel fuel |
complying with EN 590:2013 + A1:2017 or with a flashpoint not more than 100 °C |
3 |
F1 |
III |
Mixture of hydrocarbons |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
1202 |
Gas oil |
flashpoint not more than 100 °C |
3 |
F1 |
III |
Mixture of hydrocarbons |
1202 |
Heating oil, light |
extra light |
3 |
F1 |
III |
Mixture of hydrocarbons |
1202 |
Heating oil, light |
complying with EN 590:2013 + AC:2014 or with a flashpoint not more than 100 °C |
3 |
F1 |
III |
Mixture of hydrocarbons |
1203 |
Motor spirit, or gasoline, or petrol |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
1206 |
Heptanes |
pure isomers and isomeric mixture |
3 |
F1 |
II |
Mixture of hydrocarbons |
1207 |
Hexaldehyde |
n-Hexaldehyde |
3 |
F1 |
III |
Mixture of hydrocarbons |
1208 |
Hexanes |
pure isomers and isomeric mixture |
3 |
F1 |
II |
Mixture of hydrocarbons |
1210 |
Printing ink or Printing ink related material |
flammable, including printing ink thinning or reducing compound |
3 |
F1 |
I/II/III |
Rule for collective entries |
1212 |
Isobutanol |
3 |
F1 |
III |
Acetic acid |
|
1213 |
Isobutyl acetate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1214 |
Isobutylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
1216 |
Isooctenes |
pure isomers and isomeric mixture |
3 |
F1 |
II |
Mixture of hydrocarbons |
1219 |
Isopropanol |
3 |
F1 |
II |
Acetic acid |
|
1220 |
Isopropyl acetate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1221 |
Isopropylamine |
3 |
FC |
I |
Mixture of hydrocarbons and wetting solution |
|
1223 |
Kerosene |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
1224 |
3,3-Dimethyl-2-butanone |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
1224 |
Ketones, liquid, n.o.s. |
3 |
F1 |
II/III |
Rule for collective entries |
|
1230 |
Methanol |
3 |
FT1 |
II |
Acetic acid |
|
1231 |
Methyl acetate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1233 |
Methylamyl acetate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1235 |
Methylamine, aqueous solution |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
1237 |
Methyl butyrate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1247 |
Methyl methacrylate monomer, stabilized |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
1248 |
Methyl propionate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1262 |
Octanes |
pure isomers and isomeric mixture |
3 |
F1 |
II |
Mixture of hydrocarbons |
1263 |
Paint or Paint related material |
including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base or including paint thinning and reducing compound |
3 |
F1 |
I/II/III |
Rule for collective entries |
1265 |
Pentanes |
n-Pentane |
3 |
F1 |
II |
Mixture of hydrocarbons |
1266 |
Perfumery products |
with flammable solvents |
3 |
F1 |
II/III |
Rule for collective entries |
1268 |
Coal tar naphtha |
vapour pressure at 50 °C not more than 110 kPa |
3 |
F1 |
II |
Mixture of hydrocarbons |
1268 |
Petroleum distillates, n.o.s. or Petroleum products, n.o.s. |
3 |
F1 |
I/II/III |
Rule for collective entries |
|
1274 |
n-Propanol |
3 |
F1 |
II/III |
Acetic acid |
|
1275 |
Propionaldehyde |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
1276 |
n-Propyl acetate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1277 |
Propylamine |
n-Propylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
1281 |
Propyl formates |
pure isomers and isomeric mixture |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
1282 |
Pyridine |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
1286 |
Rosin oil |
3 |
F1 |
II/III |
Rule for collective entries |
|
1287 |
Rubber solution |
3 |
F1 |
II/III |
Rule for collective entries |
|
1296 |
Triethylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
1297 |
Trimethylamine, aqueous solution |
not more than 50% trimethylamine, by mass |
3 |
FC |
I/II/III |
Mixture of hydrocarbons and wetting solution |
1301 |
Vinyl acetate, stabilized |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1306 |
Wood preservatives, liquid |
3 |
F1 |
II/III |
Rule for collective entries |
|
1547 |
Aniline |
6.1 |
T1 |
II |
Acetic acid |
|
1590 |
Dichloroanilines, liquid |
pure isomers and isomeric mixture |
6.1 |
T1 |
II |
Acetic acid |
1602 |
Dye, liquid, toxic, n.o.s. or Dye intermediate, liquid, toxic, n.o.s. |
6.1 |
T1 |
I/II/III |
Rule for collective entries |
|
1604 |
Ethylenediamine |
8 |
CF1 |
II |
Mixture of hydrocarbons and wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
1715 |
Acetic anhydride |
8 |
CF1 |
II |
Acetic acid |
|
1717 |
Acetyl chloride |
3 |
FC |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1718 |
Butyl acid phosphate |
8 |
C3 |
III |
Wetting solution |
|
1719 |
Hydrogen sulphide |
aqueous solution |
8 |
C5 |
III |
Acetic acid |
1719 |
Caustic alkali liquid, n.o.s. |
inorganic |
8 |
C5 |
II/III |
Rule for collective entries |
1730 |
Antimony pentachloride, liquid |
pure |
8 |
C1 |
II |
Water |
1736 |
Benzoyl chloride |
8 |
C3 |
II |
Mixture of hydrocarbons and wetting solution |
|
1750 |
Chloroacetic acid solution |
aqueous solution |
6.1 |
TC1 |
II |
Acetic acid |
1750 |
Chloroacetic acid solution |
mixtures of mono- and dichloroacetic acid |
6.1 |
TC1 |
II |
Acetic acid |
1752 |
Chloroacetyl chloride |
