in the column "packing method", codes "op1" to "op8" refer to packing methods in 4.1.4.1, packing instruction p520 (see also 4.1.7.1). organic peroxides to be carried shall fulfil the classification and the control and emergency temperatures (derived from the sadt) as listed. for substances permitted in ibcs, see 4.1.4.2, packing instruction ibc520 and, for those permitted in tanks according to chapters 4.2 and 4.3, see 4.2.5.2.6, portable tank instruction t23. the formulations listed in packing instruction ibc520 of 4.1.4.2 and in portable tank instruction t23 of 4.2.5.2.6 may also be carried packed in accordance with packing method op8 of packing instruction p520 of 4.1.4.1, with the same control and emergency temperatures, if applicable.
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
acetyl acetone peroxide |
≤ 42 |
≥ 48 |
|
|
≥8 |
op7 |
|
|
3105 |
2) |
" |
≤ 32 as a paste |
|
|
|
|
op7 |
|
|
3106 |
20) |
acetyl cyclohexanesulphonyl peroxide |
≤ 82 |
|
|
|
≥ 12 |
op4 |
-10 |
0 |
3112 |
3) |
" |
≤ 32 |
|
≥ 68 |
|
|
op7 |
-10 |
0 |
3115 |
|
tert-amyl hydroperoxide |
≤ 88 |
≥ 6 |
|
|
≥ 6 |
op8 |
|
|
3107 |
|
tert-amyl peroxyacetate |
≤ 62 |
≥ 38 |
|
|
|
op7 |
|
|
3105 |
|
tert-amyl peroxybenzoate |
≤ 100 |
|
|
|
|
op5 |
|
|
3103 |
|
tert-amyl peroxy-2-ethylhexanoate |
≤ 100 |
|
|
|
|
op7 |
+20 |
+25 |
3115 |
|
tert-amyl peroxy-2-ethylhexyl carbonate |
≤ 100 |
|
|
|
|
op7 |
|
|
3105 |
|
tert-amyl peroxy isopropyl carbonate |
77 |
23 |
|
|
|
op5 |
|
|
3103 |
|
tert-amyl peroxyneodecanoate |
≤ 77 |
|
≥ 23 |
|
|
op7 |
0 |
+10 |
3115 |
|
" |
≤ 47 |
≥ 53 |
|
|
|
op8 |
0 |
+ 10 |
3119 |
|
tert-amyl peroxypivalate |
≤ 77 |
|
≥ 23 |
|
|
op5 |
+10 |
+15 |
3113 |
|
tert-amylperoxy-3,5,5-trimethylhexanoate |
≤ 100 |
|
|
|
|
op7 |
|
|
3105 |
|
tert-butyl cumyl peroxide |
> 42 - 100 |
|
|
|
|
op8 |
|
|
3109 |
|
" |
≤ 52 |
|
|
≥ 48 |
|
op8 |
|
|
3108 |
|
n-butyl-4,4-di-(tert-butylperoxy)valerate |
> 52 - 100 |
|
|
|
|
op5 |
|
|
3103 |
|
" |
≤ 52 |
|
|
≥ 48 |
|
op8 |
|
|
3108 |
|
tert-butyl hydroperoxide |
>79 - 90 |
|
|
|
≥ 10 |
op5 |
|
|
3103 |
13) |
" |
≤ 80 |
≥ 20 |
|
|
|
op7 |
|
|
3105 |
4) 13) |
" |
≤ 79 |
|
|
|
> 14 |
op8 |
|
|
3107 |
13) 23) |
" |
≤ 72 |
|
|
|
≥ 28 |
op8 |
|
|
3109 |
13) |
tert-butyl hydroperoxide + di-tert-butylperoxide |
< 82 + >9 |
|
|
|
≥ 7 |
op5 |
|
|
3103 |
13) |
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
tert-butyl monoperoxymaleate |
> 52 - 100 |
|
|
|
|
op5 |
|
|
3102 |
3) |
" |
≤ 52 |
≥ 48 |
|
|
|
op6 |
|
