Assimilation list

In the following table (assimilation list) dangerous substances are listed in the numerical order of their UN numbers. As a rule, each line deals with a dangerous substance, single entry or collective entry covered by a specific UN number. However, several consecutive lines may be used for the same UN number, if substances belonging to the same UN number have different names (e.g. individual isomers of a group of substances), different chemical properties, different physical properties and/or different transport conditions. In such cases the single entry or collective entry within the particular packing group is the last one of such consecutive lines.

Columns (1) to (4) of table 4.1.1.21.6, following a structure similar to that of Table A of Chapter 3.2, are used to identify the substance for the purpose of this sub-section. The last column indicates the standard liquid(s) to which the substance can be assimilated.

Explanatory notes for each column:

Column (1) UN No.

Contains the UN number:

of the dangerous substance, if the substance has been assigned its own specific UN number, or

of the collective entry to which dangerous substances not listed by name have been assigned in accordance with the criteria ("decision trees") of Part 2.

Column (2a) Proper shipping name or technical name

Contains the name of the substance, the name of the single entry, which may cover various isomers, or the name of the collective entry itself.

The indicated name can deviate from the applicable proper shipping name.

Column (2b) Description

Contains a descriptive text to clarify the scope of the entry in those cases when the classification, the transport conditions and/or the chemical compatibility of the substance may be variable.

Column (3a) Class

Contains the number of the class, whose heading covers the dangerous substance. This class number is assigned in accordance with the procedures and criteria of Part 2.

Column (3b) Classification code

Contains the classification code of the dangerous substance in accordance with the procedures and criteria of Part 2.

Column (4) Packing group

Contains the packing group number(s) (I, II or III) assigned to the dangerous substance in accordance with the procedures and criteria of Part 2. Certain substances are not assigned to packing groups.

Column (5) Standard liquid

This column indicates, as definite information, either a standard liquid or a combination of standard liquids to which the substance can be assimilated, or a reference to the rule for collective entries in 4.1.1.21.5.

Table 4.1.1.21.6: Assimilation list

UN

No.

Proper shipping name or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

1090

Acetone

 

3

F1

II

Mixture of hydrocarbons Remark: applicable only, if it is proved that the permeability of the substance out of the package intended for carriage has an acceptable

level

1093

Acrylonitrile, stabilized

 

3

FT1

I

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1104

Amyl acetates

pure isomers and isomeric mixture

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1105

Pentanols

pure isomers and isomeric mixture

3

F1

II/III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1106

Amylamines

pure isomers and isomeric mixture

3

FC

II/III

Mixture of hydrocarbons

and

wetting solution

1109

Amyl formates

pure isomers and isomeric mixture

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

1120

Butanols

pure isomers and isomeric mixture

3

F1

II/III

Acetic acid

1123

Butyl acetates

pure isomers and isomeric mixture

3

F1

II/III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1125

n-Butylamine

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

1128

n-Butyl formate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

1129

Butyraldehyde

 

3

F1

II

Mixture of hydrocarbons

1133

Adhesives

containing flammable liquid

3

F1

I/II/III

Rule for collective entries

1139

Coating solution

includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel

lining

3

F1

I/II/III

Rule for collective entries

1145

Cyclohexane

 

3

F1

II

Mixture of hydrocarbons

1146

Cyclopentane

 

3

F1

II

Mixture of hydrocarbons

1153

Ethylene glycol diethyl ether

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

1154

Diethylamine

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

1158

Diisopropylamine

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

1160

Dimethylamine aqueous solution

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

1165

Dioxane

 

3

F1

II

Mixture of hydrocarbons

1169

Extracts, aromatic, liquid

 

3

F1

II/III

Rule for collective entries

1170

Ethanol or Ethanol solution

aqueous solution

3

F1

II/III

Acetic acid

1171

Ethylene glycol monoethyl ether

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

1172

Ethylene glycol monoethyl ether acetate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

1173

Ethyl acetate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1177

2-Ethylbutyl acetate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1178

2-Ethylbutyraldehyde

 

3

F1

II

Mixture of hydrocarbons

1180

Ethyl butyrate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1188

Ethylene glycol monomethyl ether

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

1189

Ethylene glycol monomethyl ether acetate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

1190

Ethyl formate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1191

Octyl aldehydes

pure isomers and isomeric mixture

3

F1

III

Mixture of hydrocarbons

1192

Ethyl lactate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1195

Ethyl propionate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

1197

Extracts, flavouring, liquid

 

3

F1

II/III

Rule for collective entries

1198

Formaldehyde solution, flammable

aqueous solution, flashpoint between 23 °C and 60 °C

3

FC

III

Acetic acid

1202

Diesel fuel

complying with

EN 590:2013 + A1:2017 or

with a flashpoint not more than 100 °C

3

F1

III

Mixture of hydrocarbons

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

1202

Gas oil

flashpoint not more than 100 °C

3

F1

III

Mixture of hydrocarbons

1202

Heating oil, light

extra light

3

F1

III

Mixture of hydrocarbons

1202

Heating oil, light

complying with

EN 590:2013 + AC:2014 or

with a flashpoint not more

than 100 °C

3

F1

III

Mixture of hydrocarbons

1203

Motor spirit, or gasoline, or petrol

 

3

F1

II

Mixture of hydrocarbons

1206

Heptanes

pure isomers and isomeric mixture

3

F1

II

Mixture of hydrocarbons

1207

Hexaldehyde

n-Hexaldehyde

3

F1

III

Mixture of hydrocarbons

1208

Hexanes

pure isomers and isomeric mixture

3

F1

II

Mixture of hydrocarbons

1210

Printing ink

or

Printing ink related material

flammable, including printing ink thinning or reducing compound

3

F1

I/II/III

Rule for collective entries

1212

Isobutanol

 

3

F1

III

Acetic acid

1213

Isobutyl acetate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1214

Isobutylamine

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

1216

Isooctenes

pure isomers and isomeric mixture

3

F1

II

Mixture of hydrocarbons

1219

Isopropanol

 

3

F1

II

Acetic acid

1220

Isopropyl acetate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

1221

Isopropylamine

 

3

FC

I

Mixture of hydrocarbons

and

wetting solution

1223

Kerosene

 

3

F1

III

Mixture of hydrocarbons

1224

3,3-Dimethyl-2-butanone

 

3

F1

II

Mixture of hydrocarbons

1224

Ketones, liquid, n.o.s.