6.1 |
TC1 |
I |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1755 |
Chromic acid solution |
aqueous solution with not more than 30% chromic acid |
8 |
C1 |
II/III |
Nitric acid |
1760 |
Cyanamide |
aqueous solution with not more than 50% cyanamide |
8 |
C9 |
II |
Water |
1760 |
O,O-Diethyl- dithiophosphoric acid |
8 |
C9 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1760 |
O,O-Diisopropyl- dithiophosphoric acid |
8 |
C9 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1760 |
O,O-Di-n-propyl- dithiophosphoric acid |
8 |
C9 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1760 |
Corrosive liquid, n.o.s. |
flashpoint more than 60 °C |
8 |
C9 |
I/II/III |
Rule for collective entries |
1761 |
Cupriethylenediamine solution |
aqueous solution |
8 |
CT1 |
II/III |
Mixture of hydrocarbons and wetting solution |
1764 |
Dichloroacetic acid |
8 |
C3 |
II |
Acetic acid |
|
1775 |
Fluoroboric acid |
aqueous solution with not more than 50% fluoroboric acid |
8 |
C1 |
II |
Water |
1778 |
Fluorosilicic acid |
8 |
C1 |
II |
Water |
|
1779 |
Formic acid |
with more than 85% acid by mass |
8 |
C3 |
II |
Acetic acid |
1783 |
Hexamethylenediamine solution |
aqueous solution |
8 |
C7 |
II/III |
Mixture of hydrocarbons and wetting solution |
1787 |
Hydriodic acid |
aqueous solution |
8 |
C1 |
II/III |
Water |
1788 |
Hydrobromic acid |
aqueous solution |
8 |
C1 |
II/III |
Water |
1789 |
Hydrochloric acid |
not more than 38% aqueous solution |
8 |
C1 |
II/III |
Water |
1790 |
Hydrofluoric acid |
with not more than 60% hydrofluoric acid |
8 |
CT1 |
II |
Water the permissible period of use: not more than 2 years |
1791 |
Hypochlorite solution |
aqueous solution, containing wetting agents as customary in trade |
8 |
C9 |
II/III |
Nitric acid and wetting solution * |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
1791 |
Hypochlorite solution |
aqueous solution |
8 |
C9 |
II/III |
Nitric acid * |
* For UN 1791: Test to be carried out only with vent. If the test is carried out with nitric acid as the standard liquid, an acid-resistant vent and gasket shall be used. If the test is carried out with hypochlorite solutions themselves, vents and gaskets of the same design type, resistant to hypochlorite (e.g. of silicone rubber) but not resistant to nitric acid, are also permitted. |
||||||
1793 |
Isopropyl acid phosphate |
8 |
C3 |
III |
Wetting solution |
|
1802 |
Perchloric acid |
aqueous solution with not more than 50% acid, by mass |
8 |
CO1 |
II |
Water |
1803 |
Phenolsulphonic acid, liquid |
isomeric mixture |
8 |
C3 |
II |
Water |
1805 |
Phosphoric acid, solution |
8 |
C1 |
III |
Water |
|
1814 |
Potassium hydroxide solution |
aqueous solution |
8 |
C5 |
II/III |
Water |
1824 |
Sodium hydroxide solution |
aqueous solution |
8 |
C5 |
II/III |
Water |
1830 |
Sulphuric acid |
with more than 51% pure acid |
8 |
C1 |
II |
Water |
1832 |
Sulphuric acid, spent |
chemical stable |
8 |
C1 |
II |
Water |
1833 |
Sulphurous acid |
8 |
C1 |
II |
Water |
|
1835 |
Tetramethylammonium hydroxide, solution |
aqueous solution, flashpoint more than 60 °C |
8 |
C7 |
II |
Water |
1840 |
Zinc chloride solution |
aqueous solution |
8 |
C1 |
III |
Water |
1848 |
Propionic acid |
with not less than 10% and less than 90% acid by mass |
8 |
C3 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
1862 |
Ethyl crotonate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1863 |
Fuel, aviation, turbine engine |
3 |
F1 |
I/II/III |
Mixture of hydrocarbons |
|
1866 |
Resin solution |
flammable |
3 |
F1 |
I/II/III |
Rule for collective entries |
1902 |
Diisooctyl acid phosphate |
8 |
C3 |
III |
Wetting solution |
|
1906 |
Sludge acid |
8 |
C1 |
II |
Nitric acid |
|
1908 |
Chlorite solution |
aqueous solution |
8 |
C9 |
II/III |
Acetic acid |
1914 |
Butyl propionates |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1915 |
Cyclohexanone |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
1917 |
Ethyl acrylate, stabilized |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1919 |
Methyl acrylate, stabilized |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1920 |
Nonanes |
pure isomers and isomeric mixture, flashpoint between 23 °C and 60 °C |
3 |
F1 |
III |
Mixture of hydrocarbons |
1935 |
Cyanide solution, n.o.s. |
inorganic |
6.1 |
T4 |
I/II/III |
Water |
1940 |
Thioglycolic acid |
8 |
C3 |
II |
Acetic acid |
|
1986 |
Alcohols, flammable, toxic, n.o.s. |
3 |
FT1 |
I/II/III |
Rule for collective entries |
|
1987 |
Cyclohexanol |
technical pure |
3 |
F1 |
III |
Acetic acid |
1987 |
Alcohols, n.o.s. |
3 |
F1 |
II/III |
Rule for collective entries |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
1988 |
Aldehydes, flammable, toxic, n.o.s. |
3 |
FT1 |
I/II/III |
Rule for collective entries |
|
1989 |
Aldehydes, n.o.s. |
3 |
F1 |
I/II/III |
Rule for collective entries |
|
1992 |
2,6-cis-Dimethyl- morpholine |
3 |
FT1 |
III |
Mixture of hydrocarbons |
|
1992 |
Flammable liquid, toxic, n.o.s. |
3 |
FT1 |
I/II/III |
Rule for collective entries |
|
1993 |
Propionic acid vinyl ester |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1993 |
(1-Methoxy-2-propyl) acetate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
1993 |
Flammable liquid, n.o.s. |
3 |