|
3103 |
|
" |
≤ 52 |
|
|
≥ 48 |
|
op8 |
|
|
3108 |
|
" |
≤ 52 as a paste |
|
|
|
|
op8 |
|
|
3108 |
|
tert-butyl peroxyacetate |
> 52 - 77 |
≥ 23 |
|
|
|
op5 |
|
|
3101 |
3) |
" |
> 32 - 52 |
≥ 48 |
|
|
|
op6 |
|
|
3103 |
|
" |
≤ 32 |
|
≥ 68 |
|
|
op8 |
|
|
3109 |
|
tert-butyl peroxybenzoate |
> 77 - 100 |
|
|
|
|
op5 |
|
|
3103 |
|
" |
> 52 - 77 |
≥23 |
|
|
|
op7 |
|
|
3105 |
|
" |
≤ 52 |
|
|
≥ 48 |
|
op7 |
|
|
3106 |
|
tert-butyl peroxybutyl fumarate |
≤ 52 |
≥ 48 |
|
|
|
op7 |
|
|
3105 |
|
tert-butyl peroxycrotonate |
≤ 77 |
≥ 23 |
|
|
|
op7 |
|
|
3105 |
|
tert-butyl peroxydiethylacetate |
≤ 100 |
|
|
|
|
op5 |
+20 |
+25 |
3113 |
|
tert-butyl peroxy-2-ethylhexanoate |
> 52 – 100 |
|
|
|
|
op6 |
+20 |
+25 |
3113 |
|
" |
> 32 - 52 |
|
≥ 48 |
|
|
op8 |
+30 |
+35 |
3117 |
|
" |
≤ 52 |
|
|
≥ 48 |
|
op8 |
+20 |
+25 |
3118 |
|
" |
≤ 32 |
|
≥ 68 |
|
|
op8 |
+40 |
+45 |
3119 |
|
tert-butyl peroxy-2-ethylhexanoate + 2,2-di-(tert-butylperoxy)butane |
≤ 12 +≤ 14 |
≥ 14 |
|
≥ 60 |
|
op7 |
|
|
3106 |
|
" |
≤ 31 + ≤ 36 |
|
≥ 33 |
|
|
op7 |
+35 |
+40 |
3115 |
|
tert-butyl peroxy-2-ethylhexylcarbonate |
≤ 100 |
|
|
|
|
op7 |
|
|
3105 |
|
tert-butyl peroxyisobutyrate |
> 52 - 77 |
|
≥ 23 |
|
|
op5 |
+15 |
+20 |
3111 |
3) |
" |
≤ 52 |
|
≥ 48 |
|
|
op7 |
+15 |
+20 |
3115 |
|
tert-butylperoxy isopropylcarbonate |
≤ 77 |
≥ 23 |
|
|
|
op5 |
|
|
3103 |
|
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
1-(2-tert-butylperoxy isopropyl)-3- isopropenylbenzene |
≤ 77 |
≥ 23 |
|
|
|
op7 |
|
|
3105 |
|
" |
≤ 42 |
|
|
≥ 58 |
|
op8 |
|
|
3108 |
|
tert-butyl peroxy-2-methylbenzoate |
≤ 100 |
|
|
|
|
op5 |
|
|
3103 |
|
tert-butyl peroxyneodecanoate |
> 77 - 100 |
|
|
|
|
op7 |
-5 |
+5 |
3115 |
|
" |
≤ 77 |
|
≥ 23 |
|
|
op7 |
0 |
+10 |
3115 |
|
" |
≤ 52 as a stable dispersion in water |
|
|
|
|
op8 |
0 |
+10 |
3119 |
|
" |
≤ 42 as a stable dispersion in water (frozen) |
|
|
|
|
op8 |
0 |
+10 |
3118 |
|
" |
≤ 32 |
≥ 68 |
|
|
|
op8 |
0 |
+10 |
3119 |
|
tert-butyl peroxyneoheptanoate |
≤ 77 |
≥ 23 |
|
|
|
op7 |
0 |
+10 |
3115 |
|
" |
42 as a stable dispersion in water |
|
|
|
|
op8 |
0 |
+10 |
3117 |
|
tert-butyl peroxypivalate |
> 67 - 77 |
≥ 23 |
|
|
|
op5 |
0 |
+10 |
3113 |
|
" |
> 27 - 67 |
|
≥ 33 |
|
|
op7 |
0 |
+10 |
3115 |
|
" |
≤ 27 |
|
≥ 73 |
|
|
op8 |
+30 |
+35 |
3119 |
|
tert-butylperoxy stearylcarbonate |
≤ 100 |
|
|
|
|
op7 |
|
|
3106 |
|
tert-butyl peroxy-3,5,5-trimethylhexanoate |
> 37 - 100 |
|
|
|
|
op7 |
|
|
3105 |
|
" |
≤ 42 |
|
|
≥ 58 |
|
op7 |
|
|