 

3

F1

II/III

Rule for collective entries

1230

Methanol

 

3

FT1

II

Acetic acid

1231

Methyl acetate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1233

Methylamyl acetate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1235

Methylamine, aqueous solution

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

1237

Methyl butyrate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1247

Methyl methacrylate monomer, stabilized

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

1248

Methyl propionate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1262

Octanes

pure isomers and isomeric mixture

3

F1

II

Mixture of hydrocarbons

1263

Paint

or

Paint related material

including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base

or

including paint thinning and reducing compound

3

F1

I/II/III

Rule for collective entries

1265

Pentanes

n-Pentane

3

F1

II

Mixture of hydrocarbons

1266

Perfumery products

with flammable solvents

3

F1

II/III

Rule for collective entries

1268

Coal tar naphtha

vapour pressure at 50 °C not more than 110 kPa

3

F1

II

Mixture of hydrocarbons

1268

Petroleum distillates, n.o.s.

or

Petroleum products, n.o.s.

 

3

F1

I/II/III

Rule for collective entries

1274

n-Propanol

 

3

F1

II/III

Acetic acid

1275

Propionaldehyde

 

3

F1

II

Mixture of hydrocarbons

1276

n-Propyl acetate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

1277

Propylamine

n-Propylamine

3

FC

II

Mixture of hydrocarbons

and

wetting solution

1281

Propyl formates

pure isomers and isomeric mixture

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1282

Pyridine

 

3

F1

II

Mixture of hydrocarbons

1286

Rosin oil

 

3

F1

II/III

Rule for collective entries

1287

Rubber solution

 

3

F1

II/III

Rule for collective entries

1296

Triethylamine

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

1297

Trimethylamine, aqueous solution

not more than 50% trimethylamine, by mass

3

FC

I/II/III

Mixture of hydrocarbons

and

wetting solution

1301

Vinyl acetate, stabilized

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1306

Wood preservatives, liquid

 

3

F1

II/III

Rule for collective entries

1547

Aniline

 

6.1

T1

II

Acetic acid

1590

Dichloroanilines, liquid

pure isomers and isomeric mixture

6.1

T1

II

Acetic acid

1602

Dye, liquid, toxic, n.o.s.

or

Dye intermediate, liquid,

toxic, n.o.s.

 

6.1

T1

I/II/III

Rule for collective entries

1604

Ethylenediamine

 

8

CF1

II

Mixture of hydrocarbons

and

wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

1715

Acetic anhydride

 

8

CF1

II

Acetic acid

1717

Acetyl chloride

 

3

FC

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1718

Butyl acid phosphate

 

8

C3

III

Wetting solution

1719

Hydrogen sulphide

aqueous solution

8

C5

III

Acetic acid

1719

Caustic alkali liquid, n.o.s.

inorganic

8

C5

II/III

Rule for collective entries

1730

Antimony pentachloride, liquid

pure

8

C1

II

Water

1736

Benzoyl chloride

 

8

C3

II

Mixture of hydrocarbons

and

wetting solution

1750

Chloroacetic acid solution

aqueous solution

6.1

TC1

II

Acetic acid

1750

Chloroacetic acid solution

mixtures of mono- and dichloroacetic acid

6.1

TC1

II

Acetic acid

1752

Chloroacetyl chloride

 

6.1

TC1

I

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1755

Chromic acid solution

aqueous solution with not more than 30% chromic acid

8

C1

II/III

Nitric acid

1760

Cyanamide

aqueous solution with not more than 50% cyanamide

8

C9

II

Water

1760

O,O-Diethyl- dithiophosphoric acid

 

8

C9

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1760

O,O-Diisopropyl- dithiophosphoric acid

 

8

C9

II

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

1760

O,O-Di-n-propyl- dithiophosphoric acid

 

8

C9

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1760

Corrosive liquid, n.o.s.

flashpoint more than 60 °C

8

C9

I/II/III

Rule for collective entries

1761

Cupriethylenediamine solution

aqueous solution

8

CT1

II/III

Mixture of hydrocarbons

and

wetting solution

1764

Dichloroacetic acid

 

8

C3

II

Acetic acid

1775

Fluoroboric acid

aqueous solution with not more than 50% fluoroboric

acid

8

C1

II

Water

1778

Fluorosilicic acid

 

8

C1

II

Water

1779

Formic acid

with more than 85% acid by mass

8

C3

II

Acetic acid

1783

Hexamethylenediamine solution

aqueous solution

8

C7

II/III

Mixture of hydrocarbons

and

wetting solution

1787

Hydriodic acid

aqueous solution

8

C1

II/III

Water

1788

Hydrobromic acid

aqueous solution

8

C1

II/III

Water

1789

Hydrochloric acid

not more than 38% aqueous solution

8

C1

II/III

Water

1790

Hydrofluoric acid

with not more than 60% hydrofluoric acid

8

CT1

II

Water

the permissible period of use: not more than 2 years

1791

Hypochlorite solution

aqueous solution, containing wetting agents as customary

in trade

8

C9

II/III

Nitric acid

and

wetting solution *

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

1791

Hypochlorite solution

aqueous solution

8

C9

II/III

Nitric acid *

For UN 1791: Test to be carried out only with vent. If the test is carried out with nitric acid as the standard liquid, an acid-resistant vent and gasket shall be used. If the test is carried out with hypochlorite solutions themselves, vents and gaskets

of the same design type, resistant to hypochlorite (e.g. of silicone rubber) but not resistant to nitric acid, are also permitted.