F1 |
I/II/III |
Rule for collective entries |
|
2014 |
Hydrogen peroxide, aqueous solution |
with not less than 20% but not more than 60% hydrogen peroxide, stabilized as necessary |
5.1 |
OC1 |
II |
Nitric acid |
2022 |
Cresylic acid |
liquid mixture containing cresols, xylenols and methyl phenols |
6.1 |
TC1 |
II |
Acetic acid |
2030 |
Hydrazine aqueous solution |
with not less than 37% but not more than 64% hydrazine, by mass |
8 |
CT1 |
II |
Water |
2030 |
Hydrazine hydrate |
aqueous solution with 64% hydrazine |
8 |
CT1 |
II |
Water |
2031 |
Nitric acid |
other than red fuming, with not more than 55% pure acid |
8 |
CO1 |
II |
Nitric acid |
2045 |
Isobutyraldehyde |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2050 |
Diisobutylene isomeric compounds |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2053 |
Methyl isobutyl carbinol |
3 |
F1 |
III |
Acetic acid |
|
2054 |
Morpholine |
8 |
CF1 |
I |
Mixture of hydrocarbons |
|
2057 |
Tripropylene |
3 |
F1 |
II/III |
Mixture of hydrocarbons |
|
2058 |
Valeraldehyde |
pure isomers and isomeric mixture |
3 |
F1 |
II |
Mixture of hydrocarbons |
2059 |
Nitrocellulose solution, flammable |
3 |
D |
I/II/III |
Rule for collective entries: Deviating from the general procedure this rule may be applied to solvents of classification code F1 |
|
2075 |
Chloral, anhydrous, stabilized |
6.1 |
T1 |
II |
Wetting solution |
|
2076 |
Cresols, liquid |
pure isomers and isomeric mixture |
6.1 |
TC1 |
II |
Acetic acid |
2078 |
Toluene diisocyanate |
liquid |
6.1 |
T1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2079 |
Diethylenetriamine |
8 |
C7 |
II |
Mixture of hydrocarbons |
|
2209 |
Formaldehyde solution |
aqueous solution with 37% Form-aldehyde, methanol content: 8-10% |
8 |
C9 |
III |
Acetic acid |
2209 |
Formaldehyde solution |
aqueous solution, with not less than 25% formaldehyde |
8 |
C9 |
III |
Water |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
2218 |
Acrylic acid, stabilized |
8 |
CF1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2227 |
n-Butyl methacrylate, stabilized |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2235 |
Chlorobenzyl chlorides, liquid |
para-Chlorobenzyl chloride |
6.1 |
T2 |
III |
Mixture of hydrocarbons |
2241 |
Cycloheptane |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2242 |
Cycloheptene |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2243 |
Cyclohexyl acetate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2244 |
Cyclopentanol |
3 |
F1 |
III |
Acetic acid |
|
2245 |
Cyclopentanone |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
2247 |
n-Decane |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
2248 |
Di-n-butylamine |
8 |
CF1 |
II |
Mixture of hydrocarbons |
|
2258 |
1,2-Propylenediamine |
8 |
CF1 |
II |
Mixture of hydrocarbons and wetting solution |
|
2259 |
Triethylenetetramine |
8 |
C7 |
II |
Water |
|
2260 |
Tripropylamine |
3 |
FC |
III |
Mixture of hydrocarbons and wetting solution |
|
2263 |
Dimethylcyclohexanes |
pure isomers and isomeric mixture |
3 |
F1 |
II |
Mixture of hydrocarbons |
2264 |
N,N-Dimethyl- cyclohexylamine |
8 |
CF1 |
II |
Mixture of hydrocarbons and wetting solution |
|
2265 |
N,N-Dimethyl-formamide |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2266 |
Dimethyl-N-propylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
2269 |
3,3'-Imino-dipropylamine |
8 |
C7 |
III |
Mixture of hydrocarbons and wetting solution |
|
2270 |
Ethylamine, aqueous solution |
with not less than 50% but not more than 70% ethylamine, flashpoint below 23 °C, corrosive or slightly corrosive |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
2275 |
2-Ethylbutanol |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2276 |
2-Ethylhexylamine |
3 |
FC |
III |
Mixture of hydrocarbons and wetting solution |
|
2277 |
Ethyl methacrylate, stabilized |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2278 |
n-Heptene |
3 |
F1 |
II |
Mixture of hydrocarbons |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
2282 |
Hexanols |
pure isomers and isomeric mixture |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2283 |
Isobutyl methacrylate, stabilized |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2286 |
Pentamethylheptane |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
2287 |
Isoheptenes |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2288 |
Isohexenes |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2289 |
Isophoronediamine |
8 |
C7 |
III |
Mixture of hydrocarbons and wetting solution |
|
2293 |
4-Methoxy-4-methyl- pentan-2-one |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
2296 |
Methylcyclohexane |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2297 |
Methylcyclohexanone |
pure isomers and isomeric mixture |
3 |
F1 |
III |
Mixture of hydrocarbons |
2298 |
Methylcyclopentane |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2302 |
5-Methylhexan-2-one |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
2308 |
Nitrosylsulphuric acid, liquid |
8 |
C1 |
II |
Water |
|
2309 |
Octadienes |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2313 |
Picolines |
pure isomers and isomeric mixture |
3 |
F1 |
III |
Mixture of hydrocarbons |
2317 |