3106 |
|
" |
≤ 37 |
|
≥ 63 |
|
|
op8 |
|
|
3109 |
|
3-chloroperoxybenzoic acid |
> 57 - 86 |
|
|
≥ 14 |
|
op1 |
|
|
3102 |
3) |
" |
≤ 57 |
|
|
≥ 3 |
≥ 40 |
op7 |
|
|
3106 |
|
" |
≤ 77 |
|
|
≥ 6 |
≥ 17 |
op7 |
|
|
3106 |
|
cumyl hydroperoxide |
> 90 - 98 |
≤10 |
|
|
|
op8 |
|
|
3107 |
13) |
" |
≤ 90 |
≥ 10 |
|
|
|
op8 |
|
|
3109 |
13) 18) |
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
cumyl peroxyneodecanoate |
≤ 87 |
≥ 13 |
|
|
|
op7 |
- 10 |
0 |
3115 |
|
" |
≤ 77 |
|
≥ 23 |
|
|
op7 |
-10 |
0 |
3115 |
|
" |
≤ 52 as a stable dispersion in water |
|
|
|
|
op8 |
-10 |
0 |
3119 |
|
cumyl peroxyneoheptanoate |
≤ 77 |
≥ 23 |
|
|
|
op7 |
-10 |
0 |
3115 |
|
cumyl peroxypivalate |
≤ 77 |
|
≥ 23 |
|
|
op7 |
-5 |
+5 |
3115 |
|
cyclohexanone peroxide(s) |
≤ 91 |
|
|
|
≥ 9 |
op6 |
|
|
3104 |
13) |
" |
≤ 72 |
≥ 28 |
|
|
|
op7 |
|
|
3105 |
5) |
" |
≤ 72 as a paste |
|
|
|
|
op7 |
|
|
3106 |
5) 20) |
" |
≤ 32 |
|
|
≥ 68 |
|
|
|
|
exempt |
29) |
([3r-(3r,5as,6s,8as,9r,10r,12s,12ar**)]- decahydro-10-methoxy-3,6,9-trimethyl-3,12- epoxy-12h-pyrano[4,3-j]-1,2-benzodioxepin) |
≤ 100 |
|
|
|
|
op7 |
|
|
3106 |
|
diacetone alcohol peroxides |
≤ 57 |
|
≥ 26 |
|
≥ 8 |
op7 |
+40 |
+45 |
3115 |
6) |
diacetyl peroxide |
≤ 27 |
|
≥ 73 |
|
|
op7 |
+20 |
+25 |
3115 |
7) 13) |
di-tert-amyl peroxide |
≤ 100 |
|
|
|
|
op8 |
|
|
3107 |
|
2,2-di-(tert-amylperoxy)butane |
≤ 57 |
≥ 43 |
|
|
|
op7 |
|
|
3105 |
|
1,1-di-(tert-amylperoxy)cyclohexane |
≤ 82 |
≥ 18 |
|
|
|
op6 |
|
|
3103 |
|
dibenzoyl peroxide |
> 52 - 100 |
|
|
≤ 48 |
|
op2 |
|
|
3102 |
3) |
" |
> 77 - 94 |
|
|
|
≥ 6 |
op4 |
|
|
3102 |
3) |
" |
≤ 77 |
|
|
|
≥ 23 |
op6 |
|
|
3104 |
|
" |
≤ 62 |
|
|
≥ 28 |
≥ 10 |
op7 |
|
|
3106 |
|
" |
> 52 – 62 as a paste |
|
|
|
|
op7 |
|
|
3106 |
20) |
" |
> 35 - 52 |
|
|
≥ 48 |
|
op7 |
|
|
3106 |
|
" |
> 36 - 42 |
≥ 18 |
|
|
≤ 40 |
op8 |
|
|
3107 |
|
" |
≤ 56.5 as a paste |
|
|
|
≥ 15 |
op8 |
|
|
3108 |
|
" |
≤ 52 as a paste |
|
|
|
|
op8 |
|
|
3108 |
20) |
" |
≤ 42 as a stable dispersion in water |
|
|
|
|
op8 |
|
|
3109 |
|
" |
≤ 35 |
|
|
≥ 65 |
|
|
|
|
exempt |
29) |
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
di-(4-tert-butylcyclohexyl) peroxydicarbonate |
≤ 100 |
|
|
|
|
op6 |
+30 |
+35 |
3114 |
|
" |
≤ 42 as a stable dispersion in water |
|
|
|
|
op8 |
+30 |
+35 |
3119 |
|
" |
≤ 42 (as a paste) |
|
|
|
|
op7 |
+35 |
+40 |
3116 |
|
di-tert-butyl peroxide |
> 52 - 100 |
|
|
|
|
op8 |
|
|
3107 |
|
" |
≤ 52 |
|
≥ 48 |
|
|
op8 |
|
|
3109 |
25) |
di-tert-butyl peroxyazelate |