1793

Isopropyl acid phosphate

 

8

C3

III

Wetting solution

1802

Perchloric acid

aqueous solution with not more than 50% acid, by mass

8

CO1

II

Water

1803

Phenolsulphonic acid, liquid

isomeric mixture

8

C3

II

Water

1805

Phosphoric acid, solution

 

8

C1

III

Water

1814

Potassium hydroxide solution

aqueous solution

8

C5

II/III

Water

1824

Sodium hydroxide solution

aqueous solution

8

C5

II/III

Water

1830

Sulphuric acid

with more than 51% pure acid

8

C1

II

Water

1832

Sulphuric acid, spent

chemical stable

8

C1

II

Water

1833

Sulphurous acid

 

8

C1

II

Water

1835

Tetramethylammonium hydroxide, solution

aqueous solution, flashpoint more than 60 °C

8

C7

II

Water

1840

Zinc chloride solution

aqueous solution

8

C1

III

Water

1848

Propionic acid

with not less than 10% and less than 90% acid by mass

8

C3

III

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

1862

Ethyl crotonate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1863

Fuel, aviation, turbine engine

 

3

F1

I/II/III

Mixture of hydrocarbons

1866

Resin solution

flammable

3

F1

I/II/III

Rule for collective entries

1902

Diisooctyl acid phosphate

 

8

C3

III

Wetting solution

1906

Sludge acid

 

8

C1

II

Nitric acid

1908

Chlorite solution

aqueous solution

8

C9

II/III

Acetic acid

1914

Butyl propionates

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1915

Cyclohexanone

 

3

F1

III

Mixture of hydrocarbons

1917

Ethyl acrylate, stabilized

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1919

Methyl acrylate, stabilized

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1920

Nonanes

pure isomers and isomeric mixture, flashpoint between

23 °C and 60 °C

3

F1

III

Mixture of hydrocarbons

1935

Cyanide solution, n.o.s.

inorganic

6.1

T4

I/II/III

Water

1940

Thioglycolic acid

 

8

C3

II

Acetic acid

1986

Alcohols, flammable, toxic, n.o.s.

 

3

FT1

I/II/III

Rule for collective entries

1987

Cyclohexanol

technical pure

3

F1

III

Acetic acid

1987

Alcohols, n.o.s.

 

3

F1

II/III

Rule for collective entries

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

1988

Aldehydes, flammable, toxic, n.o.s.

 

3

FT1

I/II/III

Rule for collective entries

1989

Aldehydes, n.o.s.

 

3

F1

I/II/III

Rule for collective entries

1992

2,6-cis-Dimethyl- morpholine

 

3

FT1

III

Mixture of hydrocarbons

1992

Flammable liquid, toxic, n.o.s.

 

3

FT1

I/II/III

Rule for collective entries

1993

Propionic acid vinyl ester

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1993

(1-Methoxy-2-propyl) acetate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

1993

Flammable liquid, n.o.s.

 

3

F1

I/II/III

Rule for collective entries

2014

Hydrogen peroxide, aqueous solution

with not less than 20% but not more than 60% hydrogen peroxide, stabilized as

necessary

5.1

OC1

II

Nitric acid

2022

Cresylic acid

liquid mixture containing cresols, xylenols and methyl

phenols

6.1

TC1

II

Acetic acid

2030

Hydrazine aqueous solution

with not less than 37% but not more than 64% hydrazine, by mass

8

CT1

II

Water

2030

Hydrazine hydrate

aqueous solution with 64% hydrazine

8

CT1

II

Water

2031

Nitric acid

other than red fuming, with not more than 55% pure acid

8

CO1

II

Nitric acid

2045

Isobutyraldehyde

 

3

F1

II

Mixture of hydrocarbons

2050

Diisobutylene isomeric compounds

 

3

F1

II

Mixture of hydrocarbons

2053

Methyl isobutyl carbinol

 

3

F1

III

Acetic acid

2054

Morpholine

 

8

CF1

I

Mixture of hydrocarbons

2057

Tripropylene

 

3

F1

II/III

Mixture of hydrocarbons

2058

Valeraldehyde

pure isomers and isomeric mixture

3

F1

II

Mixture of hydrocarbons

2059

Nitrocellulose solution, flammable

 

3

D

I/II/III

Rule for collective entries: Deviating from the general procedure this rule may be applied to solvents of classification code F1

2075

Chloral, anhydrous, stabilized

 

6.1

T1

II

Wetting solution

2076

Cresols, liquid

pure isomers and isomeric mixture

6.1

TC1

II

Acetic acid

2078

Toluene diisocyanate

liquid

6.1

T1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2079

Diethylenetriamine

 

8

C7

II

Mixture of hydrocarbons

2209

Formaldehyde solution

aqueous solution with 37% Form-aldehyde, methanol

content: 8-10%

8

C9

III

Acetic acid

2209

Formaldehyde solution

aqueous solution, with not less than 25% formaldehyde

8

C9

III

Water

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

2218

Acrylic acid, stabilized

 

8

CF1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2227

n-Butyl methacrylate, stabilized

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2235

Chlorobenzyl chlorides, liquid

para-Chlorobenzyl chloride

6.1

T2

III

Mixture of hydrocarbons

2241

Cycloheptane

 

3

F1

II

Mixture of hydrocarbons

2242

Cycloheptene

 

3

F1

II

Mixture of hydrocarbons

2243

Cyclohexyl acetate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

2244

Cyclopentanol

 

3

F1

III

Acetic acid

2245

Cyclopentanone

 

3

F1

III

Mixture of hydrocarbons

2247

n-Decane

 

3

F1

III

Mixture of hydrocarbons

2248

Di-n-butylamine

 

8

CF1

II

Mixture of hydrocarbons

2258

1,2-Propylenediamine

 

8

CF1

II

Mixture of hydrocarbons

and

wetting solution

2259

Triethylenetetramine

 