Sodium cuprocyanide solution |
aqueous solution |
6.1 |
T4 |
I |
Water |
2320 |
Tetraethylenepentamine |
8 |
C7 |
III |
Mixture of hydrocarbons and wetting solution |
|
2324 |
Triisobutylene |
mixture of C12-mono- olefines, flashpoint between 23 °C and 60 °C |
3 |
F1 |
III |
Mixture of hydrocarbons |
2326 |
Trimethyl- cyclohexylamine |
8 |
C7 |
III |
Mixture of hydrocarbons and wetting solution |
|
2327 |
Trimethylhexamethylene- diamines |
pure isomers and isomeric mixture |
8 |
C7 |
III |
Mixture of hydrocarbons and wetting solution |
2330 |
Undecane |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
2336 |
Allyl formate |
3 |
FT1 |
I |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2348 |
Butyl acrylates, stabilized |
pure isomers and isomeric mixture |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2357 |
Cyclohexylamine |
flashpoint between 23 °C and 60 °C |
8 |
CF1 |
II |
Mixture of hydrocarbons and wetting solution |
2361 |
Diisobutylamine |
3 |
FC |
III |
Mixture of hydrocarbons and wetting solution |
|
2366 |
Diethyl carbonate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
2367 |
alpha-Methyl- valeraldehyde |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2370 |
1-Hexene |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2372 |
1,2-Di-(dimethylamino)- ethane |
3 |
F1 |
II |
Mixture of hydrocarbons and wetting solution |
|
2379 |
1,3-Dimethylbutylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
2383 |
Dipropylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
2385 |
Ethyl isobutyrate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2393 |
Isobutyl formate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2394 |
Isobutyl propionate |
flashpoint between 23 °C and 60 °C |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2396 |
Methacrylaldehyde, stabilized |
3 |
FT1 |
II |
Mixture of hydrocarbons |
|
2400 |
Methyl isovalerate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2401 |
Piperidine |
8 |
CF1 |
I |
Mixture of hydrocarbons and wetting solution |
|
2403 |
Isopropenyl acetate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2405 |
Isopropyl butyrate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2406 |
Isopropyl isobutyrate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2409 |
Isopropyl propionate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2410 |
1,2,3,6-Tetrahydro- pyridine |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2427 |
Potassium chlorate, aqueous solution |
5.1 |
O1 |
II/III |
Water |
|
2428 |
Sodium chlorate, aqueous solution |
5.1 |
O1 |
II/III |
Water |
|
2429 |
Calcium chlorate, aqueous solution |
5.1 |
O1 |
II/III |
Water |
|
2436 |
Thioacetic acid |
3 |
F1 |
II |
Acetic acid |
|
2457 |
2,3-Dimethylbutane |
3 |
F1 |
II |
Mixture of hydrocarbons |
|
2491 |
Ethanolamine |
8 |
C7 |
III |
Wetting solution |
|
2491 |
Ethanolamine solution |
aqueous solution |
8 |
C7 |
III |
Wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
2496 |
Propionic anhydride |
8 |
C3 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2524 |
Ethyl orthoformate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2526 |
Furfurylamine |
3 |
FC |
III |
Mixture of hydrocarbons and wetting solution |
|
2527 |
Isobutyl acrylate, stabilized |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2528 |
Isobutyl isobutyrate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2529 |
Isobutyric acid |
3 |
FC |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2531 |
Methacrylic acid, stabilized |
8 |
C3 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2542 |
Tributylamine |
6.1 |
T1 |
II |
Mixture of hydrocarbons |
|
2560 |
2-Methylpentan-2-ol |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2564 |
Trichloroacetic acid solution |
aqueous solution |
8 |
C3 |
II/III |
Acetic acid |
2565 |
Dicyclohexylamine |
8 |
C7 |
III |
Mixture of hydrocarbons and wetting solution |
|
2571 |
Ethylsulphuric acid |
8 |
C3 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2571 |
Alkylsulphuric acids |
8 |
C3 |
II |
Rule for collective entries |
|
2580 |
Aluminium bromide solution |
aqueous solution |
8 |
C1 |
III |
Water |
2581 |
Aluminium chloride solution |
aqueous solution |
8 |
C1 |
III |
Water |
2582 |
Ferric chloride solution |
aqueous solution |
8 |
C1 |
III |
Water |
2584 |
Methane sulphonic acid |
with more than 5% free sulphuric acid |
8 |
C1 |
II |
Water |
2584 |
Alkylsulphonic acids, liquid |
with more than 5% free sulphuric acid |
8 |
C1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2584 |
Benzene sulphonic acid |
with more than 5% free sulphuric acid |
8 |
C1 |
II |
Water |
2584 |
Toluene sulphonic acids |
with more than 5% free sulphuric acid |
8 |
C1 |
II |
Water |
2584 |
Arylsulphonic acids, liquid |
with more than 5% free sulphuric acid |
8 |
C1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2586 |
Methane sulfonic acid |
with not more than 5% free sulphuric acid |
8 |
C1 |
III |
Water |
2586 |
Alkylsulphonic acids, liquid |
with not more than 5% free sulphuric acid |
8 |
C1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
2586 |
Benzene sulphonic acid |
with not more than 5% free sulphuric acid |
8 |
C1 |
III |
Water |
2586 |
Toluene sulphonic acids |