≤ 52 |
≥ 48 |
|
|
|
op7 |
|
|
3105 |
|
2,2-di-(tert-butylperoxy)butane |
≤ 52 |
≥ 48 |
|
|
|
op6 |
|
|
3103 |
|
1,6-di-(tert-butylperoxycarbonyloxy) hexane |
≤ 72 |
≥ 28 |
|
|
|
op5 |
|
|
3103 |
|
1,1-di-(tert-butylperoxy) cyclohexane |
> 80 - 100 |
|
|
|
|
op5 |
|
|
3101 |
3) |
" |
≤ 72 |
|
≥ 28 |
|
|
op5 |
|
|
3103 |
30) |
" |
> 52 - 80 |
≥ 20 |
|
|
|
op5 |
|
|
3103 |
|
" |
> 42 - 52 |
≥ 48 |
|
|
|
op7 |
|
|
3105 |
|
" |
≤ 42 |
≥ 13 |
|
≥ 45 |
|
op7 |
|
|
3106 |
|
" |
≤ 42 |
≥ 58 |
|
|
|
op8 |
|
|
3109 |
|
" |
≤ 27 |
≥ 25 |
|
|
|
op8 |
|
|
3107 |
21) |
" |
≤ 13 |
≥ 13 |
≥ 74 |
|
|
op8 |
|
|
3109 |
|
1,1-di-(tert-butylperoxy) cyclohexane + tert-butyl peroxy-2-ethylhexanoate |
≤ 43 + ≤ 16 |
≥ 41 |
|
|
|
op 7 |
|
|
3105 |
|
di-n-butyl peroxydicarbonate |
> 27 - 52 |
|
≥ 48 |
|
|
op7 |
-15 |
-5 |
3115 |
|
" |
≤ 27 |
|
≥ 73 |
|
|
op8 |
-10 |
0 |
3117 |
|
" |
≤ 42 as a stable dispersion in water (frozen) |
|
|
|
|
op8 |
-15 |
-5 |
3118 |
|
di-sec-butyl peroxydicarbonate |
> 52 - 100 |
|
|
|
|
op4 |
-20 |
-10 |
3113 |
|
" |
≤ 52 |
|
≥ 48 |
|
|
op7 |
-15 |
-5 |
3115 |
|
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
di-(tert-butylperoxyisopropyl)benzene(s) |
> 42 - 100 |
|
|
≤ 57 |
|
op7 |
|
|
3106 |
|
" |
≤ 42 |
|
|
≥ 58 |
|
|
|
|
exempt |
29) |
di-(tert-butylperoxy) phthalate |
> 42 - 52 |
≥ 48 |
|
|
|
op7 |
|
|
3105 |
|
" |
≤ 52 as a paste |
|
|
|
|
op7 |
|
|
3106 |
20) |
" |
≤ 42 |
≥ 58 |
|
|
|
op8 |
|
|
3107 |
|
2,2-di-(tert-butylperoxy)propane |
≤ 52 |
≥ 48 |
|
|
|
op7 |
|
|
3105 |
|
" |
≤ 42 |
≥ 13 |
|
≥ 45 |
|
op7 |
|
|
3106 |
|
1,1-di-(tert-butylperoxy)-3,3,5- trimethylcyclohexane |
> 90 - 100 |
|
|
|
|
op5 |
|
|
3101 |
3) |
" |
≤ 90 |
|
≥ 10 |
|
|
op5 |
|
|
3103 |
30) |
" |
> 57 - 90 |
≥ 10 |
|
|
|
op5 |
|
|
3103 |
|
" |
≤ 77 |
|
≥ 23 |
|
|
op5 |
|
|
3103 |
|
" |
≤ 57 |
|
|
≥ 43 |
|
op8 |
|
|
3110 |
|
" |
≤ 57 |
≥ 43 |
|
|
|
op8 |
|
|
3107 |
|
" |
≤ 32 |
≥ 26 |
≥ 42 |
|
|
op8 |
|
|
3107 |
|
dicetyl peroxydicarbonate |
≤ 100 |
|
|
|
|
op8 |
+30 |
+35 |
3120 |
|
" |
≤ 42 as a stable dispersion in water |
|
|
|
|
op8 |
+30 |
+35 |
3119 |
|
di-4-chlorobenzoyl peroxide |
≤ 77 |
|
|
|
≥ 23 |
op5 |
|
|
3102 |
3) |
" |
≤ 52 as a paste |
|
|
|
|
op7 |
|
|
3106 |
20) |
" |
≤ 32 |
|
|
≥ 68 |
|
|
|
|
exempt |
29) |
dicumyl peroxide |
> 52 - 100 |
|
|
|
|
op8 |
|
|
3110 |
12) |
" |
≤ 52 |
|
|
≥ 48 |
|
|
|
|
exempt |
29) |
dicyclohexyl peroxydicarbonate |
> 91 - 100 |
|
|
|
|
op3 |
+10 |
+15 |
3112 |
3) |
" |
≤ 91 |
|
|
|
≥ 9 |
op5 |