8

C7

II

Water

2260

Tripropylamine

 

3

FC

III

Mixture of hydrocarbons

and

wetting solution

2263

Dimethylcyclohexanes

pure isomers and isomeric mixture

3

F1

II

Mixture of hydrocarbons

2264

N,N-Dimethyl- cyclohexylamine

 

8

CF1

II

Mixture of hydrocarbons

and

wetting solution

2265

N,N-Dimethyl-formamide

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2266

Dimethyl-N-propylamine

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

2269

3,3'-Imino-dipropylamine

 

8

C7

III

Mixture of hydrocarbons

and

wetting solution

2270

Ethylamine, aqueous solution

with not less than 50% but not more than 70% ethylamine, flashpoint below 23 °C, corrosive or slightly corrosive

3

FC

II

Mixture of hydrocarbons

and

wetting solution

2275

2-Ethylbutanol

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2276

2-Ethylhexylamine

 

3

FC

III

Mixture of hydrocarbons

and

wetting solution

2277

Ethyl methacrylate, stabilized

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2278

n-Heptene

 

3

F1

II

Mixture of hydrocarbons

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

2282

Hexanols

pure isomers and isomeric mixture

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2283

Isobutyl methacrylate, stabilized

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2286

Pentamethylheptane

 

3

F1

III

Mixture of hydrocarbons

2287

Isoheptenes

 

3

F1

II

Mixture of hydrocarbons

2288

Isohexenes

 

3

F1

II

Mixture of hydrocarbons

2289

Isophoronediamine

 

8

C7

III

Mixture of hydrocarbons

and

wetting solution

2293

4-Methoxy-4-methyl- pentan-2-one

 

3

F1

III

Mixture of hydrocarbons

2296

Methylcyclohexane

 

3

F1

II

Mixture of hydrocarbons

2297

Methylcyclohexanone

pure isomers and isomeric mixture

3

F1

III

Mixture of hydrocarbons

2298

Methylcyclopentane

 

3

F1

II

Mixture of hydrocarbons

2302

5-Methylhexan-2-one

 

3

F1

III

Mixture of hydrocarbons

2308

Nitrosylsulphuric acid, liquid

 

8

C1

II

Water

2309

Octadienes

 

3

F1

II

Mixture of hydrocarbons

2313

Picolines

pure isomers and isomeric mixture

3

F1

III

Mixture of hydrocarbons

2317

Sodium cuprocyanide solution

aqueous solution

6.1

T4

I

Water

2320

Tetraethylenepentamine

 

8

C7

III

Mixture of hydrocarbons

and

wetting solution

2324

Triisobutylene

mixture of C12-mono- olefines, flashpoint between

23 °C and 60 °C

3

F1

III

Mixture of hydrocarbons

2326

Trimethyl- cyclohexylamine

 

8

C7

III

Mixture of hydrocarbons

and

wetting solution

2327

Trimethylhexamethylene- diamines

pure isomers and isomeric mixture

8

C7

III

Mixture of hydrocarbons

and

wetting solution

2330

Undecane

 

3

F1

III

Mixture of hydrocarbons

2336

Allyl formate

 

3

FT1

I

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

2348

Butyl acrylates, stabilized

pure isomers and isomeric mixture

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2357

Cyclohexylamine

flashpoint between 23 °C and 60 °C

8

CF1

II

Mixture of hydrocarbons

and

wetting solution

2361

Diisobutylamine

 

3

FC

III

Mixture of hydrocarbons

and

wetting solution

2366

Diethyl carbonate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

2367

alpha-Methyl- valeraldehyde

 

3

F1

II

Mixture of hydrocarbons

2370

1-Hexene

 

3

F1

II

Mixture of hydrocarbons

2372

1,2-Di-(dimethylamino)- ethane

 

3

F1

II

Mixture of hydrocarbons

and

wetting solution

2379

1,3-Dimethylbutylamine

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

2383

Dipropylamine

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

2385

Ethyl isobutyrate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2393

Isobutyl formate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

2394

Isobutyl propionate

flashpoint between 23 °C and 60 °C

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2396

Methacrylaldehyde, stabilized

 

3

FT1

II

Mixture of hydrocarbons

2400

Methyl isovalerate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2401

Piperidine

 

8

CF1

I

Mixture of hydrocarbons

and

wetting solution

2403

Isopropenyl acetate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2405

Isopropyl butyrate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2406

Isopropyl isobutyrate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2409

Isopropyl propionate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2410

1,2,3,6-Tetrahydro- pyridine

 

3

F1

II

Mixture of hydrocarbons

2427

Potassium chlorate, aqueous solution

 

5.1

O1

II/III

Water

2428

Sodium chlorate, aqueous solution

 

5.1

O1

II/III

Water

2429

Calcium chlorate, aqueous solution

 

5.1

O1

II/III

Water

2436

Thioacetic acid

 

3

F1

II

Acetic acid

2457

2,3-Dimethylbutane

 

3

F1

II

Mixture of hydrocarbons

2491

Ethanolamine

 

8

C7

III

Wetting solution

2491

Ethanolamine solution

aqueous solution

8

C7

III

Wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

2496

Propionic anhydride

 

8

C3

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2524

Ethyl orthoformate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2526

Furfurylamine

 

3

FC

III

Mixture of hydrocarbons

and

wetting solution

2527

Isobutyl acrylate, stabilized

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2528

Isobutyl isobutyrate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

2529

Isobutyric acid

 

3

FC

III

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

2531

Methacrylic acid, stabilized

 

8

C3

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2542

Tributylamine

 

6.1

T1

II

Mixture of hydrocarbons

2560

2-Methylpentan-2-ol

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2564

Trichloroacetic acid solution

aqueous solution

8

C3

II/III

Acetic acid

2565

Dicyclohexylamine

 

8

C7

III

Mixture of hydrocarbons

and

wetting solution

2571

Ethylsulphuric acid

 