with not more than 5% free sulphuric acid |
8 |
C1 |
III |
Water |
2586 |
Arylsulphonic acids, liquid |
with not more than 5% free sulphuric acid |
8 |
C1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2610 |
Triallylamine |
3 |
FC |
III |
Mixture of hydrocarbons and wetting solution |
|
2614 |
Methallyl alcohol |
3 |
F1 |
III |
Acetic acid |
|
2617 |
Methylcyclohexanols |
pure isomers and isomeric mixture, flashpoint between 23 °C and 60 °C |
3 |
F1 |
III |
Acetic acid |
2619 |
Benzyldimethylamine |
8 |
CF1 |
II |
Mixture of hydrocarbons and wetting solution |
|
2620 |
Amyl butyrates |
pure isomers and isomeric mixture, flashpoint between 23 °C and 60 °C |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2622 |
Glycidaldehyde |
flashpoint below 23 °C |
3 |
FT1 |
II |
Mixture of hydrocarbons |
2626 |
Chloric acid, aqueous solution |
with not more than 10% chloric acid |
5.1 |
O1 |
II |
Nitric acid |
2656 |
Quinoline |
flashpoint more than 60 °C |
6.1 |
T1 |
III |
Water |
2672 |
Ammonia solution |
relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia |
8 |
C5 |
III |
Water |
2683 |
Ammonium sulphide solution |
aqueous solution, flashpoint between 23 °C and 60 °C |
8 |
CFT |
II |
Acetic acid |
2684 |
3-Diethylamino- propylamine |
3 |
FC |
III |
Mixture of hydrocarbons and wetting solution |
|
2685 |
N,N-Diethylethylene- diamine |
8 |
CF1 |
II |
Mixture of hydrocarbons and wetting solution |
|
2693 |
Bisulphites, aqueous solution, n.o.s. |
inorganic |
8 |
C1 |
III |
Water |
2707 |
Dimethyldioxanes |
pure isomers and isomeric mixture |
3 |
F1 |
II/III |
Mixture of hydrocarbons |
2733 |
Amines, flammable, corrosive , n.o.s. or Polyamines, flammable, corrosive, n.o.s. |
3 |
FC |
I/II/III |
Mixture of hydrocarbons and wetting solution |
|
2734 |
Di-sec-butylamine |
8 |
CF1 |
II |
Mixture of hydrocarbons |
|
2734 |
Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s. |
8 |
CF1 |
I/II |
Mixture of hydrocarbons and wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
2735 |
Amines, liquid, corrosive, n.o.s. or Polyamines, liquid, corrosive, n.o.s. |
8 |
C7 |
I/II/III |
Mixture of hydrocarbons and wetting solution |
|
2739 |
Butyric anhydride |
8 |
C3 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2789 |
Acetic acid, glacial or Acetic acid solution |
aqueous solution, more than 80% acid, by mass |
8 |
CF1 |
II |
Acetic acid |
2790 |
Acetic acid solution |
aqueous solution, more than 10% but not more than 80% acid, by mass |
8 |
C3 |
II/III |
Acetic acid |
2796 |
Sulphuric acid |
with not more than 51% pure acid |
8 |
C1 |
II |
Water |
2797 |
Battery fluid, alkali |
Potassium/Sodium hydroxide, aqueous solution |
8 |
C5 |
II |
Water |
2810 |
2-Chloro-6-fluorobenzyl chloride |
stabilized |
6.1 |
T1 |
III |
Mixture of hydrocarbons |
2810 |
2-Phenylethanol |
6.1 |
T1 |
III |
Acetic acid |
|
2810 |
Ethylene glycol monohexyl ether |
6.1 |
T1 |
III |
Acetic acid |
|
2810 |
Toxic liquid, organic, n.o.s. |
6.1 |
T1 |
I/II/III |
Rule for collective entries |
|
2815 |
N-Aminoethylpiperazine |
8 |
CT1 |
III |
Mixture of hydrocarbons and wetting solution |
|
2818 |
Ammonium polysulphide solution |
aqueous solution |
8 |
CT1 |
II/III |
Acetic acid |
2819 |
Amyl acid phosphate |
8 |
C3 |
III |
Wetting solution |
|
2820 |
Butyric acid |
n-Butyric acid |
8 |
C3 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2821 |
Phenol solution |
aqueous solution, toxic, non- alkaline |
6.1 |
T1 |
II/III |
Acetic acid |
2829 |
Caproic acid |
n-Caproic acid |
8 |
C3 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
2837 |
Bisulphates, aqueous solution |
8 |
C1 |
II/III |
Water |
|
2838 |
Vinyl butyrate, stabilized |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2841 |
Di-n-amylamine |
3 |
FT1 |
III |
Mixture of hydrocarbons and wetting solution |
|
2850 |
Propylene tetramer |
mixture of C12- monoolefines, flashpoint between 23 °C and 60 °C |
3 |
F1 |
III |
Mixture of hydrocarbons |
2873 |
Dibutylaminoethanol |
N,N-Di-n- butylaminoethanol |
6.1 |
T1 |
III |
Acetic acid |
2874 |
Furfuryl alcohol |
6.1 |
T1 |
III |
Acetic acid |
|
2920 |
O,O-Diethyl- dithiophosphoric acid |
flashpoint between 23 °C and 60 °C |
8 |
CF1 |
II |
n-Butylacetate/ n-Butylacetate-saturated wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
2920 |
O,O-Dimethyl- dithiophosphoric acid |
flashpoint between 23 °C and 60 °C |
8 |
CF1 |
II |
Wetting solution |
2920 |
Hydrogen bromide |
33% solution in glacial acetic acid |
8 |
CF1 |
II |
Wetting solution |
2920 |
Tetramethylammonium hydroxide |
aqueous solution, flashpoint between 23 °C and 60 °C |
8 |
CF1 |
II |
Water |
2920 |
Corrosive liquid, flammable, n.o.s. |
8 |
CF1 |
I/II |
Rule for collective entries |
|
2922 |
Ammonium sulphide |
aqueous solution, flashpoint more than 60 °C |
8 |
CT1 |
II |
Water |
2922 |
Cresols |
aqueous alkaline solution, mixture of sodium and potassium cresolate, |
8 |
CT1 |
II |
Acetic acid |
2922 |
Phenol |
aqueous alkaline solution, mixture of sodium and potassium phenolate |
8 |
CT1 |
II |
Acetic acid |
2922 |
Sodium hydrogen difluoride |
aqueous solution |
8 |
CT1 |
III |
Water |
2922 |
Corrosive liquid, toxic, n.o.s. |
8 |
CT1 |
I/II/III |
Rule for collective entries |
|
2924 |