+10 |
+15 |
3114 |
|
" |
42 as a stable dispersion in water |
|
|
|
|
op8 |
+15 |
+20 |
3119 |
|
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
didecanoyl peroxide |
≤ 100 |
|
|
|
|
op6 |
+30 |
+35 |
3114 |
|
2,2-di-(4,4-di (tert-butylperoxy) cyclohexyl) propane |
≤ 42 |
|
|
≥ 58 |
|
op7 |
|
|
3106 |
|
" |
≤ 22 |
|
≥ 78 |
|
|
op8 |
|
|
3107 |
|
di-2,4-dichlorobenzoyl peroxide |
≤ 77 |
|
|
|
≥ 23 |
op5 |
|
|
3102 |
3) |
" |
≤ 52 as a paste |
|
|
|
|
op8 |
+ 20 |
+ 25 |
3118 |
|
" |
≤ 52 as a paste with silicon oil |
|
|
|
|
op7 |
|
|
3106 |
|
di-(2-ethoxyethyl) peroxydicarbonate |
≤ 52 |
|
≥ 48 |
|
|
op7 |
-10 |
0 |
3115 |
|
di-(2-ethylhexyl) peroxydicarbonate |
> 77 – 100 |
|
|
|
|
op5 |
-20 |
-10 |
3113 |
|
" |
≤ 77 |
|
≥ 23 |
|
|
op7 |
-15 |
-5 |
3115 |
|
" |
≤ 62 as a stable dispersion in water |
|
|
|
|
op8 |
-15 |
-5 |
3119 |
|
" |
≤ 52 as a stable dispersion in water (frozen) |
|
|
|
|
op8 |
-15 |
-5 |
3120 |
|
2,2-dihydroperoxypropane |
≤ 27 |
|
|
≥ 73 |
|
op5 |
|
|
3102 |
3) |
di-(1-hydroxycyclohexyl) peroxide |
≤ 100 |
|
|
|
|
op7 |
|
|
3106 |
|
diisobutyryl peroxide |
> 32 – 52 |
|
≥ 48 |
|
|
op5 |
-20 |
-10 |
3111 |
3) |
" |
≤ 32 |
|
≥ 68 |
|
|
op7 |
-20 |
-10 |
3115 |
|
" |
≤ 42 (as a stable dispersion in water) |
|
|
|
|
op8 |
-20 |
-10 |
3119 |
|
diisopropylbenzene dihydroperoxide |
≤ 82 |
≥ 5 |
|
|
≥ 5 |
op7 |
|
|
3106 |
24) |
diisopropyl peroxydicarbonate |
> 52-100 |
|
|
|
|
op2 |
-15 |
-5 |
3112 |
3) |
" |
≤ 52 |
|
≥ 48 |
|
|
op7 |
-20 |
-10 |
3115 |
|
" |
≤ 32 |
≥ 68 |
|
|
|
op7 |
-15 |
-5 |
3115 |
|
dilauroyl peroxide |
≤ 100 |
|
|
|
|
op7 |
|
|
3106 |
|
" |
≤ 42 as a stable dispersion in water |
|
|
|
|
op8 |
|
|
3109 |
|
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
di-(3-methoxybutyl) peroxydicarbonate |
≤ 52 |
|
≥ 48 |
|
|
op7 |
-5 |
+5 |
3115 |
|
di-(2-methylbenzoyl) peroxide |
≤ 87 |
|
|
|
≥ 13 |
op5 |
+30 |
+35 |
3112 |
3) |
di-(3-methylbenzoyl) peroxide + benzoyl (3-methylbenzoyl) peroxide + dibenzoyl peroxide |
≤ 20 + ≤ 18 + ≤ 4 |
|
≥ 58 |
|
|
op7 |
+35 |
+40 |
3115 |
|
di-(4-methylbenzoyl) peroxide |
≤ 52 as a paste with silicon oil |
|
|
|
|
op7 |
|
|
3106 |
|
2,5-dimethyl-2,5-di- (benzoylperoxy)hexane |
> 82-100 |
|
|
|
|
op5 |
|
|
3102 |
3) |
" |
≤ 82 |
|
|
≥ 18 |
|
op7 |
|
|
3106 |
|
" |
≤ 82 |
|
|
|
≥ 18 |
op5 |
|
|
3104 |
|
2,5-dimethyl-2,5-di- (tert-butylperoxy)hexane |
> 90 - 100 |
|
|
|
|
op5 |
|
|
3103 |
|
" |
> 52 - 90 |
≥ 10 |
|
|
|
op7 |
|
|
3105 |
|
" |
≤ 77 |
|
|
≥ 23 |
|
op8 |
|
|