8

C3

II

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

2571

Alkylsulphuric acids

 

8

C3

II

Rule for collective entries

2580

Aluminium bromide solution

aqueous solution

8

C1

III

Water

2581

Aluminium chloride solution

aqueous solution

8

C1

III

Water

2582

Ferric chloride solution

aqueous solution

8

C1

III

Water

2584

Methane sulphonic acid

with more than 5% free sulphuric acid

8

C1

II

Water

2584

Alkylsulphonic acids, liquid

with more than 5% free sulphuric acid

8

C1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2584

Benzene sulphonic acid

with more than 5% free sulphuric acid

8

C1

II

Water

2584

Toluene sulphonic acids

with more than 5% free sulphuric acid

8

C1

II

Water

2584

Arylsulphonic acids, liquid

with more than 5% free sulphuric acid

8

C1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2586

Methane sulfonic acid

with not more than 5% free sulphuric acid

8

C1

III

Water

2586

Alkylsulphonic acids, liquid

with not more than 5% free sulphuric acid

8

C1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

2586

Benzene sulphonic acid

with not more than 5% free sulphuric acid

8

C1

III

Water

2586

Toluene sulphonic acids

with not more than 5% free sulphuric acid

8

C1

III

Water

2586

Arylsulphonic acids, liquid

with not more than 5% free sulphuric acid

8

C1

III

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

2610

Triallylamine

 

3

FC

III

Mixture of hydrocarbons

and

wetting solution

2614

Methallyl alcohol

 

3

F1

III

Acetic acid

2617

Methylcyclohexanols

pure isomers and isomeric mixture, flashpoint between

23 °C and 60 °C

3

F1

III

Acetic acid

2619

Benzyldimethylamine

 

8

CF1

II

Mixture of hydrocarbons

and

wetting solution

2620

Amyl butyrates

pure isomers and isomeric mixture, flashpoint between

23 °C and 60 °C

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2622

Glycidaldehyde

flashpoint below 23 °C

3

FT1

II

Mixture of hydrocarbons

2626

Chloric acid, aqueous solution

with not more than 10% chloric acid

5.1

O1

II

Nitric acid

2656

Quinoline

flashpoint more than 60 °C

6.1

T1

III

Water

2672

Ammonia solution

relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35%

ammonia

8

C5

III

Water

2683

Ammonium sulphide solution

aqueous solution, flashpoint between 23 °C and 60 °C

8

CFT

II

Acetic acid

2684

3-Diethylamino- propylamine

 

3

FC

III

Mixture of hydrocarbons

and

wetting solution

2685

N,N-Diethylethylene- diamine

 

8

CF1

II

Mixture of hydrocarbons

and

wetting solution

2693

Bisulphites, aqueous solution, n.o.s.

inorganic

8

C1

III

Water

2707

Dimethyldioxanes

pure isomers and isomeric mixture

3

F1

II/III

Mixture of hydrocarbons

2733

Amines, flammable, corrosive , n.o.s.

or

Polyamines, flammable, corrosive, n.o.s.

 

3

FC

I/II/III

Mixture of hydrocarbons

and

wetting solution

2734

Di-sec-butylamine

 

8

CF1

II

Mixture of hydrocarbons

2734

Amines, liquid, corrosive, flammable, n.o.s.

or

Polyamines, liquid, corrosive, flammable, n.o.s.

 

8

CF1

I/II

Mixture of hydrocarbons

and

wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

2735

Amines, liquid, corrosive, n.o.s.

or

Polyamines, liquid, corrosive, n.o.s.

 

8

C7

I/II/III

Mixture of hydrocarbons

and

wetting solution

2739

Butyric anhydride

 

8

C3

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2789

Acetic acid, glacial

or

Acetic acid solution

aqueous solution, more than 80% acid, by mass

8

CF1

II

Acetic acid

2790

Acetic acid solution

aqueous solution, more than 10% but not more than 80%

acid, by mass

8

C3

II/III

Acetic acid

2796

Sulphuric acid

with not more than 51% pure acid

8

C1

II

Water

2797

Battery fluid, alkali

Potassium/Sodium hydroxide, aqueous solution

8

C5

II

Water

2810

2-Chloro-6-fluorobenzyl chloride

stabilized

6.1

T1

III

Mixture of hydrocarbons

2810

2-Phenylethanol

 

6.1

T1

III

Acetic acid

2810

Ethylene glycol monohexyl ether

 

6.1

T1

III

Acetic acid

2810

Toxic liquid, organic, n.o.s.

 

6.1

T1

I/II/III

Rule for collective entries

2815

N-Aminoethylpiperazine

 

8

CT1

III

Mixture of hydrocarbons

and

wetting solution

2818

Ammonium polysulphide solution

aqueous solution

8

CT1

II/III

Acetic acid

2819

Amyl acid phosphate

 

8

C3

III

Wetting solution

2820

Butyric acid

n-Butyric acid

8

C3

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2821

Phenol solution

aqueous solution, toxic, non- alkaline

6.1

T1

II/III

Acetic acid

2829

Caproic acid

n-Caproic acid

8

C3

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2837

Bisulphates, aqueous solution

 

8

C1

II/III

Water

2838

Vinyl butyrate, stabilized

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2841

Di-n-amylamine

 

3

FT1

III

Mixture of hydrocarbons

and

wetting solution

2850

Propylene tetramer

mixture of C12- monoolefines, flashpoint between 23 °C and 60 °C

3

F1

III

Mixture of hydrocarbons

2873

Dibutylaminoethanol

N,N-Di-n-

butylaminoethanol

6.1

T1

III

Acetic acid

2874

Furfuryl alcohol

 

6.1

T1

III

Acetic acid

2920

O,O-Diethyl- dithiophosphoric acid

flashpoint between 23 °C and 60 °C

8

CF1

II

n-Butylacetate/

n-Butylacetate-saturated wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

2920

O,O-Dimethyl- dithiophosphoric acid

flashpoint between 23 °C and 60 °C

8

CF1

II

Wetting solution

2920

Hydrogen bromide

33% solution in glacial acetic acid

8

CF1

II

Wetting solution

2920

Tetramethylammonium hydroxide

aqueous solution, flashpoint between 23 °C and 60 °C

8

CF1

II

Water

2920

Corrosive liquid, flammable, n.o.s.