Flammable liquid, corrosive, n.o.s. |
slightly corrosive |
3 |
FC |
I/II/III |
Rule for collective entries |
2927 |
Toxic liquid, corrosive, organic, n.o.s. |
6.1 |
TC1 |
I/II |
Rule for collective entries |
|
2933 |
Methyl 2-chloro- propionate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2934 |
Isopropyl 2-chloro- propionate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2935 |
Ethyl 2-chloropropionate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2936 |
Thiolactic acid |
6.1 |
T1 |
II |
Acetic acid |
|
2941 |
Fluoroanilines |
pure isomers and isomeric mixture |
6.1 |
T1 |
III |
Acetic acid |
2943 |
Tetrahydrofurfurylamine |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
2945 |
N-Methylbutylamine |
3 |
FC |
II |
Mixture of hydrocarbons and wetting solution |
|
2946 |
2-Amino-5-diethyl- aminopentane |
6.1 |
T1 |
III |
Mixture of hydrocarbons and wetting solution |
|
2947 |
Isopropyl chloroacetate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
2984 |
Hydrogen peroxide, aqueous solution |
with not less than 8% but less than 20% hydrogen peroxide, stabilized as necessary |
5.1 |
O1 |
III |
Nitric acid |
3056 |
n-Heptaldehyde |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
3065 |
Alcoholic beverages |
with more than 24% alcohol by volume |
3 |
F1 |
II/III |
Acetic acid |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
3066 |
Paint or Paint related material |
including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base or including paint thinning and reducing compound |
8 |
C9 |
II/III |
Rule for collective entries |
3079 |
Methacrylonitrile, stabilized |
6.1 |
TF1 |
I |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3082 |
sec-Alcohol C6-C17poly (3-6) ethoxylate |
9 |
M6 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
3082 |
Alcohol C12-C15poly (1-3) ethoxylate |
9 |
M6 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
3082 |
Alcohol C13-C15poly (1-6) ethoxylate |
9 |
M6 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
3082 |
Aviation turbine fuel JP-5 |
flashpoint more than 60 °C |
9 |
M6 |
III |
Mixture of hydrocarbons |
3082 |
Aviation turbine fuel JP-7 |
flashpoint more than 60 °C |
9 |
M6 |
III |
Mixture of hydrocarbons |
3082 |
Coal tar |
flashpoint more than 60 °C |
9 |
M6 |
III |
Mixture of hydrocarbons |
3082 |
Coal tar naphtha |
flashpoint more than 60 °C |
9 |
M6 |
III |
Mixture of hydrocarbons |
3082 |
Creosote produced of coal tar |
flashpoint more than 60 °C |
9 |
M6 |
III |
Mixture of hydrocarbons |
3082 |
Creosote produced of wood tar |
flashpoint more than 60 °C |
9 |
M6 |
III |
Mixture of hydrocarbons |
3082 |
Cresyl diphenyl phosphate |
9 |
M6 |
III |
Wetting solution |
|
3082 |
Decyl acrylate |
9 |
M6 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
3082 |
Diisobutyl phthalate |
9 |
M6 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
3082 |
Di-n-butyl phthalate |
9 |
M6 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons |
|
3082 |
Hydrocarbons |
liquid, flashpoint more than 60 °C, environmentally hazardous |
9 |
M6 |
III |
Rule for collective entries |
3082 |
Isodecyl diphenyl phosphate |
9 |
M6 |
III |
Wetting solution |
|
3082 |
Methylnaphthalenes |
isomeric mixture, liquid |
9 |
M6 |
III |
Mixture of hydrocarbons |
3082 |
Triaryl phosphates |
n.o.s. |
9 |
M6 |
III |
Wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
3082 |
Tricresyl phosphate |
with not more than 3% ortho-isomer |
9 |
M6 |
III |
Wetting solution |
3082 |
Trixylenyl phosphate |
9 |
M6 |
III |
Wetting solution |
|
3082 |
Zinc alkyl dithiophosphate |
C3-C14 |
9 |
M6 |
III |
Wetting solution |
3082 |
Zinc aryl dithiophosphate |
C7-C16 |
9 |
M6 |
III |
Wetting solution |
3082 |
Environmentally hazardous substance, liquid, n.o.s. |
9 |
M6 |
III |
Rule for collective entries |
|
3099 |
Oxidizing liquid, toxic, n.o.s. |
5.1 |
OT1 |
I/II/III |
Rule for collective entries |
|
3101 3103 3105 3107 3109 3111 3113 3115 3117 3119 |
Organic Peroxide, Type B, C, D, E or F, liquid or Organic Peroxide, Type B, C, D, E or F, liquid, temperature controlled |
5.2 |
P1 |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons and nitric acid** |
||
** For UN Nos. 3101, 3103, 3105, 3107, 3109, 3111, 3113, 3115, 3117, 3119 (tert-butyl hydroperoxide with more than 40% peroxide content and peroxyacetic acids are excluded): All organic peroxides in a technically pure form or in solution in solvents which, as far as their compatibility is concerned, are covered by the standard liquid "mixture of hydrocarbons" in this list. Compatibility of vents and gaskets with organic peroxides may be verified, also independently of the design type test, by laboratory tests with nitric acid. |
||||||
3145 |
Butylphenols |
liquid, n.o.s. |
8 |
C3 |
I/II/III |
Acetic acid |
3145 |
Alkylphenols, liquid, n.o.s. |
including C2 to C12 homologues |
8 |
C3 |
I/II/III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
3149 |
Hydrogen peroxide and peroxyacetic acid mixture, stabilized |
with UN 2790 acetic acid, UN 2796 sulphuric acid and/or UN 1805 phosphoric acid, water and not more than 5% peroxyacetic acid |
5.1 |
OC1 |
II |
Wetting solution and nitric acid |
3210 |
Chlorates, inorganic, aqueous solution, n.o.s. |
5.1 |
O1 |
