list of currently assigned self-reactive substances in packagings
in the column "packing method" codes "op1" to "op8" refer to packing methods in 4.1.4.1, packing instruction p520 (see also 4.1.7.1). self-reactive substances to be carried shall fulfil the classification and the control and emergency temperatures (derived from the sadt) as listed. for substances permitted in ibcs, see 4.1.4.2, packing instruction ibc520 and, for those permitted in tanks according to chapter 4.2, see 4.2.5.2.6, portable tank instruction t23. the formulations listed in packing instruction ibc520 of 4.1.4.2 and in portable tank instruction t23 of 4.2.5.2.6 may also be carried packed in accordance with packing method op8 of packing instruction p520 of 4.1.4.1, with the same control and emergency temperatures, if applicable.
note: the classification given in this table is based on the technically pure substance (except where a concentration of less than 100% is specified). for other concentrations, the substance may be classified differently following the procedures given in part ii of the manual of tests and criteria and in 2.2.41.1.17.
|
self-reactive substance |
concen- tration (%) |
packing method |
control tempera- ture (°c) |
emergency tempera- ture (°c) |
un generic entry |
remarks |
|
acetone-pyrogallol copolymer 2-diazo-1-naphthol-5-sulphonate |
100 |
op8 |
|
|
3228 |
|
|
azodicarbonamide formulation type b, temperature controlled |
< 100 |
op5 |
|
|
3232 |
(1) (2) |
|
azodicarbonamide formulation type c |
< 100 |
op6 |
|
|
3224 |
(3) |
|
azodicarbonamide formulation type c, temperature controlled |
< 100 |
op6 |
|
|
3234 |
(4) |
|
azodicarbonamide formulation type d |
< 100 |
op7 |
|
|
3226 |
(5) |
|
azodicarbonamide formulation type d, temperature controlled |
< 100 |
op7 |
|
|
3236 |
(6) |
|
2,2' -azodi(2,4-dimethyl- 4-methoxy- valeronitrile) |
100 |
op7 |
-5 |
+5 |
3236 |
|
|
2,2' -azodi(2,4-dimethyl- valeronitrile) |
100 |
op7 |
+10 |
+15 |
3236 |
|
|
2,2' -azodi(ethyl- 2-methyl-propionate) |
100 |
op7 |
+20 |
+25 |
3235 |
|
|
1,1-azodi(hexahydrobenzonitrile) |
100 |
op7 |
|
|
3226 |
|
|
2,2' -azodi(isobutyronitrile) |
100 |
op6 |
+40 |
+45 |
3234 |
|
|
2,2' -azodi(isobutyronitrile) as a water based paste |
50% |
op6 |
|
|
3224 |
|
|
2,2' -azodi(2-methylbutyronitrile) |
100 |
op7 |
+35 |
+40 |
3236 |
|
|
benzene-1,3-disulphonyl hydrazide, as a paste |
52 |
op7 |
|
|
3226 |
|
|
benzene sulphonyl hydrazide |
100 |
op7 |
|
|
3226 |
|
|
4-(benzyl(ethyl)amino)-3-ethoxy- benzenediazonium zinc chloride |
100 |
op7 |
|
|
3226 |
|
|
4-(benzyl(methyl)amino)-3-ethoxy- benzenediazonium zinc chloride |
100 |
op7 |
+40 |
+45 |
3236 |
|
|
3-chloro-4-diethylaminobenzene- diazonium zinc chloride |
100 |
op7 |
|
|
3226 |
|
|
self-reactive substance |
concen- tration (%) |
packing method |
control tempera- ture (°c) |
emergency tempera- ture (°c) |
un generic entry |
remarks |
|
2-diazo-1-naphthol-4-sulphonyl chloride |
100 |
op5 |
|
|
3222 |
(2) |
|
2-diazo-1-naphthol-5-sulphonyl chloride |
100 |
op5 |
|
|
3222 |
(2) |
|
2-diazo-1-naphthol sulphonic acid ester mixture, type d |
< 100 |
op7 |
|
|
3226 |
(9) |
|
2,5-dibutoxy-4-(4-morpholinyl)- benzenediazonium, tetrachlorozincate (2:1) |
100 |
op8 |
|
|
3228 |
|
|
2,5-diethoxy-4-morpholino- benzenediazonium zinc chloride |
67-100 |
op7 |
+35 |
+40 |
3236 |
|
|
2,5-diethoxy-4-morpholino- benzenediazonium zinc chloride |
66 |
op7 |
+40 |
+45 |
3236 |
|
|
2,5-diethoxy-4-morpholino- benzenediazonium tetrafluoroborate |
100 |
op7 |
+30 |
+35 |
3236 |
|
|
2,5-diethoxy-4-(4-morpholinyl)- benzenediazonium sulphate |
100 |
op7 |
|
|
3226 |
|
|
2,5-diethoxy-4-(phenylsulphonyl)- benzenediazonium zinc chloride |
67 |
op7 |
+40 |
+45 |
3236 |
|
|