 

8

CF1

I/II

Rule for collective entries

2922

Ammonium sulphide

aqueous solution, flashpoint more than 60 °C

8

CT1

II

Water

2922

Cresols

aqueous alkaline solution, mixture of sodium and

potassium cresolate,

8

CT1

II

Acetic acid

2922

Phenol

aqueous alkaline solution, mixture of sodium and

potassium phenolate

8

CT1

II

Acetic acid

2922

Sodium hydrogen difluoride

aqueous solution

8

CT1

III

Water

2922

Corrosive liquid, toxic, n.o.s.

 

8

CT1

I/II/III

Rule for collective entries

2924

Flammable liquid, corrosive, n.o.s.

slightly corrosive

3

FC

I/II/III

Rule for collective entries

2927

Toxic liquid, corrosive, organic, n.o.s.

 

6.1

TC1

I/II

Rule for collective entries

2933

Methyl 2-chloro- propionate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2934

Isopropyl 2-chloro- propionate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

2935

Ethyl 2-chloropropionate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2936

Thiolactic acid

 

6.1

T1

II

Acetic acid

2941

Fluoroanilines

pure isomers and isomeric mixture

6.1

T1

III

Acetic acid

2943

Tetrahydrofurfurylamine

 

3

F1

III

Mixture of hydrocarbons

2945

N-Methylbutylamine

 

3

FC

II

Mixture of hydrocarbons

and

wetting solution

2946

2-Amino-5-diethyl- aminopentane

 

6.1

T1

III

Mixture of hydrocarbons

and

wetting solution

2947

Isopropyl chloroacetate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

2984

Hydrogen peroxide, aqueous solution

with not less than 8% but less than 20% hydrogen peroxide, stabilized as

necessary

5.1

O1

III

Nitric acid

3056

n-Heptaldehyde

 

3

F1

III

Mixture of hydrocarbons

3065

Alcoholic beverages

with more than 24% alcohol by volume

3

F1

II/III

Acetic acid

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

3066

Paint

or

Paint related material

including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base

or

including paint thinning and reducing compound

8

C9

II/III

Rule for collective entries

3079

Methacrylonitrile, stabilized

 

6.1

TF1

I

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3082

sec-Alcohol C6-C17poly (3-6) ethoxylate

 

9

M6

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

3082

Alcohol C12-C15poly (1-3) ethoxylate

 

9

M6

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

3082

Alcohol C13-C15poly (1-6) ethoxylate

 

9

M6

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

3082

Aviation turbine fuel JP-5

flashpoint more than 60 °C

9

M6

III

Mixture of hydrocarbons

3082

Aviation turbine fuel JP-7

flashpoint more than 60 °C

9

M6

III

Mixture of hydrocarbons

3082

Coal tar

flashpoint more than 60 °C

9

M6

III

Mixture of hydrocarbons

3082

Coal tar naphtha

flashpoint more than 60 °C

9

M6

III

Mixture of hydrocarbons

3082

Creosote produced of coal tar

flashpoint more than 60 °C

9

M6

III

Mixture of hydrocarbons

3082

Creosote produced of wood tar

flashpoint more than 60 °C

9

M6

III

Mixture of hydrocarbons

3082

Cresyl diphenyl phosphate

 

9

M6

III

Wetting solution

3082

Decyl acrylate

 

9

M6

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

3082

Diisobutyl phthalate

 

9

M6

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

3082

Di-n-butyl phthalate

 

9

M6

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

3082

Hydrocarbons

liquid, flashpoint more than 60 °C, environmentally

hazardous

9

M6

III

Rule for collective entries

3082

Isodecyl diphenyl phosphate

 

9

M6

III

Wetting solution

3082

Methylnaphthalenes

isomeric mixture, liquid

9

M6

III

Mixture of hydrocarbons

3082

Triaryl phosphates

n.o.s.

9

M6

III

Wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

3082

Tricresyl phosphate

with not more than 3% ortho-isomer

9

M6

III

Wetting solution

3082

Trixylenyl phosphate

 

9

M6

III

Wetting solution

3082

Zinc alkyl dithiophosphate

C3-C14

9

M6

III

Wetting solution

3082

Zinc aryl dithiophosphate

C7-C16

9

M6

III

Wetting solution

3082

Environmentally hazardous substance,

liquid, n.o.s.

 

9

M6

III

Rule for collective entries

3099

Oxidizing liquid, toxic, n.o.s.

 

5.1

OT1

I/II/III

Rule for collective entries

3101

3103

3105

3107

3109

3111

3113

3115

3117

3119

Organic Peroxide, Type B,

C, D, E or F, liquid

or

Organic Peroxide, Type B, C, D, E or F, liquid, temperature controlled

 

5.2

P1

 

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

and

mixture of hydrocarbons

and

nitric acid**

** For UN Nos. 3101, 3103, 3105, 3107, 3109, 3111, 3113, 3115, 3117, 3119 (tert-butyl hydroperoxide with more than 40% peroxide content and peroxyacetic acids are excluded): All organic peroxides in a technically pure form or in solution in solvents which, as far as their compatibility is concerned, are covered by the standard liquid "mixture of hydrocarbons" in this list. Compatibility of vents and gaskets with organic peroxides may be verified, also independently of the design type test, by laboratory tests with nitric acid.

3145

Butylphenols

liquid, n.o.s.