II/III |
Water |
|
3211 |
Perchlorates, inorganic, aqueous solution, n.o.s. |
5.1 |
O1 |
II/III |
Water |
|
3213 |
Bromates, inorganic, aqueous solution, n.o.s. |
5.1 |
O1 |
II/III |
Water |
|
3214 |
Permanganates, inorganic, aqueous solution, n.o.s. |
5.1 |
O1 |
II |
Water |
|
3216 |
Persulphates, inorganic, aqueous solution, n.o.s. |
5.1 |
O1 |
III |
Wetting solution |
|
3218 |
Nitrates, inorganic, aqueous solution, n.o.s. |
5.1 |
O1 |
II/III |
Water |
|
3219 |
Nitrites, inorganic, aqueous solution, n.o.s. |
5.1 |
O1 |
II/III |
Water |
|
3264 |
Cupric chloride |
aqueous solution, slightly corrosive |
8 |
C1 |
III |
Water |
3264 |
Hydroxylamine sulphate |
25% aqueous solution |
8 |
C1 |
III |
Water |
3264 |
Phosphorous acid |
aqueous solution |
8 |
C1 |
III |
Water |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
3264 |
Corrosive liquid, acidic, inorganic, n.o.s. |
flashpoint more than 60 °C |
8 |
C1 |
I/II/III |
Rule for collective entries; not applicable to mixtures having components of UN Nos.: 1830, 1832, 1906 and 2308 |
3265 |
Methoxyacetic acid |
8 |
C3 |
I |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3265 |
Allyl succinic acid anhydride |
8 |
C3 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3265 |
Dithioglycolic acid |
8 |
C3 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3265 |
Butyl phosphate |
mixture of mono- and di- butyl phosphate |
8 |
C3 |
III |
Wetting solution |
3265 |
Caprylic acid |
8 |
C3 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3265 |
Isovaleric acid |
8 |
C3 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3265 |
Pelargonic acid |
8 |
C3 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3265 |
Pyruvic acid |
8 |
C3 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3265 |
Valeric acid |
8 |
C3 |
III |
Acetic acid |
|
3265 |
Corrosive liquid, acidic, organic, n.o.s. |
flashpoint more than 60 °C |
8 |
C3 |
I/II/III |
Rule for collective entries |
3266 |
Sodium hydrosulphide |
aqueous solution |
8 |
C5 |
II |
Acetic acid |
3266 |
Sodium sulphide |
aqueous solution, slightly corrosive |
8 |
C5 |
III |
Acetic acid |
3266 |
Corrosive liquid, basic, inorganic, n.o.s. |
flashpoint more than 60 °C |
8 |
C5 |
I/II/III |
Rule for collective entries |
3267 |
2,2'-(Butylimino)- bisethanol |
8 |
C7 |
II |
Mixture of hydrocarbons and wetting solution |
|
3267 |
Corrosive liquid, basic, organic, n.o.s. |
flashpoint more than 60 °C |
8 |
C7 |
I/II/III |
Rule for collective entries |
3271 |
Ethylene glycol monobutyl ether |
flashpoint 60 °C |
3 |
F1 |
III |
Acetic acid |
3271 |
Ether, n.o.s. |
3 |
F1 |
II/III |
Rule for collective entries |
|
3272 |
Acrylic acid tert-butyl ester |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3272 |
Isobutyl propionate |
flashpoint below 23 °C |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
3272 |
Methyl valerate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3272 |
Trimethyl ortho-formate |
3 |
F1 |
II |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
UN No. |
Proper shipping name or technical name |
Description |
Class |
Classifi- cation Code |
Packing group |
Standard liquid |
3.1.2 |
3.1.2 |
2.2 |
2.2 |
2.1.1.3 |
||
(1) |
(2a) |
(2b) |
(3a) |
(3b) |
(4) |
(5) |
3272 |
Ethyl valerate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3272 |
Isobutyl isovalerate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3272 |
n-Amyl propionate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3272 |
n-Butylbutyrate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3272 |
Methyl lactate |
3 |
F1 |
III |
n-Butyl acetate/ n-butyl acetate-saturated wetting solution |
|
3272 |
Ester, n.o.s. |
3 |
F1 |
II/III |
Rule for collective entries |
|
3287 |
Sodium nitrite |
40% aqueous solution |
6.1 |
T4 |
III |
Water |
3287 |
Toxic liquid, inorganic, n.o.s. |
6.1 |
T4 |
I/II/III |
Rule for collective entries |
|
3291 |
Clinical waste, unspecified, n.o.s. |
liquid |
6.2 |
I3 |
II |
Water |
3293 |
Hydrazine, aqueous solution |
with not more than 37% hydrazine, by mass |
6.1 |
T4 |
III |
Water |
3295 |
Heptenes |
n.o.s |
3 |
F1 |
II |
Mixture of hydrocarbons |
3295 |
Nonanes |
flashpoint below 23 °C |
3 |
F1 |
II |
Mixture of hydrocarbons |
3295 |
Decanes |
n.o.s |
3 |
F1 |
III |
Mixture of hydrocarbons |
3295 |
1,2,3-Trimethylbenzene |
3 |
F1 |
III |
Mixture of hydrocarbons |
|
3295 |
Hydrocarbons, liquid, n.o.s. |
3 |
F1 |
I/II/III |
Rule for collective entries |
|
3405 |
Barium chlorate, solution |
aqueous solution |
5.1 |
OT1 |
II/III |
Water |
3406 |
Barium perchlorate, solution |
aqueous solution |
5.1 |
OT1 |
II/III |
Water |
3408 |
Lead perchlorate, solution |
aqueous solution |
5.1 |
OT1 |
II/III |
Water |
3413 |
Potassium cyanide, solution |
aqueous solution |
6.1 |
T4 |
I/II/III |
Water |
3414 |
Sodium cyanide, solution |
aqueous solution |
6.1 |
T4 |
I/II/III |
Water |
3415 |
Sodium fluoride, solution |
aqueous solution |
6.1 |
T4 |
III |
Water |
3422 |
Potassium fluoride, solution |
aqueous solution |
6.1 |
T4 |
III |
Water |
When IBCs are used for the carriage of liquids with a flash-point of 60 °C (closed cup) or lower, or of powders liable to dust explosion, measures shall be taken to prevent a dangerous electrostatic discharge.