diethyleneglycol bis (allyl carbonate) + di- isopropyl-peroxydicarbonate |
88+ 12 |
op8 |
-10 |
0 |
3237 |
|
|
2,5-dimethoxy-4-(4-methyl- phenylsulphonyl)benzene- diazonium zinc chloride |
79 |
op7 |
+40 |
+45 |
3236 |
|
|
4-(dimethylamino)-benzene-diazonium trichlorozincate (-1) |
100 |
op8 |
|
|
3228 |
|
|
4-dimethylamino-6-(2-dimethyl- aminoethoxy) toluene- 2-diazonium zinc chloride |
100 |
op7 |
+40 |
+45 |
3236 |
|
|
n,n'-dinitroso-n,n'- dimethyl terephthalamide, as a paste |
72 |
op6 |
|
|
3224 |
|
|
n,n'-dinitrosopentamethylene- tetramine |
82 |
op6 |
|
|
3224 |
(7) |
|
diphenyloxide-4,4'-disulphonyl hydrazide |
100 |
op7 |
|
|
3226 |
|
|
4-dipropylaminobenzene- diazonium zinc chloride |
100 |
op7 |
|
|
3226 |
|
|
2-(n,n-ethoxycarbonyl- phenylamino)-3-methoxy-4- (n-methyl-n-cyclohexylamino) benzenediazonium zinc chloride |
63-92 |
op7 |
+ 40 |
+ 45 |
3236 |
|
|
2-(n,n-ethoxycarbonyl- phenylamino)-3-methoxy-4- (n-methyl-n-cyclohexylamino) benzenediazonium zinc chloride |
62 |
op7 |
+ 35 |
+ 40 |
3236 |
|
|
n-formyl-2-(nitromethylene) -1,3-perhydrothiazine |
100 |
op7 |
+45 |
+50 |
3236 |
|
|
2-(2-hydroxyethoxy)-1- (pyrrolidin-1-yl)benzene-4- diazonium zinc chloride |
100 |
op7 |
+ 45 |
+ 50 |
3236 |
|
|
3-(2-hydroxyethoxy)-4- (pyrrolidin-1-yl) benzene diazonium zinc chloride |
100 |
op7 |
+40 |
+45 |
3236 |
|
|
2-(n,n-methylaminoethylcarbonyl)- 4-(3,4-dimethylphenylsulphonyl) benzenediazonium hydrogen sulphate |
96 |
op7 |
+45 |
+50 |
3236 |
|
|
4-methylbenzenesulphonylhydrazide |
100 |
op7 |
|
|
3226 |
|
|
self-reactive substance |
concen- tration (%) |
packing method |
control tempera- ture (°c) |
emergency tempera- ture (°c) |
un generic entry |
remarks |
|
3-methyl-4-(pyrrolidin-1-yl) benzenediazonium tetrafluoroborate |
95 |
op6 |
+45 |
+50 |
3234 |
|
|
4-nitrosophenol |
100 |
op7 |
+35 |
+40 |
3236 |
|
|
phosphorothioic acid, o-[(cyanophenyl methylene) azanyl] o,o-diethyl ester |
82-91 (z isomer) |
op8 |
|
|
3227 |
(10) |
|
self-reactive liquid, sample |
|
op2 |
|
|
3223 |
(8) |
|
self-reactive liquid, sample, temperature controlled |
|
op2 |
|
|
3233 |
(8) |
|
self-reactive solid, sample |
|
op2 |
|
|
3224 |
(8) |
|
self-reactive solid, sample, temperature controlled |
|
op2 |
|
|
3234 |
(8) |
|
sodium 2-diazo-1-naphthol- 4-sulphonate |
100 |
op7 |
|
|
3226 |
|
|
sodium 2-diazo-1-naphthol- 5-sulphonate |
100 |
op7 |
|
|
3226 |
|
|
tetramine palladium (ii) nitrate |
100 |
op6 |
+30 |
+35 |
3234 |
|
remarks
(1) azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (b) of the manual of tests and criteria. the control and emergency temperatures shall be determined by the procedure given in 7.1.7.3.1 to 7.1.7.3.6.
(2) "explosive" subsidiary hazard label required (model no. 1, see 5.2.2.2.2).
(3) azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (c) of the manual of tests and criteria.
(4) azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (c) of the manual of tests and criteria. the control and emergency temperatures shall be determined by the procedure given in 7.1.7.3.1 to 7.1.7.3.6.
(5) azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (d) of the manual of tests and criteria.
(6) azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (d) of the manual of tests and criteria. the control and emergency temperatures shall be determined by the procedure given in 7.1.7.3.1 to 7.1.7.3.6.
(7) with a compatible diluent having a boiling point of not less than 150 °c.
(8) see 2.2.41.1.15.
(9) this entry applies to mixtures of esters of 2-diazo-1-naphthol-4-sulphonic acid and 2-diazo-1-naphthol-5-sulphonic acid which fulfil the criteria of paragraph 20.4.2 (d) of the manual of test and criteria.
(10) this entry applies to the technical mixture in n-butanol within the specified concentration limits of the (z) isomer.