8

C3

I/II/III

Acetic acid

3145

Alkylphenols, liquid, n.o.s.

including C2 to C12 homologues

8

C3

I/II/III

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

3149

Hydrogen peroxide and peroxyacetic acid mixture, stabilized

with UN 2790 acetic acid, UN 2796 sulphuric acid and/or UN 1805 phosphoric acid, water and not more

than 5% peroxyacetic acid

5.1

OC1

II

Wetting solution

and

nitric acid

3210

Chlorates, inorganic, aqueous solution, n.o.s.

 

5.1

O1

II/III

Water

3211

Perchlorates, inorganic, aqueous solution, n.o.s.

 

5.1

O1

II/III

Water

3213

Bromates, inorganic, aqueous solution, n.o.s.

 

5.1

O1

II/III

Water

3214

Permanganates, inorganic, aqueous solution, n.o.s.

 

5.1

O1

II

Water

3216

Persulphates, inorganic, aqueous solution, n.o.s.

 

5.1

O1

III

Wetting solution

3218

Nitrates, inorganic, aqueous solution, n.o.s.

 

5.1

O1

II/III

Water

3219

Nitrites, inorganic, aqueous solution, n.o.s.

 

5.1

O1

II/III

Water

3264

Cupric chloride

aqueous solution, slightly corrosive

8

C1

III

Water

3264

Hydroxylamine sulphate

25% aqueous solution

8

C1

III

Water

3264

Phosphorous acid

aqueous solution

8

C1

III

Water

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

3264

Corrosive liquid, acidic, inorganic, n.o.s.

flashpoint more than 60 °C

8

C1

I/II/III

Rule for collective entries; not applicable to mixtures having components of UN Nos.: 1830, 1832, 1906 and

2308

3265

Methoxyacetic acid

 

8

C3

I

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3265

Allyl succinic acid anhydride

 

8

C3

II

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

3265

Dithioglycolic acid

 

8

C3

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3265

Butyl phosphate

mixture of mono- and di- butyl phosphate

8

C3

III

Wetting solution

3265

Caprylic acid

 

8

C3

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3265

Isovaleric acid

 

8

C3

III

n-Butyl acetate/

n-butyl acetate-saturated

wetting solution

3265

Pelargonic acid

 

8

C3

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3265

Pyruvic acid

 

8

C3

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3265

Valeric acid

 

8

C3

III

Acetic acid

3265

Corrosive liquid, acidic, organic, n.o.s.

flashpoint more than 60 °C

8

C3

I/II/III

Rule for collective entries

3266

Sodium hydrosulphide

aqueous solution

8

C5

II

Acetic acid

3266

Sodium sulphide

aqueous solution, slightly corrosive

8

C5

III

Acetic acid

3266

Corrosive liquid, basic, inorganic, n.o.s.

flashpoint more than 60 °C

8

C5

I/II/III

Rule for collective entries

3267

2,2'-(Butylimino)- bisethanol

 

8

C7

II

Mixture of hydrocarbons

and

wetting solution

3267

Corrosive liquid, basic, organic, n.o.s.

flashpoint more than 60 °C

8

C7

I/II/III

Rule for collective entries

3271

Ethylene glycol monobutyl ether

flashpoint 60 °C

3

F1

III

Acetic acid

3271

Ether, n.o.s.

 

3

F1

II/III

Rule for collective entries

3272

Acrylic acid tert-butyl ester

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3272

Isobutyl propionate

flashpoint below 23 °C

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3272

Methyl valerate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3272

Trimethyl ortho-formate

 

3

F1

II

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

UN

No.

Proper shipping name

or technical name

Description

Class

Classifi- cation Code

Packing group

Standard liquid

 

3.1.2

3.1.2

2.2

2.2

2.1.1.3

 

(1)

(2a)

(2b)

(3a)

(3b)

(4)

(5)

3272

Ethyl valerate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3272

Isobutyl isovalerate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3272

n-Amyl propionate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3272

n-Butylbutyrate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3272

Methyl lactate

 

3

F1

III

n-Butyl acetate/

n-butyl acetate-saturated wetting solution

3272

Ester, n.o.s.

 

3

F1

II/III

Rule for collective entries

3287

Sodium nitrite

40% aqueous solution

6.1

T4

III

Water

3287

Toxic liquid, inorganic, n.o.s.

 

6.1

T4

I/II/III

Rule for collective entries

3291

Clinical waste, unspecified, n.o.s.

liquid

6.2

I3

II

Water

3293

Hydrazine, aqueous solution

with not more than 37% hydrazine, by mass

6.1

T4

III

Water

3295

Heptenes

n.o.s

3

F1

II

Mixture of hydrocarbons

3295

Nonanes

flashpoint below 23 °C

3

F1

II

Mixture of hydrocarbons

3295

Decanes

n.o.s

3

F1

III

Mixture of hydrocarbons

3295

1,2,3-Trimethylbenzene

 

3

F1

III

Mixture of hydrocarbons

3295

Hydrocarbons, liquid, n.o.s.

 

3

F1

I/II/III

Rule for collective entries

3405

Barium chlorate, solution

aqueous solution

5.1

OT1

II/III

Water

3406

Barium perchlorate, solution

aqueous solution

5.1

OT1

II/III

Water

3408

Lead perchlorate, solution

aqueous solution

5.1

OT1

II/III

Water

3413

Potassium cyanide, solution

aqueous solution

6.1

T4

I/II/III

Water

3414

Sodium cyanide, solution

aqueous solution

6.1

T4

I/II/III

Water

3415

Sodium fluoride, solution

aqueous solution

6.1

T4

III

Water

3422

Potassium fluoride, solution

aqueous solution

6.1

T4

III

Water

Additional general provisions for the use of IBCs

When IBCs are used for the carriage of liquids with a flash-point of 60 °C (closed cup) or lower, or of powders liable to dust explosion, measures shall be taken to prevent a dangerous electrostatic discharge.

Every metal, rigid plastics and composite IBC, shall be inspected and tested, as relevant, in accordance with 6.5.4.4 or 6.5.4.5:

- before it is put into service;

- thereafter at intervals not exceeding two and a half and five years, as appropriate;

- after the repair or remanufacture, before it is re-used for carriage.