3108 |
|
" |
≤ 52 |
≥ 48 |
|
|
|
op8 |
|
|
3109 |
|
" |
≤ 47 as a paste |
|
|
|
|
op8 |
|
|
3108 |
|
2,5-dimethyl-2,5-di- (tert-butylperoxy)hexyne-3 |
> 86-100 |
|
|
|
|
op5 |
|
|
3101 |
3) |
" |
>52-86 |
≥ 14 |
|
|
|
op5 |
|
|
3103 |
26) |
" |
≤ 52 |
|
|
≥ 48 |
|
op7 |
|
|
3106 |
|
2,5-dimethyl-2,5-di- (2-ethylhexanoylperoxy)hexane |
≤ 100 |
|
|
|
|
op5 |
+20 |
+25 |
3113 |
|
2,5-dimethyl-2,5-dihydroperoxyhexane |
≤ 82 |
|
|
|
≥ 18 |
op6 |
|
|
3104 |
|
2,5-dimethyl-2,5-di-(3,5,5- trimethylhexanoylperoxy)hexane |
≤ 77 |
≥ 23 |
|
|
|
op7 |
|
|
3105 |
|
1,1-dimethyl-3-hydroxybutyl peroxyneoheptanoate |
≤ 52 |
≥ 48 |
|
|
|
op8 |
0 |
+10 |
3117 |
|
dimyristyl peroxydicarbonate |
≤ 100 |
|
|
|
|
op7 |
+20 |
+25 |
3116 |
|
" |
≤ 42 as a stable dispersion in water |
|
|
|
|
op8 |
+20 |
+25 |
3119 |
|
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
di-(2-neodecanoylperoxyisopropyl) benzene |
≤ 52 |
≥ 48 |
|
|
|
op7 |
-10 |
0 |
3115 |
|
di-n-nonanoyl peroxide |
≤ 100 |
|
|
|
|
op7 |
0 |
+10 |
3116 |
|
di-n-octanoyl peroxide |
≤ 100 |
|
|
|
|
op5 |
+10 |
+15 |
3114 |
|
di-(2-phenoxyethyl) peroxydicarbonate |
>85-100 |
|
|
|
|
op5 |
|
|
3102 |
3) |
" |
≤ 85 |
|
|
|
≥ 15 |
op7 |
|
|
3106 |
|
dipropionyl peroxide |
≤ 27 |
|
≥ 73 |
|
|
op8 |
+15 |
+20 |
3117 |
|
di-n-propyl peroxydicarbonate |
≤ 100 |
|
|
|
|
op3 |
-25 |
-15 |
3113 |
|
" |
≤ 77 |
|
≥ 23 |
|
|
op5 |
-20 |
-10 |
3113 |
|
disuccinic acid peroxide |
> 72-100 |
|
|
|
|
op4 |
|
|
3102 |
3) 17) |
" |
≤ 72 |
|
|
|
≥ 28 |
op7 |
+10 |
+15 |
3116 |
|
di-(3,5,5-trimethylhexanoyl) peroxide |
> 52-82 |
≥ 18 |
|
|
|
op7 |
0 |
+10 |
3115 |
|
" |
≤ 52 as a stable dispersion in water |
|
|
|
|
op8 |
+10 |
+15 |
3119 |
|
" |
> 38-52 |
≥ 48 |
|
|
|
op8 |
+10 |
+15 |
3119 |
|
" |
≤ 38 |
≥ 62 |
|
|
|
op8 |
+20 |
+25 |
3119 |
|
ethyl 3,3-di-(tert-amylperoxy)butyrate |
≤ 67 |
≥ 33 |
|
|
|
op7 |
|
|
3105 |
|
ethyl 3,3-di-(tert-butylperoxy)butyrate |
> 77 - 100 |
|
|
|
|
op5 |
|
|
3103 |
|
" |
≤ 77 |
≥ 23 |
|
|
|
op7 |
|
|
3105 |
|
" |
≤ 52 |
|
|
≥ 48 |
|
op7 |
|
|
3106 |
|
1-(2-ethylhexanoylperoxy)-1,3- dimethylbutyl peroxypivalate |
≤ 52 |
≥ 45 |
≥ 10 |
|
|
op7 |
-20 |
-10 |
3115 |
|
tert-hexyl peroxyneodecanoate |
≤ 71 |
≥ 29 |
|
|
|
op7 |
0 |
+10 |
3115 |
|
tert-hexyl peroxypivalate |
≤ 72 |
|
≥ 28 |
|
|
op7 |
+10 |
+15 |
3115 |
|
3-hydroxy-1,1-dimethylbutyl peroxyneodecanoate |
≤ 77 |
≥ 23 |
|
|
|
op 7 |
- 5 |
+ 5 |
3115 |
|
" |
≤ 52 |
≥ 48 |
|
|
|
op 8 |
- 5 |
+ 5 |
3117 |
|
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