Every metal, rigid plastics and composite IBC, shall be inspected and tested, as relevant, in accordance with 6.5.4.4 or 6.5.4.5:
- before it is put into service;
- thereafter at intervals not exceeding two and a half and five years, as appropriate;
- after the repair or remanufacture, before it is re-used for carriage.
An IBC shall not be filled and offered for carriage after the date of expiry of the last periodic test or inspection. However, an IBC filled prior to the date of expiry of the last periodic test or inspection may be carried for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection. In addition, an IBC may be carried after the date of expiry of the last periodic test or inspection:
(a) after emptying but before cleaning, for purposes of performing the required test or inspection prior to refilling; and
(b) unless otherwise approved by the competent authority, for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection in order to allow the return of dangerous goods or residues for proper disposal or recycling.
NOTE: For the particulars in the transport document, see 5.4.1.1.11.
IBCs of type 31HZ2 shall be filled to at least 80% of the volume of the outer casing.
Except for routine maintenance of metal, rigid plastics, composite and flexible IBCs performed by the owner of the IBC, whose State and name or authorized symbol is durably marked on the IBC, the party performing routine maintenance shall durably mark the IBC near the manufacturer's UN design type mark to show:
(a) The State in which the routine maintenance was carried out; and
(b) The name or authorized symbol of the party performing the routine maintenance.
Packing instructions applicable to dangerous goods of Classes 1 to 9 are specified in Section 4.1.4. They are subdivided in three sub-sections depending on the type of packagings to which they apply:
Sub-section 4.1.4.1 for packagings other than IBCs and large packagings; these packing instructions are designated by an alphanumeric code starting with the letter "P" or "R" for packagings specific to RID and ADR;
Sub-section 4.1.4.2 for IBCs; these are designated by an alphanumeric code starting with the letters "IBCs";
Sub-section 4.1.4.3 for large packagings; these are designated by an alphanumeric code starting with the letters "LP".
Generally, packing instructions specify that the general provisions of 4.1.1, 4.1.2 or 4.1.3, as appropriate, are applicable. They may also require compliance with the special provisions of Sections 4.1.5, 4.1.6, 4.1.7, 4.1.8 or 4.1.9 when appropriate. Special packing provisions may also be specified in the packing instruction for individual substances or articles. They are also designated by an alphanumeric code comprising the letters:
"PP" for packagings other than IBCs and large packagings, or "RR" for special provisions specific to RID and ADR;
"B" for IBCs or "BB" for special packing provisions specific to RID and ADR; "L" for large packagings or "LL" for special packing provisions specific to ADR.
Unless otherwise specified, each packaging shall conform to the applicable requirements of Part 6. Generally packing instructions do not provide guidance on compatibility and the user shall not select a packaging without checking that the substance is compatible with the packaging material selected (e.g. glass receptacles are unsuitable for most fluorides). Where glass receptacles are permitted in the packing instructions porcelain, earthenware and stoneware packagings are also allowed.
Column (8) of Table A of Chapter 3.2 shows for each article or substance the packing instruction(s) that shall be used. Columns (9a) and (9b) indicate the special packing provisions and the mixed packing provisions (see 4.1.10) applicable to specific substances or articles.
Each packing instruction shows, where applicable, the acceptable single and combination packagings. For combination packagings, the acceptable outer packagings, inner packagings and when applicable the maximum quantity permitted in each inner or outer packaging, are shown. Maximum net mass and maximum capacity are as defined in 1.2.1.
The following packagings shall not be used when the substances being carried are liable to become liquid during carriage:
Packagings
Drums: 1D and 1G
Boxes: 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1 and 4H2
Bags: 5L1, 5L2, 5L3, 5H1, 5H2, 5H3, 5H4, 5M1 and 5M2
Composite packagings: 6HC, 6HD2, 6HG1, 6HG2, 6HD1, 6PC, 6PD1, 6PD2, 6PG1, 6PG2
and 6PH1
Large packagings
Flexible plastics: 51H (outer packaging) IBCs
For substances of packing group I: All types of IBC For substances of packing groups II and III:
Wooden: 11C, 11D and 11F
Fibreboard: 11G
Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2
Composite: 11HZ2 and 21HZ2
For the purposes of this paragraph, substances and mixtures of substances having a melting point equal to or less than 45 °C shall be treated as solids liable to become liquid during carriage.
Where the packing instructions in this Chapter authorize the use of a particular type of packaging (e.g. 4G; 1A2), packagings bearing the same packaging identification code followed by the letters "V", "U" or "W" marked in accordance with the requirements of Part 6 (e.g. 4GV, 4GU or 4GW; 1A2V, 1A2U or 1A2W) may also be used under the same conditions and limitations applicable to the use of that type of packaging according to the relevant packing instructions. For example, a combination packaging marked with the packaging code "4GV" may be used whenever a combination packaging marked "4G" is authorized, provided the requirements in the relevant packing instruction regarding types of inner packagings and quantity limitations are respected.
Unless otherwise indicated in ADR, pressure receptacles conforming to:
(a) the applicable requirements of Chapter 6.2; or
(b) the national or international standards on the design, construction, testing, manufacturing and inspection, as applied by the country in which the pressure receptacles are manufactured, provided that the provisions of 4.1.3.6 are met, and that, for metallic cylinders, tubes, pressure drums, bundles of cylinders and salvage pressure receptacles, the construction is such that the minimum burst ratio (burst pressure divided by test pressure) is:
(i) 1.50 for refillable pressure receptacles;
(ii) 2.00 for non-refillable pressure receptacles,
are authorized for the carriage of any liquid or solid substance other than explosives, thermally unstable substances, organic peroxides, self-reactive substances, substances where significant pressure may develop by evolution of chemical reaction and radioactive material (unless permitted in 4.1.9).
This sub-section is not applicable to the substances mentioned in 4.1.4.1, packing instruction P200, table 3.
Every design type of pressure receptacle shall be approved by the competent authority of the country of manufacture or as indicated in Chapter 6.2.