An IBC shall not be filled and offered for carriage after the date of expiry of the last periodic test or inspection. However, an IBC filled prior to the date of expiry of the last periodic test or inspection may be carried for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection. In addition, an IBC may be carried after the date of expiry of the last periodic test or inspection:

(a) after emptying but before cleaning, for purposes of performing the required test or inspection prior to refilling; and

(b) unless otherwise approved by the competent authority, for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection in order to allow the return of dangerous goods or residues for proper disposal or recycling.

NOTE: For the particulars in the transport document, see 5.4.1.1.11.

IBCs of type 31HZ2 shall be filled to at least 80% of the volume of the outer casing.

Except for routine maintenance of metal, rigid plastics, composite and flexible IBCs performed by the owner of the IBC, whose State and name or authorized symbol is durably marked on the IBC, the party performing routine maintenance shall durably mark the IBC near the manufacturer's UN design type mark to show:

(a) The State in which the routine maintenance was carried out; and

(b) The name or authorized symbol of the party performing the routine maintenance.

General provisions concerning packing instructions

Packing instructions applicable to dangerous goods of Classes 1 to 9 are specified in Section 4.1.4. They are subdivided in three sub-sections depending on the type of packagings to which they apply:

Sub-section 4.1.4.1 for packagings other than IBCs and large packagings; these packing instructions are designated by an alphanumeric code starting with the letter "P" or "R" for packagings specific to RID and ADR;

Sub-section 4.1.4.2 for IBCs; these are designated by an alphanumeric code starting with the letters "IBCs";

Sub-section 4.1.4.3 for large packagings; these are designated by an alphanumeric code starting with the letters "LP".

Generally, packing instructions specify that the general provisions of 4.1.1, 4.1.2 or 4.1.3, as appropriate, are applicable. They may also require compliance with the special provisions of Sections 4.1.5, 4.1.6, 4.1.7, 4.1.8 or 4.1.9 when appropriate. Special packing provisions may also be specified in the packing instruction for individual substances or articles. They are also designated by an alphanumeric code comprising the letters:

"PP" for packagings other than IBCs and large packagings, or "RR" for special provisions specific to RID and ADR;

"B" for IBCs or "BB" for special packing provisions specific to RID and ADR; "L" for large packagings or "LL" for special packing provisions specific to ADR.

Unless otherwise specified, each packaging shall conform to the applicable requirements of Part 6. Generally packing instructions do not provide guidance on compatibility and the user shall not select a packaging without checking that the substance is compatible with the packaging material selected (e.g. glass receptacles are unsuitable for most fluorides). Where glass receptacles are permitted in the packing instructions porcelain, earthenware and stoneware packagings are also allowed.

Column (8) of Table A of Chapter 3.2 shows for each article or substance the packing instruction(s) that shall be used. Columns (9a) and (9b) indicate the special packing provisions and the mixed packing provisions (see 4.1.10) applicable to specific substances or articles.

Each packing instruction shows, where applicable, the acceptable single and combination packagings. For combination packagings, the acceptable outer packagings, inner packagings and when applicable the maximum quantity permitted in each inner or outer packaging, are shown. Maximum net mass and maximum capacity are as defined in 1.2.1.

The following packagings shall not be used when the substances being carried are liable to become liquid during carriage:

Packagings

Drums: 1D and 1G

Boxes: 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1 and 4H2

Bags: 5L1, 5L2, 5L3, 5H1, 5H2, 5H3, 5H4, 5M1 and 5M2

Composite packagings: 6HC, 6HD2, 6HG1, 6HG2, 6HD1, 6PC, 6PD1, 6PD2, 6PG1, 6PG2

and 6PH1

Large packagings

Flexible plastics: 51H (outer packaging) IBCs

For substances of packing group I: All types of IBC For substances of packing groups II and III:

Wooden: 11C, 11D and 11F

Fibreboard: 11G

Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2

Composite: 11HZ2 and 21HZ2

For the purposes of this paragraph, substances and mixtures of substances having a melting point equal to or less than 45 °C shall be treated as solids liable to become liquid during carriage.

Where the packing instructions in this Chapter authorize the use of a particular type of packaging (e.g. 4G; 1A2), packagings bearing the same packaging identification code followed by the letters "V", "U" or "W" marked in accordance with the requirements of Part 6 (e.g. 4GV, 4GU or 4GW; 1A2V, 1A2U or 1A2W) may also be used under the same conditions and limitations applicable to the use of that type of packaging according to the relevant packing instructions. For example, a combination packaging marked with the packaging code "4GV" may be used whenever a combination packaging marked "4G" is authorized, provided the requirements in the relevant packing instruction regarding types of inner packagings and quantity limitations are respected.

Pressure receptacles for liquids and solids

Unless otherwise indicated in ADR, pressure receptacles conforming to:

(a)    the applicable requirements of Chapter 6.2; or

(b)    the national or international standards on the design, construction, testing, manufacturing and inspection, as applied by the country in which the pressure receptacles are manufactured, provided that the provisions of 4.1.3.6 are met, and that, for metallic cylinders, tubes, pressure drums, bundles of cylinders and salvage pressure receptacles, the construction is such that the minimum burst ratio (burst pressure divided by test pressure) is:

(i)    1.50 for refillable pressure receptacles;

(ii)    2.00 for non-refillable pressure receptacles,

are authorized for the carriage of any liquid or solid substance other than explosives, thermally unstable substances, organic peroxides, self-reactive substances, substances where significant pressure may develop by evolution of chemical reaction and radioactive material (unless permitted in 4.1.9).

This sub-section is not applicable to the substances mentioned in 4.1.4.1, packing instruction P200, table 3.

Every design type of pressure receptacle shall be approved by the competent authority of the country of manufacture or as indicated in Chapter 6.2.

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