" |
≤ 52 as a stable dispersion in water |
|
|
|
|
op 8 |
- 5 |
+ 5 |
3119 |
|
isopropyl sec-butyl peroxydicarbonate +di-sec-butyl peroxydicarbonate +di-isopropyl peroxydicarbonate |
≤ 32 + ≤ 15 – 18 ≤ 12 – 15 |
≥ 38 |
|
|
|
op7 |
-20 |
-10 |
3115 |
|
" |
≤ 52 + ≤ 28 + ≤ 22 |
|
|
|
|
op5 |
-20 |
-10 |
3111 |
3) |
isopropylcumyl hydroperoxide |
≤ 72 |
≥ 28 |
|
|
|
op8 |
|
|
3109 |
13) |
p-menthyl hydroperoxide |
> 72 - 100 |
|
|
|
|
op7 |
|
|
3105 |
13) |
" |
≤ 72 |
≥ 28 |
|
|
|
op8 |
|
|
3109 |
27) |
methylcyclohexanone peroxide(s) |
≤ 67 |
|
≥ 33 |
|
|
op7 |
+35 |
+40 |
3115 |
|
methyl ethyl ketone peroxide(s) |
see remark 8) |
≥ 48 |
|
|
|
op5 |
|
|
3101 |
3) 8) 13) |
" |
see remark 9) |
≥ 55 |
|
|
|
op7 |
|
|
3105 |
9) |
" |
see remark 10) |
≥ 60 |
|
|
|
op8 |
|
|
3107 |
10) |
methyl isobutyl ketone peroxide(s) |
≤ 62 |
≥ 19 |
|
|
|
op7 |
|
|
3105 |
22) |
methyl isopropyl ketone peroxide(s) |
see remark 31) |
≥ 70 |
|
|
|
op8 |
|
|
3109 |
31) |
organic peroxide, liquid, sample |
|
|
|
|
|
op2 |
|
|
3103 |
11) |
organic peroxide, liquid, sample, temperature controlled |
|
|
|
|
|
op2 |
|
|
3113 |
11) |
organic peroxide, solid, sample |
|
|
|
|
|
op2 |
|
|
3104 |
11) |
organic peroxide, solid, sample, temperature controlled |
|
|
|
|
|
op2 |
|
|
3114 |
11) |
3,3,5,7,7-pentamethyl-1,2,4-trioxepane |
≤ 100 |
|
|
|
|
op8 |
|
|
3107 |
|
peroxyacetic acid, type d, stabilized |
≤ 43 |
|
|
|
|
op7 |
|
|
3105 |
13) 14) 19) |
peroxyacetic acid, type e, stabilized |
≤ 43 |
|
|
|
|
op8 |
|
|
3107 |
13) 15) 19) |
peroxyacetic acid, type f, stabilized |
≤ 43 |
|
|
|
|
op8 |
|
|
3109 |
13) 16) 19) |
peroxylauric acid |
100 |
|
|
|
|
op8 |
+35 |
+40 |
3118 |
|
1-phenylethyl hydroperoxide |
≤ 38 |
|
≥ 62 |
|
|
op8 |
|
|
3109 |
|
pinanyl hydroperoxide |
> 56 – 100 |
|
|
|
|
op7 |
|
|
3105 |
13) |
copyright © united nations, 2019. all rights reserved
- 183 -
organic peroxide |
concentration (%) |
diluent type a (%) |
diluent type b (%) 1) |
inert solid (%) |
water |
packing method |
control temperature (°c) |
emergency temperature (°c) |
number (generic entry) |
subsidiary hazards and remarks |
" |
≤ 56 |
≥ 44 |
|
|
|
op8 |
|
|
3109 |
|
polyether poly-tert-butylperoxy- carbonate |
52 |
|
48 |
|
|
op8 |
|
|
3107 |
|
1,1,3,3-tetramethylbutyl hydroperoxide |
≤ 100 |
|
|
|
|
op7 |
|
|
3105 |
|
1,1,3,3-tetramethylbutyl peroxy-2- ethylhexanoate |
≤ 100 |
|
|
|
|
op7 |
+15 |
+20 |
3115 |
|
1,1,3,3- tetramethylbutyl peroxyneodecanoate |
≤ 72 |
|
≥ 28 |
|
|
op7 |
-5 |
+5 |
3115 |
|
" |
≤ 52 as a stable dispersion in water |
|
|
|
|
op8 |
-5 |
+5 |
3119 |
|
1,1,3,3-tetramethylbutyl peroxypivalate |
77 |
23 |
|
|
|
op7 |
0 |
+10 |
3115 |
|
3,6,9-triethyl-3,6,9-trimethyl-1,4,7 triperoxonane |
≤ 17 |
≥ 18 |
|
≥ 65 |
|
op8 |
|
|
3110 |
|
3,6,9-triethyl-3,6,9-trimethyl -1,4,7 triperoxonane |
≤ 42 |
≥ 58 |
|
|
|
op7 |
|
|
3105 |
28) |
remarks (refer to the last column of the table in 2.2.52.4):
diluent type b may always be replaced by diluent type a. the boiling point of diluent type b shall be at least 60°c higher than the sadt of the organic peroxide.
available oxygen 4.7%.
"explosive" subsidiary hazard label required (model no.1, see 5.2.2.2.2).
diluent may be replaced by di-tert-butyl peroxide.
available oxygen 9%.
with 9% hydrogen peroxide; available oxygen 10%.
only non-metallic packagings allowed.
available oxygen > 10% and 10.7%, with or without water.
available oxygen 10% , with or without water.
available oxygen 8.2% , with or without water. 11) see 2.2.52.1.9.
up to 2000 kg per receptacle assigned to organic peroxide type f on the basis of large scale trials.
"corrosive" subsidiary hazard label required (model no.8, see 5.2.2.2.2).
peroxyacetic acid formulations which fulfil the criteria of the manual of tests and criteria, paragraph 20.4.3 (d).
peroxyacetic acid formulations which fulfil the criteria of the manual of tests and criteria, paragraph 20.4.3 (e).
peroxyacetic acid formulations which fulfil the criteria of the manual of tests and criteria, paragraph 20.4.3 (f).
addition of water to this organic peroxide will decrease its thermal stability.
no "corrosive" subsidiary hazard label (model no.8, see 5.2.2.2.2) required for concentrations below 80%.
mixtures with hydrogen peroxide, water and acid(s).
with diluent type a, with or without water.
with 25% diluent type a by mass, and in addition ethylbenzene.
with 19%, diluent type a by mass, and in addition methyl isobutyl ketone.
with < 6% di-tert-butyl peroxide.
with 8% 1-isopropylhydroperoxy-4-isopropylhydroxybenzene.
diluent type b with boiling point > 110 °c.
with < 0.5% hydroperoxides content.
for concentrations more than 56%, "corrosive" subsidiary hazard label required (model no.8, see 5.2.2.2.2).
available active oxygen 7.6% in diluent type a having a 95% boil-off point in the range of 200 - 260 °c.
not subject to the requirements of adr for class 5.2.
diluent type b with boiling point > 130 °c.
active oxygen 6.7%.